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151.
The viscoelastic properties of a rubber–resin blend, which influences performance of the blend as a pressure-sensitive adhesive, depend upon the structure of the resin as well as its molecular weight. The effect of the concentration of a compatible resin in the blend was examined using a mechanical spectrometer. Four types of resins were used. These are the rosin esters, polyterpenes, pure monomer resins such as polystyrene and poly(vinyl cyclohexane), and petroleum stream resins. Each was examined in blends with both natural rubber and styrene–butadiene rubber over a range of concentrations. It is shown that the temperature of the tan δ peak for compatible systems can be predicted by the Fox equation, T = W1T + W2T, where W1 and W2 are the weight fractions of the resin and rubber, respectively, and the Tg's are the tan δ peak temperatures in K. The plateau modulus G for a blend can be identified as the G′ value in the rubbery plateau at the point where tan δ is at a minimum. The relationship between G and G, the plateau modulus for the undiluted elastomer, is shown to be proportional to the volume fraction of the elastomer raised to the 2.3–2.4 power for natural rubber with six different compatible resins. The exponent for styrene–butadiene rubber is 2.5–2.6 with four different resins. Using these relationships, both the tan δ peak temperature and plateau modulus can be predicted for a rubber–resin system from data on the unmodified elastomer and on one typical rubber–resin blend. 相似文献
152.
The effect of preparation method on MnO
x
–CeO2 mixed oxide catalysts for methane combustion at low temperature was investigated by means of BET, XRD, XPS, H2-TPR techniques and methane oxidation reaction. The catalysts were prepared by the conventional coprecipitation, plasma and
modified coprecipitation methods, respectively. It was found that the catalyst prepared by modified coprecipitation was the
most active, over which methane conversion reached 90% at a temperature as low as 390 °C. The XRD results showed the preparation
methods had no effect on the solid solution structure of MnO
x
–CeO2 catalysts. More Mn4+ and richer lattice oxygen were found on the surface of the modified coprecipitation prepared catalyst with the help of XPS
analysis, and its reduction and BET surface area were remarkably promoted. These factors could be responsible for its higher
activity for methane combustion at low temperature. 相似文献
153.
154.
The process of 180°domain switching in PbTiO_3 single crystal under an antiparallel electric field was investigated by the three-dimensional phase field simulation,especially the effect of electric field on the type and duration of domain switching.It is found that the polarization reversal of domains takes place under an antiparallel electric field in PbTiO_3 single crystal.The results of the phase field simulation indicate that there is only 90°domain switching under a weak electric field.With the rise... 相似文献
155.
目的:对肿节风注射液进行异常毒性、溶血与凝聚试验、过敏反应安全性实验评价。方法:根据《中国药典》2010年版一部附录"中药注射剂安全性检查法应用指导原则"的要求及相关项目的技术规范进行试验。结果:按每只小鼠尾静脉注射0.5ml肿节风注射液,结果实验小鼠均无异常反应;溶血与凝聚试验供试品管中的溶液在3小时内不发生溶血和凝聚;按豚鼠腹腔注射0.5ml/只和静脉注射1.0ml/只作为本品的致敏剂量和激发剂量,结果试验豚鼠均未出现过敏反应。结论:本肿节风注射液进行的异常毒性、溶血与凝聚试验和致敏反应的安全性评价符合规定。 相似文献
156.
157.
A facultative heterotrophic strain (DS-0205) was isolated from a deep-sea sediment sample collected at a depth of 5.2 km in
the eastern Pacific Ocean, China. Strain DS-0205 is motile helmet-like single cell or pairs, forming hemisphere with the center
sunken of variable size. It has a widespread carbon source and nitrogen source, including agarose, citric acid, salicin, D-glucitol nitrate, sodium nitrite and ethylamine. It can grow in the following environment: temperature 4–37 °C, pH 2.0–12.0,
tolerance to NaCl⩽15%. Two phylogenetic trees, one based on the ITS and 5.8S rRNA sequences and the other based on the 18S
rRNA sequences, unite strain DS-0205(=JCM 0205) to the type strain of Rhodosporidium diobovatum JCM 3787 through a considerable evolutionary distance. These results suggest that strain DS-0205 is a new strain of the Rhodosporidium diobovatum. 相似文献
158.
以工程中常见的配筋率较大(〉0.85)、厚度较小(≤120 mm)的板为对象,通过对冲切破坏特征的观察分析,假定沿纵向钢筋平面,混凝土劈裂所致的纵筋销栓失效为连锁破坏源,建立了新的错动冲切模型并推导了上限解。研究发现,与按搜集到的构件样本总体分析结果相比(均值为1.072,变异系数为0.250),符合上述特征的试件组,其冲切承载力理论计算值和试验观测值之比的均值变化不大(为1.017),而变异系数有显著降低(为0.184),说明所作假定及所建模型用于描述该类板的受力行为是合适的。 相似文献
159.
Asymptotic state behaviour and its modeling for saturated sand 总被引:3,自引:0,他引:3
A new double hardening elasto-plastic model is proposed in this paper based on the existing unified hardening model (UH model).
By assuming that there is part coupling effect between the plastic volumetric strain and plastic shear strain, hardening parameters
consisting of a coupled and an uncoupled components are adopted in this model. A unique feature of this model is that it can
describe not only the conventional drained and undrained behaviors of soil, but also the stress-strain relationships of soil
under partially drained conditions which can be volumetric compression or dilation. Adopting the asymptotic state concept,
simple equations for estimating the limiting stress ratio under undrained or earth pressure at rest (i.e. K
0) conditions are derived. The new model is relatively simple to be adopted in practice for two reasons. First, the same soil
parameters as in Cam-clay model are used except the addition of one extra parameter, the stress ratio at the characteristic
state. Second, all the parameters can be determined using conventional triaxial compression tests.
Supported by the National Natural Science Foundation of China (Grant Nos. 10672010 and 50479001) and the National Earthquake
Science Item (Grant No. 200808076) 相似文献
160.