High efficiency red phosphorescent organic light-emitting diodes using a spirobenzofluorene type phosphine oxide as a host material

High efficiency red phosphorescent organic light-emitting diodes have been developed using a spirobenzofluorene type phosphine oxide (SPPO2) as a host material. The SPPO2 had a high glass transition temperature of 119 °C and a smooth surface morphology with a surface roughness less than 1 nm. The red device with the SPPO2 as a host showed a quantum efficiency of 14.3% with a current efficiency of 20.4 cd/A.     

Scheduling sensor activity for information coverage of discrete targets in sensor networks

In this paper, we study the problem of scheduling sensor activity to cover a set of targets with known locations such that all targets can be monitored all the time and the network can operate as long as possible. A solution to this scheduling problem is to partition all sensors into some sensor covers such that each cover can monitor all targets and the covers are activated sequentially. In this paper, we propose to provide information coverage instead of the conventional sensing disk coverage for target. The notion of information coverage is based on estimation theory to exploit the collaborative nature of geographically distributed sensors. Due to the use of information coverage, a target that is not within the sensing disk of any single sensor can still be considered to be monitored (information covered) by the cooperation of more than one sensor. This change of the problem settings complicates the solutions compared to that by using a disk coverage model. We first define the target information coverage (TIC) problem and prove its NP‐completeness. We then propose a heuristic to approximately solve our problem. Simulation results show that our heuristic is better than an existing algorithm and is close to the upper bound when only the sensing disk coverage model is used. Furthermore, simulation results also show that the network lifetime can be significantly improved by using the notion of information coverage compared with that by using the conventional definition of sensing disk coverage. Copyright © 2008 John Wiley & Sons, Ltd.     

Room-Temperature-Processable Highly Reliable Resistive Switching Memory with Reconfigurability for Neuromorphic Computing and Ultrasonic Tissue Classification

Reversible metal-filamentary mechanism has been widely investigated to design an analog resistive switching memory (RSM) for neuromorphic hardware-implementation. However, uncontrollable filament-formation, inducing its reliability issues, has been a fundamental challenge. Here, an analog RSM with 3D ion transport channels that can provide unprecedentedly high reliability and robustness is demonstrated. This architecture is realized by a laser-assisted photo-thermochemical process, compatible with the back-end-of-line process and even applicable to a flexible format. These superior characteristics also lead to the proposal of a practical adaptive learning rule for hardware neural networks that can significantly simplify the voltage pulse application methodology even with high computing accuracy. A neural network, which can perform the biological tissue classification task using the ultrasound signals, is designed, and the simulation results confirm that this practical adaptive learning rule is efficient enough to classify these weak and complicated signals with high accuracy (97%). Furthermore, the proposed RSM can work as a diffusive-memristor at the opposite voltage polarity, exhibiting extremely stable threshold switching characteristics. In this mode, several crucial operations in biological nervous systems, such as Ca²⁺ dynamics and nonlinear integrate-and-fire functions of neurons, are successfully emulated. This reconfigurability is also exceedingly beneficial for decreasing the complexity of systems—requiring both drift- and diffusive-memristors.     

级联布喇格声光互作用的频移与光束偏转分析

声光器件在设计和制作中,由于器件结构和功能上的需要,常采用级联形式的声光互作用。根据声光互作用的一般理论,对不同的声光互作用条件下,级联布喇格声光互作用的频移和光束偏转进行了分析。当组合两次不同的声光互作用,可以得到不同的频移和光束偏转。并指出,通过调节两声波的频率,可以使输出光波的传播方向不随声波频率的改变而变化。     

An efficient implementation of surface impedance boundaryconditions for the finite-difference time-domain method

An efficient way to implement the surface impedance boundary conditions (SIBC) for the finite-difference time-domain (FDTD) method is presented in this paper. Surface impedance boundary conditions are first formulated for a lossy dielectric half-space in the frequency domain. The impedance function of a lossy medium is approximated with a series of first-order rational functions. Then, the resulting time-domain convolution integrals are computed using recursive formulas which are obtained by assuming that the fields are piecewise linear in time. Thus, the recursive formulas derived here are second-order accurate. Unlike a previously published method [7] which requires preprocessing to compute the exponential approximation prior to the FDTD simulation, the preprocessing time is eliminated by performing a rational approximation on the normalized frequency-domain impedance. This approximation is independent of material properties, and the results are tabulated for reference. The implementation of the SIBC for a PEC-backed lossy dielectric shell is also introduced     

A Temperature‐Controllable Microelectrode and Its Application to Protein Immobilization

This letter presents a smart integrated microfluidic device which can be applied to actively immobilize proteins on demand. The active component in the device is a temperature‐controllable microelectrode array with a smart polymer film, poly(N‐isopropylacrylamide) (PNIPAAm) which can be thermally switched between hydrophilic and hydrophobic states. It is integrated into a micro hot diaphragm having an integrated micro heater and temperature sensors on a 2‐micrometer‐thick silicon oxide/silicon nitride/silicon oxide (O/N/O) template. Only 36 mW is required to heat the large template area of 2 mm×16 mm to 40°C within 1 second. To relay the stimulus‐response activity to the microelectrode surface, the interface is modified with a smart polymer. For a model biomolecular affinity test, an anti‐6‐(2, 4‐dinitrophenyl) aminohexanoic acid (DNP) antibody protein immobilization on the microelectrodes is demonstrated by fluorescence patterns.     

Dopamine: Just the Right Medicine for Membranes

Mussel‐inspired chemistry has attracted widespread interest in membrane science and technology. Demonstrating the rapid growth of this field over the past several years, substantial progress has been achieved in both mussel‐inspired chemistry and membrane surface engineering based on mussel‐inspired coatings. At this stage, it is valuable to summarize the most recent and distinctive developments, as well as to frame the challenges and opportunities remaining in this field. In this review, recent advances in rapid and controllable deposition of mussel‐inspired coatings, dopamine‐assisted codeposition technology, and photoinitiated grafting directly on mussel‐inspired coatings are presented. Some of these technologies have not yet been employed directly in membrane science. Beyond discussing advances in conventional membrane processes, emerging applications of mussel‐inspired coatings in membranes are discussed, including as a skin layer in nanofiltration, interlayer in metal‐organic framework based membranes, hydrophilic layer in Janus membranes, and protective layer in catalytic membranes. Finally, some critical unsolved challenges are raised in this field and some potential pathways are proposed to address them.     

Nonfullerene Electron Transporting Material Based on Naphthalene Diimide Small Molecule for Highly Stable Perovskite Solar Cells with Efficiency Exceeding 20%

This study reports a new nonfullerene electron transporting material (ETM) based on naphthalene diimide (NDI) small molecules for use in high‐performance perovskite solar cells (PSCs). These solar cells simultaneously achieve high power conversion efficiency (PCE) of over 20% and long‐term stability. New NDI‐ID (N,N′‐Bis(1‐indanyl)naphthalene‐1,4,5,8‐tetracarboxylic diimide) consisting of an N‐substituted indane group having simultaneous alicyclic and aromatic characteristics is synthesized by a low‐cost, one‐step reaction, and facile purification method. The partially flexible characteristics of an alicyclic cyclopentene group on indane groups open the possibility of low‐temperature solution processing. The conformational rigidity and aromaticity of phenyl and alicyclic groups contribute to high temporal stability by strong secondary bonds. NDI‐ID has herringbone packed semiconducting NDI cores that exhibit up to 0.2 cm² V^?1 s^?1 electron mobility in field effect transistors. The inverted PSCs based on CH(NH₂)₂PbI_3–xBr_x with NDI‐ID ETM exhibit very high PCEs of up to 20.2%, which is better than that of widely used PCBM (phenyl‐C61‐butyric acid methyl ester) ETM‐based PSCs. Moreover, NDI‐ID‐based PSCs exhibit very high long‐term temporal stability, retaining 90% of the initial PCE after 500 h at 100 °C with 1 sun illumination without encapsulation. Therefore, NDI‐ID is a promising ETM for highly efficient, stable PSCs.     

Improving Radio Frequency Transmission Properties of Graphene via Carrier Concentration Control toward High Frequency Transmission Line Applications

Graphene has been gradually studied as a high‐frequency transmission line material owing to high carrier mobility with frequency independence up to a few THz. However, the graphene‐based transmission lines have poor conductivity due to their low carrier concentration. Here, it is observed that the radio frequency (RF) transmission performance could be severely hampered by the defect‐induced scattering, even though the carrier concentration is increased. As a possible solution, the deposition of the amorphous carbon on the graphene is studied in the high‐frequency region up to 110 GHz. The DC resistance is reduced by as much as 60%, and the RF transmission property is also enhanced by 3 dB. Also, the amorphous carbon covered graphene shows stable performance under a harsh environment. These results prove that the carrier concentration control is an effective and a facile method to improve the transmission performance of graphene. It opens up the possibilities of using graphene as interconnects in the ultrahigh‐frequency region.