微波场中铌精矿碳热还原反应行为研究

目前铌资源的研究大多处于常规加热阶段,因为能耗高、冷中心等问题无法广泛推广。微波加热技术是一种新型加热技术,可以有效避免冷中心等问题。借助微波马弗炉将铌精矿碳热还原反应与微波加热相结合,探究还原温度、配碳比及保温时间对铌精矿金属化率的影响,以及金属颗粒的成长行为。研究结果表明,微波加热在碳热还原反应中优于常规加热,在微波加热下,还原温度为1100℃、保温30 min、配碳比为1时,金属化率达到94.84%;1000℃时NbC开始生成,1100℃时铌钛产物主要为(Ti,Nb)C,1300℃时,钛的产物主要以TiC形式存在。     

“金属布”硬质复合涂层的微观组织及性能

用Ｘ射线衍射仪、扫描电镜、摩擦磨损试验等，研究了粉末冶金“金属布”及其钢表面改性技术在钢表面制备的ＷＣ－Ｎｉ系合金复合涂层的微观组织和性能。结果表明：该合金涂层中硬质相的体积含量可大于６０％；涂层的微观组织有两类：一种是在粘结相中均匀分布的碳化物与弥散分布的球状粘结相富集区构成的非均匀结构；另一种是碳化物和粘结相都均匀分布的均匀结构。碳化物分布区的硬度大于Ｈｖ１０７６，粘结相富集区的硬度在Ｈｖ９６７～Ｈｖ４５８之间。涂层与钢基体之间有几～几十微米的界面过渡区，形成剪切结合强度大于４００ＭＰａ的冶金结合。复合涂层的耐磨性明显优于调质Ｔ８工具钢。     

全球钛业回顾和展望

概述了磁光记录原理，介绍了磁光盘的基板材料，并重点阐述了稀土－过渡（ＲＥ－ＴＭ）合金非晶膜的制造方法，性能及其保护膜。另外还扼要介绍了氧化物单晶膜，多晶膜和多层超薄磁光记录膜的优缺点，并指出多层膜磁光记录材料是今后的发展方向。     

PRESSURE DISTRIBUTION IN THE AIR-SPARGED HYDROCYCLONE

ＰＲＥＳＳＵＲＥＤＩＳＴＲＩＢＵＴＩＯＮＩＮＴＨＥＡＩＲ－ＳＰＡＲＧＥＤＨＹＤＲＯＣＹＣＬＯＮＥ￥Ｃｈｕ，Ｌｉａｎｇｙｉｎ；ＬｕｏＱｉａｎ（ＭｉｎｅｒａｌＥｎｇｉｎｅｅｒｉｎｇＤｅｐａｒｔｍｅｎｔ，ＮｏｒｔｈｅａｓｔｅｒｎＵｎｉｖｅｒｓｉｔｙ，Ｓｈｅ...     

Flow field in air-sparged hydrocyclone

ＦＬＯＷＦＩＥＬＤＩＮＡＩＲ－ＳＰＡＲＧＥＤＨＹＤＲＯＣＹＣＬＯＮＥＣｈｕ，Ｌｉａｎｇｙｉｎ；Ｌｕｏ，Ｑｉａｎ（ＭｉｎｅｒａｌＥｎｇｉｎｅｅｒｉｎｇＤｅｐａｒｔｍｅｎｔ，Ｐ．Ｏ．Ｂｏｘ１３９ＮｏｒｔｈｅａｓｔｅｒｎＵｎｉｖｅｒｓｉｔｙ，Ｓｈｅｎｙａｎ...     

Ti－24Al－11Nb腐蚀疲劳断口形貌的研究

Ｔｉ－２４Ａｌ－１１Ｎｂ腐蚀疲劳断口形貌的研究张跃，褚武扬，王燕斌，肖纪美（北京科技大学北京１０００８３）１引言对Ｔｉ－２４ＡＩ－１１Ｎｂ合金的断裂特征和断口形貌已进行了较多的研究［“］．在３００ｏＣ的氢气中该合金能发生氢致开裂，其断口形貌与过载断口...     

VAc/AA改性的VAE乳液高速接嘴卷烟胶的研制

介绍了VAc/AA改性的VAE乳液高速接嘴卷烟胶的制备方法。研究了各种因素对胶粘剂性能的影响。结果表明 :VAc/AA用量增加 ,VAE乳液的粘接性能增强。选择与VAE乳液相适应的乳化剂和控制适宜的pH值 ,可以增加VAE乳液的稳定性。采用滴加引发剂和混合单体的方法 ,可以避免过速反应产生及大粒径胶粒生成     

Preparation of Protein-Stabilized β-Carotene Nanodispersions by Emulsification–Evaporation Method

This work was initiated to prepare protein-stabilized β-carotene nanodispersions using emulsification–evaporation. A pre-mix of the aqueous phase composed of a protein and hexane containing β-carotene was subjected to high-pressure homogenization using a microfluidizer. Hexane in the resulting emulsion was evaporated under reduced pressures, causing crystallization and precipitation of β-carotene inside the droplets and formation of β-carotene nanoparticles. Sodium caseinate (SC) was the most effective emulsifier among selected proteins in preparing the nanodispersion, with a monomodal β-carotene particle-size distribution and a 17-nm mean particle size. The results were confirmed by transmission-electron microscopy analysis. SC-stabilized nanodispersion also had considerably high ζ-potential (−27 mV at pH 7), suggesting that the nanodispersion was stable against particle aggregation. Increasing the SC concentration decreased the mean particle size and improved the polydispersity of the nanodispersions. Nanodispersions prepared with higher β-carotene concentrations and higher organic-phase ratios resulted in larger β-carotene particles. Although increased microfluidization pressure did not decrease particle size, it did improve the polydispersity of the nanodispersions. Repeating the microfluidization process at 140 MPa caused the nanodispersions to become polydisperse, indicating the loss of emulsifying capacity of SC due to protein denaturation.     

Effects of enzymes and gamma irradiation on the tensile strength and morphology of poly(p-dioxanone) fibers

The objective of this study was to examine how and to what extent a new degradable polymeric fiber, poly(p-dioxanone), used as a surgical suture material, degrades in the presence of enzymes and after γ-irradiation. The degradation of the fiber was studied mechanically using an Instron and morphologically by SEM. Both esterase and trypsin enzymes and their corresponding buffer controls were used. The fibers were γ-irradiated at the dosages ranging from 0 to 20 Mrad, immersed in the solution for up to 70 days, and then removed for tensile strength and morphological examinations. It was found that γ-irradiation alone lowered the tensile strength of PDS fibers and made them more susceptible to hydrolysis. Esterase and trypsin did not accelerate the hydrolytic degradtion of this fiber to any significant level. Both γ-irradiation and enzymes influenced the gross morphological characteristic of PDS fibers when they were subjected to hydrolysis. The most important morphological observations were the formation of surface cracks and chips on the fibers and the subsequent peeling of the chips. Enzyme-treated PDS fibers exhibited similar morphological findings but the size of the chips was smaller. The morphological observations of PDS fibers were consistent with the tensile strength data.     

Multi-dimensional transient mathematical simulator of blast furnace process based on multi-fluid and kinetic theories

The ironmaking blast furnace is regarded as one of the biggest and most complex industrial reactors, because it includes various materials like gas, lump granular materials, liquids and powders and more than 30 major reactions and phase changes in a single reaction vessel. The mathematical simulator of this process developed in this study used the multi-fluid treatment as its framework, since the motions of these materials were governed by different flow mechanisms. The rates of the interactions among the phases and the chemical reactions were evaluated based on kinetic theories. The model successfully reproduced the fields of velocity, temperature and reaction in the furnace and its validity was confirmed. The simulator was also applied to a novel operation, namely the top gas recycling combined with the carbon-composite iron-ore charging and the waste plastics injection, and the advantages in furnace efficiency and environmental load were quantitatively indicated.