Cyclic oxidation response of multiphase niobium-based alloys

Cyclic oxidation tests were performed on multiphase Nb-based alloys containing silicide, Laves, and Nb solid solution phases. In particular, the oxidation resistance of six alloys with various compositions (Nb, Ti, Hf, Cr, Ge, and Si) and microstructures was characterized by thermal cycling from ambient temperature to a peak temperature that ranges from 900 °C to 1400 °C. Weight change data were obtained and the corresponding spalled oxides were collected and identified by X-ray diffraction. The results indicated that Nb-based alloys formed a mixture of CrNbO₄, Nb₂O₅, and Nb₂O₅ · TiO₂, with possibly small amounts of SiO₂ or GeO₂. The oxidation resistance was improved when CrNbO₄ formed instead of Nb₂O₅ and Nb₂O₅ · TiO₂. These results were used to assess the influence of microstructure and composition on the oxidation resistance of multiphase Nb-based alloys.     

Micromechanical approach to damage mechanics of composite materials with fabric tensors

The purpose of this study is to apply continuum damage mechanics – introduced through the concept of fabric tensors – to composite materials within the framework of the theory of elasticity. A directional data model of damage mechanics for composite materials will be developed using fabric tensors. The introduction of fabric tensors into the analysis of damage of composite materials will allow for an enhanced and better understood physical meaning of damage. The micromechanical approach will be used here to relate the damage effect through fabric tensors to the behavior of composite materials. In this approach, damage mechanics is introduced separately to the constituents of the composite material through different constituents’ damage effect tensors. The damaged properties of the composite system as a whole can then be obtained by proper homogenization of the damaged properties of the constituents.

The derivation of a generalized formulation of damage evolution will be shown here in a mathematically consistent manner that is based on sound thermodynamic principles. Numerical examples will be presented to show applicability. In addition, damage evolution for the one-dimensional tension case is also illustrated.     

Thomas Fincke und die <Emphasis Type="Italic">Geometria rotundi</Emphasis>

Thomas Fincke (January 6^th, 1561–April 24^th, 1656), born in Flensburg (Germany), was one of the very most important and significant scientists in Denmark during the seventeenth century, a mathematician and astrologer and physician in the beginning of modern science, a representative of humanism and an influentual academic organizer. He studied in Strasbourg (since 1577) and Padua (since 1583) and received his M.D. in Basel (1587), he practised as a physician throughout his life (since 1587 or 1590) and became a professor at Copenhagen (1591). But he was best known because of his Geometriae rotundi libri XIIII (1583), a famous book on plane and spherical trigonometry, based not on Euclid but on Petrus Ramus. In this influentual work, in which Fincke introduced the terms tangent and secant and probable first noticed the Law of Tangents and the so-called Newton-Oppel-Mauduit-Simpson-Mollweide-Gauss-formula, he showed himself to be „abreast of the mathematics of his time“.      

Fault-aware Communication Mapping for NoCs with Guaranteed Latency

As feature sizes shrink, transient failures of on-chip network links become a critical problem. At the same time, many applications require guarantees on both message arrival probability and response time. We address the problem of transient link failures by means of temporally and spatially redundant transmission of messages, such that designer-imposed message arrival probabilities are guaranteed. Response time minimisation is achieved by a heuristic that statically assigns multiple copies of each message to network links, intelligently combining temporal and spatial redundancy. Concerns regarding energy consumption are addressed in two ways. First, we reduce the total amount of transmitted messages, and, second, we minimise the application response time such that the resulted time slack can be exploited for energy savings through voltage reduction. The advantages of the proposed approach are guaranteed message arrival probability and guaranteed worst case application response time.     

Structure and catalytic properties of dealuminated modified zeolites Y

The effect of treatment with a zirconyl nitrate aqueous solution on the structure; the hydroxyl-layer constitution; and the adsorptive, acid, and catalytic properties of dealuminated zeolite Y was studied. The zeolite was prepared by boiling NH₄Y in an ethylenediaminetetraacetic acid disodium salt solution followed by ion exchange with ammonium chloride and calcination in a 100% steam flow at 750°C. X-ray diffraction, IR spectroscopy, and DTA data show the formation of an ultrastable form of zeolite Y. The incorporation of zirconium in zeolite led to an increase in the proportion of strong acid sites, thus raising the yield of cracking products during n-hexane conversion tested on platinum-containing catalyst samples.     

Structure and Certain Properties of Hot-Pressed Boron Carbide-Based Ceramic with Calcium-Silicon Additive

The influence which the composition of powder mixtures, the treatment conditions which the mixtures are subjected to, and the conditions under which the hot-pressed composite materials B₄C – (5-10 mass%) calcium-silicon are fabricated exert on the structure, nature of failure, and mechanical properties of these materials is investigated. Optimum properties are possessed by material containing 10 mass% of addition. It is shown that the structure, morphology, and dispersivity, as well as the nature of the distribution of the components that are added to the composite material (secondary phase) vary as the temperature of hot pressing changes. Maximal mechanical characteristics of the composite material (σ_bend = 560 MPa, K _1c = 4.7 MPa·m^1/2, HV = 37 GPa) are attained at hot-pressing temperatures in the range 2000-2100°C.     

Copper-zirconium tungstate composites exhibiting low and negative thermal expansion influenced by reinforcement phase transformations

A fully-dense Cu-75 vol pct ZrW₂O₈ metal matrix composite was fabricated by hot isostatic pressing of Cu-coated ZrW₂O₈ particles. A small amount of the high-pressure γ-ZrW₂O₈ phase was created during the cooldown and depressurization following densification; near complete transformation to γ-ZrW₂O₈ was achieved by subsequent cold isostatic pressing. The thermal expansion behavior of the composite between 25°C and 325°C was altered by the cold isostatic pressing treatment, and also depended on the length of time that had passed between thermal cycles. The measured thermal expansion coefficients within specific temperature ranges varied from −6·10⁻⁶ K⁻¹ to far above the thermal expansion coefficient of the copper matrix. The complex temperature-dependent expansion/contraction behavior could be justified by considering the evolution of phase transformations taking place in the ZrW₂O₈ phase, which were observed by in-situ synchrotron X-ray diffraction measurements.