Polarographic Study of Thio-acetic Acid

The polarographic behaviour of thio-acetic acid (RSH) at dropping mercury electrode (d.m.e.) has been investigated in presence of KNO₃ in the pH range 2–10.5 at 30.0 ± 0.2°C in 50% alcoholic medium at 0.2 M ionic strength. Well defined anodic waves were obtained at all pH values in the concentration range studied. At pH < 2.2 and > 10.5 ill defined anodic waves were obtained. The effect of pH, concentration of RSH, temperature, drop time and alcohol on the wave characteristic and the mechanism of the reaction occurring at the surface of the mercury drop have been studied in detail. A small prewave was also observed at pH 9.1 and 10.5, which has been assigned adsorption characteristics. The reversibility of the reaction mechanism was confirmed by a number of methods. The wave is diffusion controlled and reversible involving one electron transfer process: Mathematical and experimental evidence shows that the anodic wave of RSH at. d.m.e. does not correspond to formation of (RSSR) but to a mercury compound RSHg according to the above equation. The diffusion coefficient and temperature coefficient for (30–45°C) of i_d at pH 4.0 and 9.1 have been found to be 1.698; 1.965 × 10⁻⁶ cm²/sec and 1.08%; 1.20% per degree respectively. The dissociation constant pKa was found to be 4.25 by the plot of E_1/2 vs. pH. The linearity of i_d with RSH concentrations provides a rapid and precise method for the determination of RSH down to 0.2 mM.     

Assessment of Metal Contamination in the Mine Water of the West Bokaro Coalfield,India

This study was carried out in the West Bokaro coalfield area of the Jharkhand state of India to assess water quality for drinking and domestic purposes. Thirty mine water samples were collected from opencast and underground mines, and concentrations of Al, As, Ba, Cr, Cu, Fe, Mn, Ni, Se, and Zn were determined using ICP-MS. Spatial distribution maps were prepared using GIS software so that the quality of the mine water could be easily understood. Metal concentrations were higher in the pre-monsoon season than in the post-monsoon season, irrespective of location, but there were more significant seasonal variations in the opencast mine water than in the underground mine water. The concentrations of Al, Ba, Fe, Mn, and Ni exceeded the desirable as well as the permissible drinking water limits in both seasons. The quality of the surface water as well as the groundwater in the region may be adversely affected by the high metal concentrations in this mine water.     

Shared hardware,high throughput implementation of 2D 4 × 4 and 8 × 8 integer transform for H.264/AVC high-profile coders

Two-dimensional discrete cosine transforms are used in the core transformations in all profiles of the H.264/Advanced video coding (AVC) standard. In this paper, implementing the resource sharing of high throughput 4 × 4 and 8 × 8 forward and inverse integer transforms for high definition H.264 is presented. It is shown that the 4 × 4 forward/inverse transform can be obtained from 8 × 8 forward/inverse transform using selective data input and data arrangement at intermediate stages. Fast 8 × 8 forward and inverse transform is implemented using matrix decomposition and matrix operation such as Kronecker product and direct sum. The proposed implementation does not require any transpose memory and has a dual clocked pipeline structure. Compared with existing designs, the gate count is reduced by 27.7% in the proposed design. The maximum operating frequency of the proposed system is approx. 1.3 GHz, while the throughput is 7 G and 18.7 G pixels/s for 4 × 4 and 8 × 8 forward integer transforms, respectively. The proposed design can be used for real time H.264/AVC high definition processing owing to its high throughput and low hardware cost.     

Molecular mobility in a homologous series of amorphous solid glucose oligomers

The molecular mobility of amorphous solid biomaterials influences the stability of dried foods and pharmaceuticals, the viability of seeds and spores, and the desiccation-tolerance of organisms during anhydrobiosis. Current understanding of how structure correlates with molecular mobility in the glassy state is inadequate. We used phosphorescence from vanillin dispersed in amorphous films to study the effect of temperature on molecular mobility in the homologous series of oligosaccharides glucose, maltose, maltotriose, maltotetraose, maltopentaose, maltohexaose, and maltoheptaose. Phosphorescence emission spectra and intensity decays were collected from −10 to as high as 130 °C. Emission peak energy, a measure of the extent of dipolar relaxation around the excited state prior to emission, decreased monotonically with temperature, decreasing more significantly in the glassy state in larger sugars (higher degree of polymerisation). The intensity decays were well fitted with sums of either four (glucose, maltose, maltotriose) or three exponentials (maltotetraose, maltopentaose, maltohexaose, maltoheptaose); fit lifetimes at each temperature varied over nearly two orders of magnitude, suggesting a comparable range in matrix dynamic heterogeneity. The lifetimes decreased monotonically with temperature, while the lifetime amplitudes favoured the long lifetime components at lower and short lifetime components at higher temperatures near T_g. Arrhenius analysis indicated that the rate of non-radiative decay, which reflects coupling of probe vibrations with matrix motions and thus provides an estimate of the matrix molecular mobility, increased with molecular size in the glassy state. Both apparent activation energy and activation entropy increased systematically with temperature in all sugars. These data provide additional evidence that the rate and extent of molecular mobility in glassy state carbohydrates is higher in sugars of greater molecular size (mass) and thus higher glass transition temperature and provides additional insight into the molecular dynamics of the glassy state in carbohydrates.     

Electrospinning pure protein solutions in core–shell fibers

Electrospinning of protein‐loaded fibers faces many challenges, e.g. burst release owing to segregation of the protein on the fiber surface, loss of activity due to electrospinning conditions, limitation of loading capacity etc. Core–shell electrospinning provides an effective way to electrospin fibers wherein the core can be loaded with bioactive molecules in friendly conditions of a compatible polymer solution, thereby protecting the molecules from the electrostatic field and organic solvent of shell solutions. The shell polymer, after the electrospinning, acts as a barrier to control the release of the loaded molecules. However, the limitation of loading capacity still remains due the prerequisite of using an additional polymer as additive to achieve the minimum viscosity of the core solution required for viscous drag by the shell solution being drawn by the electrostatic force. The work reported here aims to alleviate the need of a polymer additive by using aqueous protein solutions of very high concentration. High concentrations of protein solutions were successfully electrospun as the core of the protein–poly(lactide‐co‐glycolic acid) core–shell fibers. A partitioning effect was seen in the controlled release of hydrophilic proteins as they were retained in the aqueous core for longer times. Using lysozyme as a model protein, it was shown that the activity is significantly retained after electrospinning, compared with electrospinning in monolithic fibers. Moreover, the lysozyme activity was also comparable with the lysozyme released from core–shell fibers spun using poly(vinyl acetate) as additive in the core. Copyright © 2012 Society of Chemical Industry     

Impulse Pressure Assisted Diffusion Bonding of Low Carbon Steel Using Silver Interlayer

In the present study, impulse pressure assisted diffusion bonding of low carbon steel was carried out using silver interlayer. To study the influence of input process parameters namely bonding temperature (T), maximum pulse pressure (P), and number of pulses (N), experiments of diffusion bonding were conducted according to the Taguchi L9 orthogonal array. To reveal the typical bond interface characteristics, selected samples were examined by scanning electron microscopy (FESEM) equipped with energy dispersive spectroscopy (EDS). The EDS analysis revealed a diffusion affected zone at the interface due to the diffusion of silver and iron across the interface. Lap joints were developed to measure the shear strength of the diffusion bonds. The optimum level of bonding temperature, maximum pulse pressure and number of pulses (875 °C, 10 MPa and 10 pulses) were identified. The ANOVA results indicated that bonding temperature had the highest statistical effect of 66.37% on shear strength followed by number of pulses and maximum pulse pressure. The fracture surface of the lap joints was also examined by FESEM and X-ray diffraction analysis.