用于纤维材料表面耐磨涂层的制备与性能表征

为使涤纶织物应用范围更广,更耐磨,本文制备了一种有机硅树脂基纳米硼化钛碳化钛复合涂层,通过正交实验法得到最佳的涂层方案,并尝试将其应用于涤纶织物,以改善涤纶织物的表面结构,进而实现涤纶织物表面优异的耐磨性能.为测试涂层对涤纶织物性能的影响, 采用泰伯式耐磨仪、液滴形状分析仪、电子织物强力机、扫描电子显微镜(SEM)研究了涂层织物的耐磨性能、疏水性能、物理机械性能和磨损织物的表面微观形态.研究表明：当有机硅树脂与无水乙醇质量比为75: 25,含量(质量分数)为93%;超分散剂含量为1.5%;乙醇增稠剂含量为1.5%;纳米硼化钛和碳化钛质量比为2: 1,含量为4%时,所得涂层溶液应用于涤纶织物后会形成一层包覆层,耐磨性能最优.对于涂覆量为15 g/m²的涤纶,拉伸断裂强力由573.92 N提高到620.48 N,顶破强力由652.34 N提高到790.07 N,撕裂强力由9.87 N降低到5.78 N,疏水性能有较大提高,接触角可达到120°以上.     

在盐湖地区暴露48个月纯锌的腐蚀行为

采用X射线衍射(XRD)、扫描电子显微镜(SEM)、金相显微镜和电化学阻抗等手段研究了锌在青海盐湖大气环境(富盐干旱型大气环境)中的腐蚀行为。结果表明,在青海盐湖大气环境中锌的腐蚀规律遵循经验公式m=Atn。锌的向地面比向天面腐蚀严重,向天面暴晒48个月出现锈层脱落现象。两个表面的腐蚀产物均由Zn5(OH)8Cl2·H2O,Zn5(CO)3(OH)6和Zn4SO4(OH)6·3H2O组成,锈层均富含SiO2。电化学结果表明,随着暴晒时间的延长向地面的极化电阻Rp逐渐增大,而向天面的Rp逐渐增加,而暴晒48个月时减小。锈层有抑制基体腐蚀的作用,对两个表面锈层的保护性随暴晒时间的延长而增大,而向天面暴晒48个月时保护性减弱。     

Aggregation of silver nanoplates in the presence of L‐cysteine and the application for separation

A facile method was investigated to fabricate the aggregated silver nanoplates as products for separation materials. Initially, ageing of L‐cysteine capped silver nanoplates in ethanol solvent led to fast aggregation. Then, the as‐formed aggregates were easily prepared as powder due to the highly volatile properties of ethanol. Interestingly, the aggregated powder would be soluble again after the dispersion in water and the re‐dispersed nanoplates could be obtained. Furthermore, the heavy metal ions such as Cu²⁺, Pb²⁺ and Hg²⁺ would soon accelerate the aggregation of the dispersed silver nanoplates again. The reversible aggregation process could be employed for separation applications in the future.Inspec keywords: silver, nanoparticles, aggregation, nanofabrication, organic compounds, separation, dissolving, copper, lead, mercury (metal)Other keywords: aggregation, L‐cysteine, separation materials, ageing, L‐cysteine capped silver nanoplates, ethanol solvent, aggregated powder, heavy metal ions, Ag, Cu, Pb, Hg     

Synthesis of ultrathin semicircle-shaped copper nanowires in ethanol solution for low haze flexible transparent conductors

Nano Research - Copper nanowires (CuNWs) are becoming an indispensable item for next-generation transparent optical devices due to their excellent conductivity and transparency. In this work,...     

Aggregation-induced emission luminogen-assisted stimulated emission depletion nanoscopy for super-resolution mitochondrial visualization in live cells

Nano Research - Aggregation-induced emission luminogens (AIEgens) are fluorescent agents that are ideal for bioimaging and have been widely used for organelle targeting, cellular mapping, and...     

直升机超临界尾传动轴限幅减振器非线性动力学特性研究

直升机超临界尾传动轴在跨临界转速时会产生剧烈的振动。限幅减振器是专门针对尾传动轴跨临界减振问题设计的一种复合式减振器。限幅减振器与尾传动轴组成的系统具有摩擦、碰撞等强非线性特征,动力学特性异常复杂。为揭示限幅减振器工作机理并指导减振器设计,建立了具有双间隙结构的限幅减振器与尾传动轴系统的弹簧-质量-阻尼等效模型。分别基于直接时间域积分和时频变换谐波平衡（Harmonic Balance Method with Alternating Frequency-Time Domain Technique）+数值延拓（Numerical Continuation）两种方法对控制方程进行了求解。计算结果表明,限幅减振器存在无作用、正常减振、异常减振、限位四种工作状态。其中,限位状态是针对故障工况下尾传动轴进行的临时限位保护。此外,进一步研究了减振器参数对减振和限位效果的影响,得到了传动轴与碰摩环之间间隙、碰撞刚度以及临界摩擦力对限幅减振器减振效果的影响规律。发现存在最优临界摩擦力,且最优临界摩擦力与传动轴不平衡量等有关。同时限位状态下,通过增加碰摩环与底座之间的碰撞刚度可以减小限位幅值,但也会产生...     

沙漠砂混凝土框架节点抗震性能试验研究

为研究古尔班通古特沙漠砂混凝土框架节点的抗震性能,对 9 个缩尺比为 1/2 的框架节点进行了拟静力试验研究,研究了沙漠砂替代率、轴压比和配箍率对节点破坏模式、耗能能力、延性、刚度和恢复力模型的影响。研究结果表明：沙漠砂替代率由 0% 逐渐增加到 80% 时,试件的破坏现象、骨架曲线、耗能、刚度退化主要受沙漠砂混凝土的强度和应力?应变关系影响,延性逐渐降低,且沙漠砂替代率为 80% 的构件其延性较首个试件降低了 11.48%;轴压比由 0.2 逐渐增加到 0.6 时,峰值荷载提高约 3%,延性降低约 5%,等效黏滞阻尼系数增加约 18%,刚度退化程度增加;配箍率由 0.50% 逐渐增加到 2.52% 时,峰值荷载提高近 10%,延性提高约 6%,等效黏滞阻尼系数增加约25%,刚度退化减缓。整体而言,沙漠砂混凝土框架节点的抗震性能与普通混凝土试件相似。建立了沙漠砂混凝土框架节点的三折线恢复力模型,且计算模型与试验结果吻合良好。     

Regulation of Polymer Configurations Enables Green Solvent-Processed Large-Area Binary All-Polymer Solar Cells With Breakthrough Performance and High Efficiency Stretchability Factor

With the great potential of the all-polymer solar cells for large-area wearable devices, both large-area device efficiency and mechanical flexibility are very critical but attract limited attention. In this work, from the perspective of the polymer configurations, two types of terpolymer acceptors PYTX-A and PYTX-B (X = Cl or H) are developed. The configuration difference caused by the replacement of non-conjugated units results in distinct photovoltaic performance and mechanical flexibility. Benefiting from a good match between the intrinsically slow film-forming of the active materials and the technically slow film-forming of the blade-coating process, the toluene-processed large-area (1.21 cm²) binary device achieves a record efficiency of 14.70%. More importantly, a new parameter of efficiency stretchability factor (ESF) is proposed for the first time to comprehensively evaluate the overall device performance. PM6:PYTCl-A and PM6:PYTCl-B yield significantly higher ESF than PM6:PY-IT. Further blending with non-conjugated polymer donor PM6-A, the best ESF of 3.12% is achieved for PM6-A:PYTCl-A, which is among the highest comprehensive performances.     

The Garden of Forking Paths – Forms of Scholarship and the ‘Formations’ Pre-Prints System for Cultural Studies and Related Fields

This paper describes and analyses a web-based pre-prints project in the UK's Electronic Libraries Programme in order to raise issues about the forms of scholarship that are best suited to online working. Specifically, the paper describes some of the underlying processes at work in academic research and seeks to match these, where appropriate, to forms of online working. In doing so, the paper describes in detail a scholarship of integration which seems well suited to online tools such as pre-prints systems, but speculates that such forms of scholarship are too seldom explicitly identified when academics refer to research as a totality. As a consequence the potential match between working practices and emerging tools may not be obvious to academic researchers. To investigate these issues further, the paper examines the degrees of formality involved in different kinds of online communication and describes how academic working practices might be supported by adapting established groupware tools such as Lotus Notes. The eLib Formations project, which is using Notes to develop an integrated pre-prints and e-journal system for research in cultural studies and related fields, is described in detail, focusing on the underlying technology and the overall design.