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11.
This study examines the incorporation of highly unsaturated n−3 fatty acids (HUFA) into triacylglycerols (TAG) of brown adipose
tissue (BAT), and their effect on the positional distribution of saturated (SFA) and of unsaturated (UFA) 16- or 18-carbon
fatty acids. To this end, rats were fed a fish oil diet for up to four weeks. The stereospecific analysis of TAG was based
on generation ofsn-1,2- andsn-2,3-acylglycerols by Grignard degradation, followed by synthesis of phosphatidic acid and specific hydrolysis with phospholipase
A2. From the end of the first week of fish oil feeding, a steady-state in the fatty acid composition of TAG in BAT was reached.
HUFA concentration increased 30-fold, mainly at the expense of n−9 UFA and of SFA. The amount of SFA decreased selectively
at position 3, where these fatty acids were progressively replaced by n−3 HUFA. By contrast, the amount of UFA decreased at
all positions, and their positional distribution was not affected. About 60% of HUFA was incorporated at position 3. Nearly
twice as much 22∶6n−3 was incorporated into TAG than had been previously observed in white adipose tissue (WAT) [Leray, C.,
Raclot, T., and Groscolas, R. (1993)Lipids 28, 279–284]. At the steady-state, the distribution of HUFA was characterized by high proportions of 22∶6n−3 and 20∶5n−3 in
position 3. Moreover, in each position of TAG, a steady level was reached rapidly (within 1 wk). It is concluded that, during
fish-oil feeding, fatty acids in TAG of BAT show characteristic time-course changes that lead to a characteristic composition
and a tissue-specific positional distribution. This suggests that adipose tissue has its own specificity in controlling the
build-up of TAG stores, which is likely to be regulated by the specificity of acylating enzymes as well as molecular rearrangements. 相似文献
12.
Sabine Braipson-Danthine Claude Deroanne 《Journal of the American Oil Chemists' Society》2006,83(7):571-581
Several oils and fats often used for the industrial preparation of European shortenings were blended in binary systems. The
equilibrium (after 48 h at 15°C) solid fat contents (SFC; determined by pulsed NMR spectroscopy) were measured and plotted
against blend composition. SFC of the blends resulted from the SFC of each fat for the considered temperature as well as the
type of interaction existing between those fats (namely, ideal behavior, monotectic interaction, eutectic interaction, and
so on). The type of relationship fitted was dependent on the kind of interaction: Linear relationships were found for total
compatibility between fats, and polynomial-type (order 2) relationships were found for fats exhibiting incompatibility. Some
corresponding ternary oils and fats blends were also prepared and analyzed. Selected relationships (regression equations of
the fitted curves) obtained for binary blends were combined in order to calculate the SFC of the corresponding ternary blends.
Experimental values were generally close to predicted ones. The representation of SFC as a function of composition is interesting
as it allows one to determine rapidly and easily the type of molecular interaction between two fats and also to determine
equations that can be combined to calculate easily the SFC of corresponding ternary blends crystallized in the same way with
a good accuracy. The texture (hardness) of several binary and ternary blends was also measured. The combination of the results
obtained for SFC with the results obtained for the hardness of binary blends allows the prediction of the hardness of a corresponding
ternary blend under the same conditions. 相似文献
13.
Claude Deslouis Bernard Tribollet Guiliano Mengoli Marco M. Musiani 《Journal of Applied Electrochemistry》1988,18(3):374-383
The electrochemical behaviour of a Cu rotating disc electrode in neutral aerated NaCl solution was investigated in the cathodic and anodic ranges and at the corrosion potential. In the cathodic range, where the reduction of oxygen takes place, reduction peaks allow the identification and quantitative evaluation of insoluble corrosion products (CuCl and Cu2O). In the anodic range Cu is dissolved, most likely as CuCl
2
–
. A new mechanism for the anodic dissolution is proposed after comparing our data with previously published mechanisms. Corrosion currents were found to decrease with time and to be a function of the rotation rate of the electrode. Both the mixed kinetics of the anodic partial reaction and diffusion through a porous layer seem to be relevant in controllingl
corr. 相似文献
14.
A series of polymers based on methylmethacrylate, butylacrylate, and ω‐perfluorooctylalkylacrylate were prepared by radical polymerization. By changing both the length of the hydrocarbon spacer, between the fluorinated chain and the ester function of the fluorinated monomer, and its concentration, the surface properties of the resulting terpolymers were greatly influenced. Polymers containing small amounts of fluorinated comonomer units had considerably reduced surface energies compared to the copolymer poly (methylmethacrylate‐co‐butylacrylate) taken as reference. The outermost surface composition has been investigated by the XPS technique, confirming the strong fluorine enrichment. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 821–827, 2006 相似文献
15.
Nocturnal intragastric feeding has been shown to be an effective means to improve clinical and biochemical features in glycogen
storage disease type I (GSD-I). In this study, we investigated the fatty acid patterns in a whole plasma and in circulating
lipoproteins in patients on this therapy. The results demonstrated massive concentration of total fatty acids coupled with
higher levels of triglycerides, free cholesterol, cholesterol ester and phospholipids. This hyperlipidemia involved all fatty
acids without distinction of carbon or bond numbers. However, the increase was more pronounced for saturated than polyunsaturated
fatty acids, as was demonstrated by the ratios of both oleic acid to linoleic acid (1.91±0.40 vs 0.80±0.09 in controls) and
of ω3+ω6 to ω9 fatty acid families (0.92±0.11 vs 1.66±0.08 in controls). The fatty acid patterns in very low (VLDL), low (LDL)
and high (HDL) density lipoprotein showed substantial differences in composition, reflecting an association between an abnormal
lipoprotein pattern and essential fatty acid deficiency. Furthermore, GSD-I patients exhibited a significant increase in VLDL
(17±2 vs 47±7 mg/dl) and LDL cholesterol (124±7 vs 206±24 mg/dl), coupled with a decrease in HDL cholesterol (49±4 vs 28±3
mg/dl). These data documenting high LDL cholesterol and low HDL cholesterol associated with an increased concentration and
proportion of saturated fatty acids suggest that GSD-I patients on nocturnal intragastric feeding are at high risk for atherosclerosis
and its complications. 相似文献
16.
Abdoul Bitar Stéphane Dauzère-Pérès Claude Yugma Renaud Roussel 《Journal of Scheduling》2016,19(4):367-376
In this paper, we propose a metaheuristic for solving an original scheduling problem with auxiliary resources in a photolithography workshop of a semiconductor plant. The photolithography workshop is often a bottleneck, and improving scheduling decisions in this workshop can help to improve indicators of the whole plant. Two optimization criteria are separately considered: the weighted flow time (to minimize) and the number of products that are processed (to maximize). After stating the problem and giving some properties on the solution space, we show how these properties help us to efficiently solve the problem with the proposed memetic algorithm, which has been implemented and tested on large generated instances. Numerical experiments show that good solutions are obtained within a reasonable computational time. 相似文献
17.
Nadia Magnenat Thalmann Igor Sunday Pandzic Jean‐Claude Moussaly 《Digital Creativity》2013,24(2):59-66
Abstract This paper describes the making of a short film on the Xian terra‐cotta soldiers using our integrated HU‐MANOID software. The method of creating and animating the soldiers’ faces is first presented. Then, we show how our approach, based on metaballs and spline surfaces, was used for designing and deforming soldiers’ bodies. For the animation of the bodies, we describe the motion control methods. Clothes for the soldiers are then described as well as horses and decor design. For the rendering, we explained our strategy using parallel machines. Finally, problems of integration are addressed. 相似文献
18.
19.
Deduction modulo is a way to combine computation and deduction in proofs, by applying the inference rules of a deductive system (e.g. natural deduction or sequent calculus) modulo some congruence that we assume here to be presented by a set of rewrite rules. Using deduction modulo is equivalent to proving in a theory corresponding to the rewrite rules, and leads to proofs that are often shorter and more readable. However, cuts may be not admissible anymore.We define a new system, the unfolding sequent calculus, and prove its equivalence with the sequent calculus modulo, especially w.r.t. cut-free proofs. It permits to show that it is even undecidable to know if cuts can be eliminated in the sequent calculus modulo a given rewrite system.Then, to recover the cut admissibility, we propose a procedure to complete the rewrite system such that the sequent calculus modulo the resulting system admits cuts. This is done by generalizing the Knuth–Bendix completion in a non-trivial way, using the framework of abstract canonical systems.These results enlighten the entanglement between computation and deduction, and the power of abstract completion procedures. They also provide an effective way to obtain systems admitting cuts, therefore extending the applicability of deduction modulo in automated theorem proving. 相似文献
20.