Catalyst‐controlled chemodivergent annulation between o‐indolo anilines and diazo compounds has explored for the synthesis of indolo‐fused diazepine and quinoxaline. Under the Rh(III) catalyst, reaction proceeded through the free amine assisted C2−H activation followed by amidation leading to the diazepino[1,7‐a]indole in a highly selective manner. While with Ru(II) catalyst, reaction involves formation Ru−carbene complex followed by −NH2 group insertion and cascade cyclization via metallo‐ene type reaction, β‐hydride elimination to furnish the indolo[1,2‐a]quinoxaline as the predominating product. This strategy directs modular approach towards the construction of unique indolo‐fused diazepine/quinoxaline as well as pyrrolo‐fused diazepine/quinoxaline scaffolds in excellent yields.
Underwater visual inspection is an important task for checking the structural integrity and biofouling of the ship hull surface to improve the operational safety and efficiency of ships and floating vessels. This paper describes the development of an autonomous in‐water visual inspection system and its application to visual hull inspection of a full‐scale ship. The developed system includes a hardware vehicle platform and software algorithms for autonomous operation of the vehicle. The algorithms for vehicle autonomy consist of the guidance, navigation, and control algorithms for real‐time and onboard operation of the vehicle around the hull surface. The environmental perception of the developed system is mainly based on optical camera images, and various computer vision and optimization algorithms are used for vision‐based navigation and visual mapping. In particular, a stereo camera is installed on the underwater vehicle to estimate instantaneous surface normal vectors, which enables high‐precision navigation and robust visual mapping, not only on flat areas but also over moderately curved hull surface areas. The development process of the vehicle platform and the implemented algorithms are described. The results of the field experiment with a full‐scale ship in a real sea environment are presented to demonstrate the feasibility and practical performance of the developed system. 相似文献
Thin film metal–insulator–metal capacitors with undoped HfO2 as the insulator are fabricated by sputtering from ceramic targets and subsequently annealed. The influence of film thickness and annealing temperature is characterized by electrical and structural methods. After annealing, the films show distinct ferroelectric properties. Grazing incidence X‐ray diffraction measurements reveal a dominant ferroelectric orthorhombic phase for thicknesses in the 10–50 nm range and a negligible non‐ferroelectric monoclinic phase fraction. Sputtering HfO2 with additional oxygen during the deposition decreases the remanent polarization. Overall, the impact of oxygen vacancies and interstitials in the HfO2 film during deposition and annealing is correlated to the phase formation process. 相似文献
In this study, an efficient and stable large‐area blade‐coated organic solar cell (OSC) module with an active area of 216 cm2 (16 elementary cells connected in series) is demonstrated by combining appropriate thermal annealing treatment with the use of 4,4′‐(((methyl(4‐sulphonatobutyl)ammonio)bis(propane‐3,1‐diyl))bis(dimethyl‐ammoniumdiyl))bis‐(butane‐1‐sulfonate) (MSAPBS) as the cathode interfacial layer. For the opaque device using poly[4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b;4,5‐b′]dithiophene‐2,6‐diyl‐alt‐(4‐(2‐ethylhexyl)‐3‐fluorothieno[3,4‐b]thiophene‐)‐2‐carboxylate‐2‐6‐diyl)] (PBDTTT‐EFT (PTB7‐Th)):[6,6]‐phenyl C71‐butyric acid methyl ester (PC71BM) blend film as the active layer, the power conversion efficiency (PCE) of 5.6% is achieved under AM 1.5G solar light illumination. Very encouragingly, our strategy can be applicable for semitransparent OSCs, and a remarkable PCE up to 4.5% is observed. To the best of our knowledge, the PCE of 5.6% for opaque device and 4.5% for semitransparent device represent the highest PCE ever reported for OSCs with the active area exceeding 100 cm2. The devices also show an impressive stability under outdoor environment, where the efficiency decay is less than 30% for 60 days. Our findings can pave the way toward the development of organic solar cell modules with high performance and long‐term stability. 相似文献
Soiling problems are always encountered for equipment installed in outdoor environments, such as headlamps of automobiles, air conditioners, solar collectors, and so on. How to prevent soiling problems on this equipment is one of the challenges for the design of their external layouts. Thus, evaluations of the dust sedimentation quantities on the surfaces of such equipment are necessary. Outdoor testing is usually straightforward but it takes a long time to experience various environmental parameters, such as dust-laden air, wind speed, wind direction, and so on. Indoor tests, performed in a dust test chamber, are instruments for controlling various environmental parameters independently. The conventional design for a dust test chamber is aimed at providing for a test under extreme environmental conditions. The uniformity of dust sedimentation rate within the chamber is not rigorously controlled. Nevertheless, some applications such as the effect of dust sedimentation on the glazing of solar collector require uniform distribution of dustfall in the test chamber for the indoor (laboratory) test. An improved design for a conventional dust test chamber is proposed. Performance tests done with the remodeled dust test chamber based on the improved design show that the normalized standard deviation of the dustfall concentration can be controlled within 2.41% ± 1.29%. 相似文献
In profile monitoring for a multivariate manufacturing process, the functional relationship of the multivariate profiles rarely occurs in linear form, and the real data usually do not follow a multivariate normal distribution. Thus, in this paper, the functional relationship of multivariate nonlinear profile data is described via a nonparametric regression model. We first fit the multivariate nonlinear profile data and obtain the reference profiles through support vector regression (SVR) model. The differences between the observed multivariate nonlinear profiles and the reference profiles are used to calculate the vector of metrics. Then, a nonparametric revised spatial rank exponential weighted moving average (RSREWMA) control chart is proposed in the phase II monitoring. Moreover, a simulation study is conducted to evaluate the detecting performance of our proposed nonparametric RSREWMA control chart under various process shifts using out‐of‐control average run length (ARL1 ). The simulation results indicate that the SREWMA control chart coupled with the metric of mean absolute deviation (MAD) can be used to monitor the multivariate nonlinear profile data when a common fixed design (CFD) is not applicable in the phase II study. Finally, a realistic multivariate nonlinear profile example is used to demonstrate the usefulness of our proposed RSREWMA control chart and its monitoring schemes. 相似文献
Organic semiconductors (OSCs) have been widely studied due to their merits such as mechanical flexibility, solution processability, and large‐area fabrication. However, OSC devices still have to overcome contact resistance issues for better performances. Because of the Schottky contact at the metal–OSC interfaces, a non‐ideal transfer curve feature often appears in the low‐drain voltage region. To improve the contact properties of OSCs, there have been several methods reported, including interface treatment by self‐assembled monolayers and introducing charge injection layers. Here, a selective contact doping of 2,3,5,6‐tetrafluoro‐7,7,8,8‐tetracyanoquinodimethane (F4‐TCNQ) by solid‐state diffusion in poly(2,5‐bis(3‐hexadecylthiophen‐2‐yl)thieno[3,2‐b]thiophene) (PBTTT) to enhance carrier injection in bottom‐gate PBTTT organic field‐effect transistors (OFETs) is demonstrated. Furthermore, the effect of post‐doping treatment on diffusion of F4‐TCNQ molecules in order to improve the device stability is investigated. In addition, the application of the doping technique to the low‐voltage operation of PBTTT OFETs with high‐k gate dielectrics demonstrated a potential for designing scalable and low‐power organic devices by utilizing doping of conjugated polymers. 相似文献
