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991.
992.
993.
Seok Hun Kang In Gyoo Kim Bit-Na Kim Ji Hwan Sul Young Sun Kim In-Kyu You 《ETRI Journal》2018,40(2):275-282
Flash reduction of graphene oxide is an efficient method for producing high quality reduced graphene oxide under room temperature ambient conditions without the use of hazardous reducing agents (such as hydrazine and hydrogen iodide). The entire process is fast, low-cost, and suitable for large-scale fabrication, which makes it an attractive process for industrial manufacturing. Herein, we present a simple fabrication method for a flexible in-plane graphene micro-supercapacitor using flash light irradiation. All carbon-based, monolithic supercapacitors with in-plane geometry can be fabricated with simple flash irradiation, which occurs in only a few milliseconds. The thinness of the fabricated device makes it highly flexible and thus useful for a variety of applications, including portable and wearable electronics. The rapid flash reduction process creates a porous graphene structure with high surface area and good electrical conductivity, which ultimately results in high specific capacitance (36.90 mF cm−2) and good cyclic stability up to 8,000 cycles. 相似文献
994.
Hetero‐Nanonet Rechargeable Paper Batteries: Toward Ultrahigh Energy Density and Origami Foldability 下载免费PDF全文
Sung‐Ju Cho Keun‐Ho Choi Jong‐Tae Yoo Jeong‐Hun Kim Yong‐Hyeok Lee Sang‐Jin Chun Sang‐Bum Park Don‐Ha Choi Qinglin Wu Sun‐Young Lee Sang‐Young Lee 《Advanced functional materials》2015,25(38):6029-6040
Forthcoming smart energy era is in strong pursuit of full‐fledged rechargeable power sources with reliable electrochemical performances and shape versatility. Here, as a naturally abundant/environmentally friendly cellulose‐mediated cell architecture strategy to address this challenging issue, a new class of hetero‐nanonet (HN) paper batteries based on 1D building blocks of cellulose nanofibrils (CNFs)/multiwall carbon nanotubes (MWNTs) is demonstrated. The HN paper batteries consist of CNF/MWNT‐intermingled heteronets embracing electrode active powders (CM electrodes) and microporous CNF separator membranes. The CNF/MWNT heteronet‐mediated material/structural uniqueness enables the construction of 3D bicontinuous electron/ion transport pathways in the CM electrodes, thus facilitating electrochemical reaction kinetics. Furthermore, the metallic current collectors‐free, CNF/MWNT heteronet architecture allows multiple stacking of CM electrodes in series, eventually leading to user‐tailored, ultrathick (i.e., high‐mass loading) electrodes far beyond those accessible with conventional battery technologies. Notably, the HN battery (multistacked LiNi0.5Mn1.5O4 (cathode)/multistacked graphite (anode)) provides exceptionally high‐energy density (=226 Wh kg?1 per cell at 400 W kg?1 per cell), which surpasses the target value (=200 Wh kg?1 at 400 W kg?1) of long‐range (=300 miles) electric vehicle batteries. In addition, the heteronet‐enabled mechanical compliance of CM electrodes, in combination with readily deformable CNF separators, allows the fabrication of paper crane batteries via origami folding technique. 相似文献
995.
UV‐Triggered Polydopamine Secondary Modification: Fast Deposition and Removal of Metal Nanoparticles
Yi Zeng Xin Du Wei Hou Xiaojiang Liu Cun Zhu Bingbing Gao Liangdong Sun Qiwei Li Junlong Liao Pavel A. Levkin Zhongze Gu 《Advanced functional materials》2019,29(34)
Since the first report in 2007, polydopamine (PDA) coating has shown great potential as a general and versatile method to create functional nanocoatings on arbitrary substrates. Slow kinetics and poor controllability of the coating and secondary modification processes, however, have limited the further development of this attractive method. In this work, it is demonstrated that UV irradiation at 365 nm significantly accelerates the process of secondary modification of a PDA‐coated surface. The kinetics of both thiol and amine modifications of PDA are increased 12‐fold via UV irradiation, while the kinetics of metal ion reduction at the PDA interface is increased more than 550 times. Moreover, it is demonstrated that irradiating a PDA/metal nanoparticle composite surface with UV light at 254 nm leads to dissolution of the deposited metal nanoparticles (MNPs). Finally, grayscale metallic patterns, dynamic deposition, and removal of MNPs on PDA surface are realized with the proposed method. 相似文献
996.
Zhanwei Zhou Yadong Liu Minghua Zhang Chenzi Li Ruoxi Yang Jing Li Chenggen Qian Minjie Sun 《Advanced functional materials》2019,29(39)
Protein‐based theranostic agents (PBTAs) exhibit superior performance in the diagnosis and therapy of cancers. However, the in vivo applications of PBTA are largely limited by undesired accumulation, penetration, or selectivity. Here, an ATP‐supersensitive protein cluster is fabricated for promoting PBTA delivery and enhancing magnetic resonance imaging (MRI)‐guided tumor photothermal therapy. Gd3+‐ and CuS‐coloaded small bovine serum albumin nanoparticles (GdCuB) are synthesized as the model protein with a size of 9 nm and are encapsulated into charge switchable polycations (DEP) to form DEP/GdCuB nanoclusters of 120 nm. In blood circulation, DEP/GdCuB significantly extends the half‐lifetime and thereby enhances the tumor accumulation of GdCuB. When the clusters reach the tumor site, the extracellular adenosine triphosphate (ATP) can effectively trigger the release of GdCuB, resulting in tumoral deep penetration as well as the activation of T1‐weighted MRI (r1 value switched from 2.8 × 10?3 to 11.8 × 10?3 m ?1 s?1). Furthermore, this delivery strategy also improves the tumoral photothermal therapy efficacy with the MRI‐guided therapy. The study of ATP‐activated nanoclusters develops a novel strategy for tumor deep penetration and on/off imaging of PBTA by size switchable technology, and reveals the potential for MRI‐guided therapy of cancers. 相似文献
997.
Fog radio access network (F‐RAN) architectures provide markedly improved performance compared to conventional approaches. In this paper, an efficient genetic algorithm‐based content distribution scheme is proposed that improves the throughput and reduces the transmission delay of a F‐RAN. First, an F‐RAN system model is presented that includes a certain number of randomly distributed fog access points (F‐APs) that cache popular content from cloud and other sources. Second, the problem of efficient content distribution in F‐RANs is described. Third, the details of the proposed optimal genetic algorithm‐based content distribution scheme are presented. Finally, simulation results are presented that show the performance of the proposed algorithm rapidly approaches the optimal throughput. When compared with the performance of existing random and exhaustive algorithms, that of the proposed method is demonstrably superior. 相似文献
998.
混合pin/肖特基(MPS)二极管是广泛应用于电子电路中的快恢复功率器件,具有高击穿电压、快速开关和正向电流大等特性。对MPS二极管漂移区的少数载流子的特性进行了仿真分析。仿真结果表明,MPS二极管的p^+区向漂移区注入的少数载流子浓度随外加正向电压和pn结面积占元胞总面积比例的增大而增大。虽然漂移区的少数载流子改变了MPS二极管的工作模式,增大了电流,但是存储在漂移区的少数载流子增大了反向峰值电流和恢复时间,进而增大了功耗并降低了关断速度。折中考虑正向电流和反向恢复特性,可获得具有正向电流大、反向峰值电流小和反向恢复时间短的MPS二极管。 相似文献
999.
To progressively provide the competitive rate-distortion performance for aerial imagery,a quantized block compressive sensing(QBCS) framework is presented,which incorporates two measurement-side control parameters:measurement subrate(S) and quantization depth(D).By learning how different parameter combinations may affect the quality-bitrate characteristics of aerial images,two parameter allocation models are derived between a bitrate budget and its appropriate parameters.Based on the corresponding allocation models,a model-guided image coding method is proposed to pre-determine the appropriate(S,D) combination for acquiring an aerial image via QBCS.The data-driven experimental results show that the proposed method can achieve near-optimal quality-bitrate performance under the QBCS framework. 相似文献
1000.
Xiaowu He Yifeng Song Ying Yu Ben Ma Zesheng Chen Xiangjun Shang Haiqiao Ni Baoquan Sun Xiuming Dou Hao Chen Hongyue Hao Tongtong Qi Shushan Huang Hanqing Liu Xiangbin Su Xinliang Su Yujun Shi Zhichuan Niu 《半导体学报》2019,40(7):27-37
A brief introduction of semiconductor self-assembled quantum dots (QDs) applied in single-photon sources is given. Single QDs in confined quantum optical microcavity systems are reviewed along with their optical properties and coupling characteristics. Subsequently, the recent progresses in In(Ga)As QDs systems are summarized including the preparation of quantum light sources, multiple methods for embedding single QDs into different microcavities and the scalability of single-photon emitting wavelength. Particularly, several In(Ga)As QD single-photon devices are surveyed including In(Ga)As QDs coupling with nanowires, InAs QDs coupling with distributed Bragg reflection microcavity and the In(Ga)As QDs coupling with micropillar microcavities. Furthermore, applications in the field of single QDs technology are illustrated, such as the entangled photon emission by spontaneous parametric down conversion, the single-photon quantum storage, the chip preparation of single-photon sources as well as the single-photon resonance-fluorescence measurements. 相似文献