Selectivity of high surface area Ce0.68Zr0.32O2 for the new generation of TWC under environments with different redox character

A number of experiments were carried out with fresh and aged high surface area Ce_0.68Zr_0.32O₂ mixed oxide samples with complex feed-streams in order to determine their performance as three way catalyst (TWC). The results confirmed the oxygen storage capacity (OSC) of these samples, which favour NO conversion in cycled versus stationary stoichiometric operation. Several experiments carried out with different feed-streams have shown that a pre-reducing treatment can significantly improve both NO reduction at low-temperature and selectivity to N₂, which can be very useful to reduce the emission of nitrogen oxides immediately after starting the automobile. Although a significant reduction of the specific surface area of the mixed oxide takes place during ageing at 1173 K, it has been shown that the performance of the sample remains similar or even better than when fresh, due to an increased OSC. Thus, the reduction of CO and hydrocarbon emissions during start could be achieved by situating the catalytic converter nearer the exhaust to the engine, where the catalyst will be heated faster.     

Flow Properties of Tailored Net-Shape Thermoplastic Composite Preforms

A novel thermoplastic programmable preforming process, TP-P4, has been used to manufacture preforms for non-isothermal compression molding. Commingled glass and polypropylene yarns are deposited by robot onto a vacuum screen, followed by a heat-setting operation to stabilize the as-placed yarns for subsequent handling. After an optional additional preconsolidation stage, the preforms are molded by preheating and subsequent press forming in a shear edge tool. The in- and out-of-plane flow capabilities of the material were investigated, and compared to those of 40 _wt% Glass Mat Thermoplastics (GMTs). Although the TP-P4 material has a fiber fraction of 60 _wt%, the material could be processed to fill 77 mm deep ribs with a thickness of 3 mm, indicative of complex part production. The pressure requirements for out-of-plane flow were shown to depend on the fiber length and fiber alignment. Segregation phenomena were found to be less severe with TP-P4 than with GMT material.     

“Click” Synthesis of a Heterobifunctional Ferrocenyl Dendrimer with Molecular Recognition Properties and Influence of the Ferrocenyl Redox Potential on the Formation of Gold Nanoparticles

Alkyne protection by complexation of ethynylferrocene with dicobalt octacarbonyl followed by regioselective acetylation, then deprotection and “click” reaction with a nona-azido-terminated arene-cored dendrimer leads to the heterodifunctional nona(1,2,3-triazolyl-acetylferrocenyl) dendrimer. Cyclic voltammetry of this metallodendrimer shows recognition of both ATP^2? and Pd²⁺. HAuCl₄ is reduced much more slowly to gold nanoparticles by the nona(triazolyl-acetylferrocenyl dendrimer than by the nona(triazolylferrocenyl) dendrimer due to the shift of redox potential in the new heterodifunctional dendrimer compared to that of the parent ferrocenyl dendrimer.     

Back-end soft and hard defect monitoring using a single test chip

The objective of this paper is to present a mixed test structure designed to characterize yield losses due to hard defect and back-end process variation (PV) at die and wafer level. A brief overview of the structure, designed using a ST-Microelectronics’ 130 nm technology, is given. This structure is based on a SRAM memory array for detecting hard defects. Moreover each memory cell can be configured in the Ring Oscillator (RO) mode for back-end PV characterization. The structure is tested in both modes (SRAM, RO) using a single test flow. The test data analysis method is presented and applied to experimental results to confirm the ability of the structure to monitor PV and defect density.     

Spark Plasma Sintering of fine alpha-silicon nitride ceramics with LAS for spatial applications

Many space systems such as satellite mirrors and their supporting structures require to be made from very low-thermal expansion materials combining both high hydrostability and relatively high mechanical properties. In this study, we have applied the “composite concept” in order to explore the possibility of fabricating near zero thermal expansion silicon nitride based ceramics. Consequently, a negative thermal expansion material belonged to the lithium aluminosilicate family (LAS powder crystallized under de β-eucryptite structure) was introduced in an alpha-silicon nitride fine powder (5 and 20 vol% of LAS) and the resulting composite system was sintered by Spark Plasma Sintering (SPS) at 1400 and 1500 °C. In the case of 20 vol% LAS compositions, relatively well-densified ceramics (94.4% of the theoretical density) were produced without adding any further sintering additive. The addition of yttria and alumina oxides allowed enhancing the densification level up to 98.2% (20 vol% LAS compositions) or from 62.3% up to 96.7% of the theoretical density in 5 vol% LAS materials. Nevertheless, it was impossible to full consolidate silicon nitride/LAS composite ceramics at temperatures lower than the temperature at which β-eucryptite melts, even by using SPS technology. Moreover, because of the relatively low temperatures involved in SPS, the α to β-Si₃N₄ transformation was avoided, resulting in microstructures composed of fine equiaxed α-Si₃N₄ grains (<200 nm) and of a glassy phase. Even if the effect of having a very large negative thermal expansion material was lost during the sintering step (because of the β-eucryptite melting), ceramics containing only 20 vol% of LAS-based phase exhibited very interesting values as regards of mechanical properties (strength, hardness, toughness, and Young's modulus), thermal conductivity and thermal expansion coefficient. We discuss in this work why we are so interested in developing dense silicon nitride/LAS ceramics sintered without any further additive addition, even though β-eucryptite is melted during the process and the transformation to the β phase is avoided.     

Use of microfibrillated cellulose and dendritic copper for the elaboration of conductive films from water- and ethanol-based dispersions

In this study, microfibrillated cellulose (MFC) and dendritic copper were used as binder and conductive phase for the elaboration of self-standing conductive films and coatings. A filtration technique was used to prepare MFC/Cu films from particle dispersions in water and ethanol. In aqueous slurries copper oxidized and an additional corona treatment or the use of zinc particles as sacrificial anode were necessary to obtain films with conductivities ranging from 70 to 2500 S m^?1, respectively. In ethanol-based MFC/Cu slurries, copper was subjected to limited oxidation. However, the low packing density of conductive particles (below the percolation threshold) led to resistive films which, after densification by calendering, displayed extremely high conductivities, up to 70000 S m^?1. Aqueous MFC/Cu slurries were successfully used for the deposition of conductive coatings on copy paper by Mayer rod coating and screen printing, which were subsequently treated by corona discharge and calendering. The obtained coatings displayed intermediate conductivity (i.e. 95 and 570 S m^?1 for rod coating and screen printing, respectively), which can be further increased using zinc particles or ethanol-based formulations.     

Pullulan–STMP hydrogels: a way to correlate crosslinking mechanism,structure and physicochemical properties

Rheological and swelling properties of hydrogels based on pullulan crosslinked with sodium trimetaphosphate (STMP) are explained according to various polymer and crosslinking agent concentrations using ³¹P-nuclear magnetic resonance study. This method has allowed determining the amount of all the species present in the medium when varying both pullulan and STMP concentrations. We have clearly demonstrated with a good agreement by both ³¹P-NMR and rheology that a critical STMP concentration occurs which is function of pullulan concentration. This typical crosslinking agent concentration delimitates the maximum of gel structure together with the minimum of swelling.     

The European project trust—reconfigurable terminals and supporting networks

To date, research into reconfigurable mobile communications has predominantly focussed on the software radio concept, and specifically on the hardware technologies required to move physical layer processing into a programmable environment [1, 2, 3]. Although an interesting and necessary challenge, this only represents a fraction of the overall support and technology required to realise the potential of the concept. Other necessary developments include network/terminal cooperation for seamless inter-standard handoff, QoS management for software download and reconfiguration, a secure software download mechanism, terminal software and mobile radio network architecture supporting terminal reconfiguration, management for software downloads, configuration management, capability negotiation, radio resource management and spectrum allocation policies etc… This paper describes results from the EuropeanIst Trust (Transparently Reconfigurable UbiquitouS Terminal) [4] project concerning user and operator requirements, the proposed overall system environment, security issues, concerted radio resource management, and expected time frame for the development of reconfigurable terminals.