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131.
The demand for sustainable energy sources, like biomass, solar energy, hydro and wind power, is connected to challenges like energy storage and fluctuating energy supply. Regarding the second challenge, industry has to evolve their existing processes from steady state processes to dynamic ones. This work is concerned with the conception of an inline spectroscopy-based optimization routine for chemical reactions under dynamic process conditions, which implements the search for a well applicable optimization algorithm. The studied reaction to reach this goal is a nitroaldol condensation. 相似文献
132.
Ricardo Cambraia Parreira Diana Paola Gmez‐Mendoza Itamar Couto Guedes de Jesus Rafael Pereira Lemos Anderson Kennedy Santos Cristiana Perdigo Rezende Henrique Csar Pereira Figueiredo Mauro Cunha Xavier Pinto Frank Kjeldsen Silvia Guatimosim Rodrigo Ribeiro Resende Thiago Verano‐Braga 《Proteomics. Clinical applications》2020,14(4)
133.
Daniel E. Azofeifa Neville Clark William E. Vargas Hugo Solis E. Avendano Michael Cambronero Diana Valverde-Mendez 《International Journal of Hydrogen Energy》2017,42(35):22373-22378
We report measurements of the optical transmission, between 240 and 1040 nm, and electrical resistivity of polycrystalline zirconium thin films as they absorb hydrogen. Both are measured as H2 pressure is increased up to 880 mbar, at room temperature. Films, 20–22 nm thick, are deposited on fused quartz substrates by e-beam evaporation at 5.3 × 10?7 mbar base pressure and covered with a 8.0 nm Pd over-coat. The morphology of the films is studied by means of AFM images. The complex refractive indices of Zr and Pd are extracted numerically from the transmission spectra by using a spectral projected gradient method for different hydrogen pressures. The corresponding dielectric functions for various Zr hydrogen concentrations are described with the parametric Drude-Lorentz and Brendel-Bormann (DL & BB) models. The Acceptance-Probability-Controlled Simulated Annealing approach is applied to calculate the parameters of the DL & BB model. This allows us to describe the effect of increasing hydrogen absorption on these parameters and in derived quantities, like the relaxation time and the effective mass of conduction electrons, the electrical resistance, the Fermi energy, and the electronic density of states at the Fermi level. 相似文献
134.
In the present work, a photoproduct of chlortetracycline (CTC) was identified for the first time in hog lagoon samples from confined animal feeding operations. Screening of several samples by LC/ESI-MS indicated the presence of a potential photooxygenation product of CTC with a nominal mass that was 32 Da higher than the parent drug. Generation of this assumed photoproduct (designated M510) was achieved in a 24-h irradiation experiment of an oxygenated alkaline medium containing 50 mg L(-)(1) CTC. Accurate mass measurements with an ESI-TOF-MS of the protonated isomerization product of CTC (iCTC) and the postulated photooxygenation product, bearing two oxygen atoms more than iCTC, were m/z 479.1229 and 511.1109, respectively. These corresponded to errors of -2.8 ppm for iCTC and +1.0 ppm for M510 relative to the theoretical masses. The generation of second- and third-stage mass spectra in an ESI-ion trap-MS showed similar characteristic fragmentation patterns for iCTC and the photoproduct M510, leading to the conclusion that the M510 structure consisted of an iCTC-like skeleton bearing two additional hydroxy groups. The site and configuration of one hydroxylation was confidently assigned, while the position of the other hydroxy group was tentatively assigned. Comparison of the (+)-ESI-MS(3) spectrum and the retention time of M510 in the sample from the irradiation experiment with those from the hog lagoon samples yielded excellent agreement, suggesting that the compounds were identical. Quantitative analysis of seven hog lagoon samples showed iCTC concentrations of 1910-15 800 microg L(-)(1), while the levels of M510 were found to be between 46 and 303 microg L(-)(1). 相似文献
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136.
Adherence rates to ferric citrate as compared to active control in patients with end stage kidney disease on dialysis 下载免费PDF全文
Diana Jalal Molly McFadden Jamie P. Dwyer Kausik Umanath Erwin Aguilar Yoram Yagil Barbara Greco Mohammed Sika Julia B. Lewis Tom Greene Simin Goral 《Hemodialysis international. International Symposium on Home Hemodialysis》2017,21(2):243-249
Introduction: Oral phosphate binders are the main stay of treatment of hyperphosphatemia. Adherence rates to ferric citrate, a recently approved phosphate binder, are unknown. Methods: We conducted a post‐hoc analysis to evaluate whether adherence rates were different for ferric citrate vs. active control in 412 subjects with end stage kidney disease (ESKD) who were randomized to ferric citrate vs. active control (sevelamer carbonate and/or calcium acetate). Adherence was defined as percent of actual number of pills taken to total number of pills prescribed. Findings: There were no significant differences in baseline characteristics including gender, race/ethnicity, and age between the ferric citrate and active control groups. Baseline phosphorus, calcium, and parathyroid hormone levels were similar. Mean (SD) adherence was 81.4% (17.4) and 81.7% (15.9) in the ferric citrate and active control groups, respectively (P = 0.88). Adherence remained similar between both groups after adjusting for gender, race/ethnicity, age, cardiovascular disease (CVD), and diabetic nephropathy (mean [95% CI]: 81.4% [78.2, 84.6] and 81.5% [77.7, 85.2] for ferric citrate and active control, respectively). Gender, race/ethnicity, age, and diagnosis of diabetic nephropathy did not influence adherence to the prescribed phosphate binder. Subjects with CVD had lower adherence rates to phosphate binder; this was significant only in the active control group. Discussion: Adherence rates to the phosphate binder, ferric citrate, were similar to adherence rates to active control. Similar adherence rates to ferric citrate are notable since tolerance to active control was an entry criteria and the study was open label. Gender, race/ethnicity, nor age influenced adherence. 相似文献
137.
Qiao Zhang Ji-Bong Joo Zhenda Lu Michael Dahl Diana Q. L. Oliveira Miaomiao Ye Yadong Yin 《Nano Research》2011,4(1):103-114
Mesoporous nanocrystal clusters of anatase TiO2 with large surface area and enhanced photocatalytic activity have been successfully synthesized. The synthesis involves the
self-assembly of hydrophobic TiO2 nanocrystals into submicron clusters, coating of these clusters with a silica layer, thermal treatment to remove organic
ligands and improve the crystallinity of the clusters, and finally removing silica to expose the mesoporous catalysts. With
the help of the silica coating, the clusters not only maintain their small grain size but also keep their mesoporous structure
after calcination at high temperatures (with BET surface area as high as 277 m2/g). The etching of SiO2 also results in the clusters having high dispersity in water. We have been able to identify the optimal calcination temperature
to produce TiO2 nanocrystal clusters that possess both high crystallinity and large surface area, and therefore show excellent catalytic
efficiency in the decomposition of organic molecules under illumination by UV light. Convenient doping with nitrogen converts
these nanocrystal clusters into active photocatalysts in both visible light and natural sunlight. The strategy of forming
well-defined mesoporous clusters using nanocrystals promises a versatile and useful method for designing photocatalysts with
enhanced activity and stability. 相似文献
138.
Photovoltaic devices using GaAs nanopillar radial p-n junctions are demonstrated by means of catalyst-free selective-area metal-organic chemical vapor deposition. Dense, large-area, lithographically defined vertical arrays of nanowires with uniform spacing and dimensions allow for power conversion efficiencies for this material system of 2.54% (AM 1.5 G) and high rectification ratio of 213 (at ±1 V). The absence of metal catalyst contamination results in leakage currents of ~236 nA at -1 V. High-resolution scanning photocurrent microscopy measurements reveal the independent functioning of each nanowire in the array with an individual peak photocurrent of ~1 nA at 544 nm. External quantum efficiency shows that the photocarrier extraction highly depends on the degenerately doped transparent contact oxide. Two different top electrode schemes are adopted and characterized in terms of Hall, sheet resistance, and optical transmittance measurements. 相似文献
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