High Temperature Oxidation Behavior of Conventional and Nb-Modified MAR-M246 Ni-Based Superalloy

The present investigations focused on the thermal oxidation of two variants of MAR-M246 alloy having the same contents of Ta and Nb in at. pct, considering the effects of total replacement of Ta by Nb. The alloys were produced by investment casting using high purity elements in induction furnace under vacuum atmosphere. The alloys were oxidized pseudo-isothermally at 800 °C, 900 °C and 1000 °C up to 1000 hours under lab air. Protective oxidation products growing on the surface of the oxidized samples were mainly Al₂O₃, Cr₂O₃. Other less protective oxide such as spinels (NiCr₂O₄ and CoCr₂O₄) and TiO₂ were also detected as oxidation products. The conventional alloy exhibited slight internal oxidation at 800 °C and an enhanced resistance at 900 °C and 1000 °C. The Nb-modified alloy presented an exacerbated internal oxidation and nitridation at 900 °C and 1000 °C and an enhanced resistance at 800 °C. At 1000 °C, Nb-modified alloy was particularly affected by excessive spalling as the main damage mechanisms. From a kinetic point of view, both alloys exhibit the same behavior at 800 °C and 900 °C, with k_p values typical of alumina forming alloys (2 × 10⁻¹⁴ to 3.6 × 10⁻¹³ g² cm⁻⁴ s⁻¹). However, Ta modified alloys exhibited superior oxidation resistance at 1000 °C when compared to the Nb modified alloy due to better adherence of the protective oxide scale.

     

Accelerated Design of Eutectic High Entropy Alloys by ICME Approach

Eutectic high entropy alloy with seven components is designed based on the integrated computational materials engineering (ICME) framework. The framework includes thermodynamic prediction using calculation of phase diagrams (CALPHAD), microstructure simulation using phase-field method, and experimental validation. The designed alloy shows the eutectic structure consisting of FCC and laves phase in the composition range from 8.25 to 10 at. pct Ta. The simulation and experimental results are co-related and a framework is proposed that can be used for high entropy alloy design subjected to various manufacturing processes.

     

Power Supply at Metallurgical Iron-and-Steel Works: Features and Development Prospects

Metallurgist - The article provides a brief assessment of the current state of power supply units at metallurgical plants and prospects for their future development. The principal power-supply...     

Remelting of Iron Shavings with the Synergistic Effect of Minimum Metal Loss

Metallurgist - The well-known technologies of remelting iron shavings lead to significant (30%) losses of metal. An electroslag smelting furnace with graphite electrodes is proposed for remelting...     

Combustion in Ni–Al System with Cu Additive (Powder or Rod). Experiment and Mathematical Model

Russian Journal of Non-Ferrous Metals - Experimental studies have been carried out with theoretical calculations of wave synthesis in the Ni–Al–Cu system using a mathematical model....     

A multi-objective model for seasonal personnel reassignment

The focus of this research was the development of a model to address the problem of reassigning summer construction workers to winter snow and ice removal teams in an efficient and cost-effective manner. The model is a multi-objective integer program that can generate the complete and precise trade-off curve between the objectives of minimizing total distance that the reassigned workforce must travel from their respective homes to one of many site locations, and minimizing the maximum distance that any one worker must travel. System constraints include demand requirements for workers at each site and the limited availability of state-owned vehicles that may be issued to workers assigned to remote sites. Details of the model structure and solution procedure are presented together with the results of an actual application.