相位测量定位法在焦炉车辆上的应用与研究

文中通过测量载波相位进行定位的方法来解决焦炉车辆的定位问题，以达到无线定位的目的。并对定位的数学模型进行了详细的分析与论述。     

复合吸附剂CaO/Al2O3对CO2吸附性能的研究-研究生论坛

采用过量浸渍法制备了不同质量分数的复合吸附剂CaO/Al2O3,并采用CO2-TPD、低温氮气吸附脱附、XRD以及FT-IR等方法对吸附剂的结构进行了表征。采用容量法测定了吸附剂在25 oC和70 oC条件下的吸附性能。结果表明,CO2在与吸附剂的作用过程中形成了CaCO3;在吸附温度为70 oC、压力为1.0 MPa的条件下,当CaO的负载量为5wt.%时,复合吸附剂的吸附效果最好,吸附量为36.45 mg/g。用D-R模型计算了复合吸附剂的吸附热,用Clausius-Clapeyron方程研究了复合吸附剂吸附过程的吸附焓变与覆盖度的关系。结果表明,复合吸附剂的吸附热随着CaO掺杂量的增加而增加,而吸附过程的吸附焓变随着吸附质覆盖度的增加而降低。     

An NMR study of acid sites on chlorided alumina catalysts using trimethylphosphine as a probe

The MAS-NMR spectra of adsorbed trimethylphosphine (TMP) were used to determine the concentration of Brønsted and Lewis acid sites on pure and chlorinated-Al₂O₃ samples. Chlorination with CHCl₃,CCl₄ or AlCl₃ promoted the formation of Brønsted acid centers, which are characterized by the protonated adduct of TMP. This adduct has a³¹P chemical shift of ca. –3.8 ppm and a J_P–H scalar coupling of 517 Hz. Additional resonances in the –44 to –54 ppm range are attributed to Lewis acid-base pairs. In some cases a partially resolved J_P–Al coupling is observed, which confirms the assignment. Upon thermal treatment of a chlorinated sample at temperatures > 200°C, the concentration of Brønsted acid centers decreased; the concentration of one type of Lewis acid increased and another remained almost constant. In a parallel set of experiments the initial conversion ofn-hexane at 150°C and the yields of cracking and isomerization products were determined. Comparable functional relationships were observed between the loss of Brønsted acid sites and the decrease in yields of both cracking and isomerization products. These results suggest that Bransted acidity is responsible for the cracking and isomerization ofn-hexane over chlorided aluminas at 150°C.     

基于局部重要性采样的SAR图像纹理特征提取方法

合成孔径雷达（Synthetic aperture radar,SAR）图像因为相干斑现象和目标响应的空间变化呈现出一种纹理特性,局部二进编码等局部图像特征 在光学纹理描述中获得较好的结果,但光学纹理特征在描述SAR图像纹理特性中因为相干成像特性往往失效. 本文 在前期工作纹理特征框架的基础上,提出了一种局部重要性采样二进编码的SAR图像纹理特征（Feature extraction based on local important sampling binary,LISBF）描述方法:首先,利用样本图像对局部采样位 置进行随机自适应采样,基于重要性采样（Important sample,IS）方法输出递归学习位置结果;然后,利用学习出的纹理重要采样点对进 行二进特征编码;最后,通过映射和统计生成描述算子. 该特征较固定位置采样能够获取更大范围信息,同时能通 过采样避免特征维数的急剧增大;通过自适应学习重要性关键点较随机采样 更容易捕捉纹理固有信息;较好地适应了SAR图像极低信噪比和斑点现象的纹理. 本文将该特征用于真实图像和标准纹理库的分类研究,实验结果证明了该特征的有效性.     

Recent studies of self-condensation and co-condensation of melamine-formaldehyde resins; cure at low temperatures

Self-condensation: recent research on the chemical pathways by which alcoholated melamine-formaldehyde (MF) resins react with themselves and on the product structures is summarized. Model compound studies suggest that bridges are less stable than widely thought unless they are in hexahydro-1,3,5-triazine ring structures. In acyclic structures they are probably less stable than bridges. Co-condensation: studies of how the composition of MF resins influences the rates of reaction with poly(ol) co-reactant show that MF resins that contain very low levels of and/or functionality are quite reactive. Reactivities of a variety of poly(ester) and acrylic coreactants were studied. By combining reactive MF resins with reactive co-reactants one can formulate high solids enamels that cure by co-condensation in 30 min at 50 to 65 °C with 0.5 parts per hundred (phr) of p-toluenesulfonic acid (p-TSA) catalyst. Cure at 25 °C appears feasible with higher catalyst levels.     

利用腈纶废丝合成絮凝剂PAN—DCD

本文以腈纶废丝为原料与双氰双胺在碱性溶液中反应，成功地制得含有多种活性基因的聚合物ＰＡＮ－ＤＣＤ，并用于染料废水脱色及炼油厂废水除油，除酚的处理研究，与常规使用的几种絮凝剂进行处理结果对照，实验结果表明：该产品单独使用处理效果明显优于其他絮凝剂，与聚铝复合使用处理效果更为理想。     

辊压机水泥联台粉磨系统生产设计应注意的问题

山水集团新建粉磨站均采用辊压机和水泥磨组成的联合粉磨工艺，全部采用了国产化设备，且所建生产线均在短期内顺利实现了达标达产。文章概要介绍了该类粉磨生产线的主机配置及工艺流程；重点分析了为确保该类生产线的快速建成、高效益运行．在设计和生产管理中应该注意的相关问题和细节。     

对二甲苯直接电解氧化反应的研究

研究了在有机溶剂、支持电解质和碳棒存在下，对二甲苯的直接电解氧化反应，使用GC－MS方法分析鉴定了主要电解氧化产物，讨论了电解氧化产物成分随电解时间的变化规律，提出了对二甲苯的直接电解氧化反应过程。     

气相酯化反应的高效催化剂—活性炭固载的杂多酸（HPA／C）

在气－固反应体系中研究了固载在活性炭上的硅钨（ＳｉＷ_（１２））和磷钨（ＰＷ_（１２））杂多酸在合成乙酸乙酯和乙酸丁酯中的催化性能。实验结果表明，反应温度、空间速度和反应物的配比均对催化活性有明显影响，并且，负载催化剂表面酸量与酯化反应活性之间存在着相应的顺变关系。催化剂在较低反应温度和相当大的流速下具有较高的酯化活性，且性能稳定，有一定的应用前景。