基于主成分分析的串联电池组故障诊断实用方法

为了保证电动汽车和储能系统的安全运行,电池组的故障诊断研究备受关注。针对目前面向电池组故障诊断方法相对匮乏且实用性不佳的问题,提出了一种基于主成分分析(PCA)的故障诊断实用方法,以准确地区分组内的电池单体故障和连接故障。首先,提出了非硬件冗余的交叉测量拓扑,分别用不同数量的传感器测量电池和连接板;然后,分析组内测量电压的变化特点,引入PCA对故障特征进行提取,为了保证PCA模型适配,提出了PCA实时建模与故障诊断一体化的思路,并基于此设计了完整的故障诊断方案;最后,利用实验对所提方法进行验证,结果表明所提方法能够可靠区分电池单体故障和连接故障,准确检测阈值法无法检测的电池单体故障,且强鲁棒于荷电状态、健康状态和温度差异的影响。现场运行数据也证实了所提方法能够有效避免发生虚警。     

一种基于无线射频通讯的共享雨伞系统

目前,以资源优化可利用和绿色出行为理念的共享经济蓬勃发展,基于此,本发明针对用户遇到突发性降雨天气时对雨伞临时需求,本文设计并实现了一款共享雨伞。本设计发明设计一类伞上装有电子标签的雨伞及雨伞借还系统,使用射频识别技术读取电子标签,使用Java技术编写微信小程序,利用STM32单片机控制伞桩的内部运行,便捷用户突遇突发性天气时及时满足用户对伞的需求,还提高社会资源的利用率。     

An improved Henry gas solubility optimization for optimization tasks

Applied Intelligence - The henry gas solubility optimization (HGSO) is a new nature-inspired algorithm that mimics Henry Gas Solubility to solve global optimization problems. The main changes of...     

一种抗背景干扰的多尺度人群计数算法

人群计数技术以估计人群图片或视频中的人数为目标,可以有效预防人群踩踏事故的发生,广泛应用于安防预警、城市规划及大型集会管理等领域。然而,由于人群尺度变化、背景干扰、人群分布不均、遮挡和透视效应等因素的影响,单幅图片的人群计数仍是一项非常具有挑战性的任务。针对人群计数中多尺度变化和背景干扰问题,提出一种抗背景干扰的多尺度人群计数算法。以VGG16网络结构为基础,引入特征金字塔构建多尺度特征融合骨干网络解决人群多尺度变化问题,设计Double-Head-CC结构对融合后的特征图进行前景背景分割和密度图预测以抑制背景干扰。基于密度图的局部相关性和多任务学习,定义多重损失函数和多任务联合损失函数进行网络优化。在ShanghaiTech、UCF-QNRF和JHU-CROWD++数据集上进行训练和评测,实验结果表明,该算法能够很好地预测人群密度分布和人群数量,具有较高的准确性,且鲁棒性强、泛化性能良好。     

Evolution of the structure and mechanical properties of a FeNi alloy during annealing after megaplastic deformation

Evolution of the structure and mechanical properties of a FeNi alloy annealed after megaplastic deformation (MPD) at room temperature in the Bridgman chamber has been studied by the transmission electron microscopy, electron backscatter diffraction, and microhardness measurement techniques. It is established that the primary recrystallization process during annealing is accompanied by growth of the recrystallized grains formed at the preliminary MPD stage. At the same time, the deformation fragments cannot grow because of the extremely low mobility of their boundaries.

     

Insights into the Influence of Work Functions of Cathodes on Efficiencies of Perovskite Solar Cells

Though various efforts on modification of electrodes are still undertaken to improve the efficiency of perovskite solar cells, attributing to the large scope of these methods, it is of significance to unveil the working principle systematically. Herein, inverted perovskite solar cells based on indium tin oxide (ITO)/poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS)/CH₃NH₃PbI₃/phenyl‐C61‐butyric acid methyl ester (PC₆₁ BM)/buffer metal/Al are constructed. Through the choice of different buffer metals to tune work function of the cathode, the contact nature of the active layer with the cathode could be manipulated well. In comparison with the device using Au/Al as the electrode that shows an unfavorable band bending for conducting the excited electrons to the cathode, the one with Ca/Al presents a dramatically improved efficiency over 17.1%, ascribed to the favorable band bending at the interface of the cathode with the active layer. Details for tuning the band bending and the corresponding charge transfer mechanism are given in a systematic manner. Thus, a general guideline for constructing perovskite photovoltaic devices efficiently is provided.     

Retracted: Dual Effects of Nanostructuring and Oxygen Vacancy on Photoelectrochemical Water Oxidation Activity of Superstructured and Defective Hematite Nanorods

An Ar atmospheric treatment is rationally used to etch and activate hematite nanoflakes (NFs) as photoanodes toward enhanced photoelectrochemical water oxidation. The formation of a highly ordered hematite nanorods (NRs) array containing a high density of oxygen vacancy is successfully prepared through in situ reduction of NFs in Ar atmosphere. Furthermore, a hematite (104) plane and an iron suboxide layer at the absorber/back‐contact interface are formed. The material defects produced by a thermal oxidation method can be critical for the morphology transformation from 2D NFs to 1D NRs. The resulting hematite NR photoanodes show high efficiency toward solar water splitting with improved light harvesting capabilities, leading to an enhanced photoresponse due to the artificially formed oxygen vacancies.     

In-situ synthesis of TiO2 nanostructures on Ti foil for enhanced and stable photocatalytic performance

TiO_2 nanostructures with strong interfacial adhesion and diverse morphologies have been in-situ grown on Ti foil substrate through a multiple-step method based on conventional plasma electrolytic oxidation(PEO) technology, hydrothermal reaction and ion exchange process. The PEO process is critical to the formation of TiO_2 seeding layer for the nucleation of Na_2Ti_3O_7 and H_2Ti_3O_7 mediates that are strongly attached to the Ti foil. An ion exchange reaction can finally lead to the formation of H_2Ti_3O_7 nanostructures with diverse morphologies and the calcination process can turn the H_2Ti_3O_7 nanostructures into TiO_2 nanostructures with enhanced crystallinity. The morphology of the TiO_2 nanostructures including nanoparticles(NP), nanowhiskers(NWK), nanowires(NW) and nanosheets(NS) can be easily tailored by controlling the NaOH concentration and reaction time during hydrothermal process. The morphology, composition and optical properties of TiO_2 photocatalysts were analyzed using scanning electron microscope(SEM), X-ray diffraction(XRD), photoluminescence(PL) spectroscopy and UV–vis absorption spectrum. Photocatalytic tests indicate that the TiO_2 nanosheets calcined at 500?C show good crystallization and the best capability of decomposing organic pollutants. The decoration of Ag cocatalyst can further improve the photocatalytic performance of the TiO_2 nanosheets as a result of the enhanced charger separation efficiency. Cyclic photocatalytic test using TiO_2 nanostructures grown on Ti foil substrate demonstrates the superior stability in the photodegradation of organic pollutant, suggesting the promising potential of in-situ growth technology for industrial application.     

Effects of redox-active interlayer anions on the oxygen evolution reactivity of NiFe-layered double hydroxide nanosheets

Nickel-iron layered double hydroxide (NiFe-LDH) nanosheets have shown optimal oxygen evolution reaction (OER) performance; however, the role of the intercalated ions in the OER activity remains unclear. In this work, we show that the activity of the NiFe-LDHs can be tailored by the intercalated anions with different redox potentials. The intercalation of anions with low redox potential (high reducing ability), such as hypophosphites, leads to NiFe-LDHs with low OER overpotential of 240 mV and a small Tafel slope of 36.9 mV/dec, whereas NiFe-LDHs intercalated with anions of high redox potential (low reducing ability), such as fluorion, show a high overpotential of 370 mV and a Tafel slope of 80.8 mV/dec. The OER activity shows a surprising linear correlation with the standard redox potential. Density functional theory calculations and X-ray photoelectron spectroscopy analysis indicate that the intercalated anions alter the electronic structure of metal atoms which exposed at the surface. Anions with low standard redox potential and strong reducing ability transfer more electrons to the hydroxide layers. This increases the electron density of the surface metal sites and stabilizes their high-valence states, whose formation is known as the critical step prior to the OER process.

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