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101.
Christoph Schmerbauch Jesus Gonzalez‐Julian Robert Röder Carsten Ronning Olivier Guillon 《Journal of the American Ceramic Society》2014,97(6):1728-1735
We report the sintering behavior of nanocrystalline zinc oxide under external AC electric field between 0 and 160 V/cm. In situ acquisition of density by means of laser dilatometry, evaluation of specimen temperature, real‐time measurement of electric field and current help analyze this peculiar behavior. Field strength and blocking electrodes significantly affect densification and microstructure, which was evaluated in the vicinity of the flash event and for the fully sintered material. High current densities flow through the sample at high electric fields, entailing a sudden increment of the temperature estimated to several hundreds of K and an exaggerated grain growth. In contrast, low current density flows through the sample at lower electric fields, which guarantees normal grain growth and highest final density. Macroscopic photoluminescence measurements give insights into the development of the defect structure. Electric fields are expected to enhance defect mobility, explaining the high densification rates observed during the sintering process. 相似文献
102.
G. Glas Rudolf Gompper M. Junius R. Mertz H.-U. Wagner Heinrich Nth M. Staudigl 《Advanced Synthesis \u0026amp; Catalysis》1990,332(6):949-967
Donor Substituted 2,4-Diazacyclopentadienones and Indigoid 1,3,5,7-Tetraazafulvalenes Hydrolysis of tris(diethylamino)imidazolylium chloride gives rise to 2,5-bis-diethyl-amino-4H-imidazolin-4-one; thiolysis leads, depending on conditions, to 2,5-bis-diethylamino-4H-imidazolin-4-thione or potassium 2,6-bis-diethylamino-1,3,5,7-tetraazafulvalene-4,8-dithiolate. The latter can be protonated to form green 2,6-bis(dimethylamino)-3,4,7,8-tetrahydro-1,3,5,7-tetraaza-fulvalen-4,8-dithione, a new indigoid compound, and alkylated to give blue 2,6-bis-diethylamino-4,8-bis-alkylthio-1,3,5,7-tetraazafulvalenes. Treatment of 2,5-bis-diethylamino-4H-imidazolin-4-thione with copper furnishes 2,6,4,8-tetrakis-diethylamino-1,3,5,7-tetraazafulvalene. – Oxidation of 2,6-bis-dimethylamino-3,4,7,8-tetrahydro-1,3,5,7-tetraazafulvalen-4,8-dithione gives rise to (2,2′-bis-diethylamino-4,4′-bi(4H-imidazol)-5,5′-dithione, corresponding to dehydroindigo, and reduction leads to a colorless compound, corresponding to leucoindigo. 相似文献
103.
Jason Iles Raminta Zmuidinaite Christoph Sadee Anna Gardiner Jonathan Lacey Stephen Harding Jernej Ule Debra Roblett Jonathan Heeney Helen Baxendale Ray K. Iles 《International journal of molecular sciences》2022,23(8)
The immune response to SARS-CoV-2 infection requires antibody recognition of the spike protein. In a study designed to examine the molecular features of anti-spike and anti-nucleocapsid antibodies, patient plasma proteins binding to pre-fusion stabilised complete spike and nucleocapsid proteins were isolated and analysed by matrix-assisted laser desorption ionisation–time of flight (MALDI-ToF) mass spectrometry. Amongst the immunoglobulins, a high affinity for human serum albumin was evident in the anti-spike preparations. Careful mass comparison revealed the preferential capture of advanced glycation end product (AGE) forms of glycated human serum albumin by the pre-fusion spike protein. The ability of bacteria and viruses to surround themselves with serum proteins is a recognised immune evasion and pathogenic process. The preference of SARS-CoV-2 for AGE forms of glycated serum albumin may in part explain the severity and pathology of acute respiratory distress and the bias towards the elderly and those with (pre)diabetic and atherosclerotic/metabolic disease. 相似文献
104.
Stefan Wagner Marcus Moser Christoph Greubel Katrin Peeper Patrick Reichart Astrid Pundt Günther Dollinger 《International Journal of Hydrogen Energy》2013
Hydrogen absorption in thin metal films clamped to rigid substrates results in mechanical stress that changes the hydrogen's chemical potential by ΔμH(σ) = −1.124σ kJ/molH for σ measured in [GPa]. In this paper we show that local stress relaxation by the detachment of niobium hydrogen thin films from the substrate affects the chemical potential on the local scale: using coincident proton–proton scattering at a proton microprobe, the hydrogen concentration is determined with μm resolution, revealing that hydrogen is not homogenously distributed in the film. The local hydrogen solubility of the film changes with its local stress state, mapping the buckled film fraction. In niobium hydrogen thin films loaded up to nominal concentrations in the two-phase coexistence region, the clamped film fraction remains in the solid solution phase, while the buckles represent the hydride phase. These results are compared to a simple model taking the stress impact on the chemical potential into account. 相似文献
105.
Ahmed G. Solomah Reinhard Odoj Christoph Freiburg 《Journal of the American Ceramic Society》1983,66(10):c182-c183
A new identification and indexing for the phase BaAl2 Ti5 O14 were accomplished using an X-ray diffraction technique. The new lattice parameters for the tetragonal lattice structure are: a0 =9.990 × 10-10 m and c0 =12.264 × 10-10 m, with a corresponding volume 1.224 × 10-27 m3 . The data provided by the Joint Committee on Powder Diffraction Standards are inconsistent both in lattice parameter values and Miller indices. The X-ray powder diffraction pattern of BaAl2 Ti5 O14 was indexed using the LSUCR (least-squares unit cell refinement) computer program. 相似文献
106.
Christoph Gottschalk Aiko Huckauf Arne Dübecke Florian Kaltner Matthias Zimmermann Ines Rahaus 《Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment》2018,35(7):1366-1383
The contamination of honey with hepatotoxic pyrrolizidine alkaloids (PAs) is a well-known hazard for food safety. While management strategies and controls of the honey industry aim to reduce the PA levels, uncertainties remain with regard to the safety of regionally produced and marketed honey. In addition, a previous study showed large differences of results obtained after various periods of storage and apparent differences between the analytical results of different laboratories. Therefore, this study aimed at examining these uncertainties by monitoring the impact of storage on the PA and PA N-oxide (PANO) content of two freshly harvested honeys and on possible demixing effects caused by pollen settling. Additionally, three analytical approaches – target analysis with matrix-matched calibration or standard addition and a sum parameter method – were applied for a comparative analysis of 20 honeys harvested in summer 2016. All samples originated from Schleswig-Holstein in Northern Germany where the PA plant Jacobaea vulgaris is currently observed on a massive scale. The results of the time series analyses showed that PANO levels markedly decreased within a few weeks and practically reached the LOD 16 weeks after harvest. Tertiary PAs, by contrast, remained stable and did not increase as a consequence of PANO decrease. The experiments on a putative demixing, which may result in a heterogeneous distribution of PAs/PANOs, revealed that there was no such effect during storage of up to 12 weeks. A comparison of the PA/PANO levels obtained by different analytical approaches showed that in some cases the sum parameter method yielded much higher levels than the target approaches, whereas in other cases, the target analysis with standard addition found higher levels than the other two methods. In summary, the results of this study highlight uncertainties regarding the validity and comparability of analytical results and consequently regarding health risk assessment. 相似文献
107.
In the design process of transmissions, one major criterion is the resulting noise emission of the powertrain due to the gear excitation. Within the past years, a lot of investigations have shown that the noise emission can be correlated to the quasi-static transmission error. Therefore, the transmission error can be used as a characteristic value for quality assurance by experimental inspections as well as for a tooth contact analysis in the design process.The noise behavior of gearboxes is mainly caused by the excitation in the tooth mesh. The standardized design and calculation methods for gears concentrate on the reduction of the excitation level. But often the physical sound characteristics do not fit in with the human noise perception. Thus gear design rules are required that are able to rate the excitation according to the perception.The effect of the targeted topography scatter generally described is the reduction of the gear mesh amplitudes with an increase of the background noise. The objective of the report is to develop an understanding of the influence of different micro geometry scatters on the excitation behavior.Finally, it is the aim to design an aurally-accurate micro geometry scattering for the optimization of ground bevel gears in terms of tonality reduction and increased background noise. By means of a variant calculation and weighted target variables, psychoacoustic optimized micro geometry scattering is designed. At the same time, attention is also focused on a simple production of mixed topographies. 相似文献
108.
Nano design for macroscopic coatings – new application potentials by PVD coatings up to 100 μm thickness Non-homogeneous coatings still limit the application of thicker layers due to defect growth and irregular layer thickness distribution along the surface of complex shaped components. Therefore, the layer thickness is usually limited to about 10 μm. In order to limit the surface roughness by the growing layer, multilayer coating systems are deposited by highly ionized plasmas. This allows significantly smoother layers to be produced, which until now could only be produced by mechanical finishing. Furthermore, by combining selected material systems and targeted parameter selection, structures can be deposited during coating, especially on edges, which result in a reduction of the cutting edge radius. In future, edge geometries should therefore be able to be specifically adjusted through the coating process. 相似文献
109.
Ein international erfolgreiches Schema für Cybersicherheits-Zertifizierungen bedarf akzeptierter und implementierter Sicherheitsstandards. Dieser Artikel erörtert kritisch die komplexen Anforderungen hinsichtlich der Vollständigkeit, Dynamik und Durchsetzung aus europäischer Perspektive und zeigt am Beispiel der eIDAS-Verordnung die Herausforderungen bei der Umsetzung auf. 相似文献
110.