“Click” Synthesis of a Heterobifunctional Ferrocenyl Dendrimer with Molecular Recognition Properties and Influence of the Ferrocenyl Redox Potential on the Formation of Gold Nanoparticles

Alkyne protection by complexation of ethynylferrocene with dicobalt octacarbonyl followed by regioselective acetylation, then deprotection and “click” reaction with a nona-azido-terminated arene-cored dendrimer leads to the heterodifunctional nona(1,2,3-triazolyl-acetylferrocenyl) dendrimer. Cyclic voltammetry of this metallodendrimer shows recognition of both ATP^2? and Pd²⁺. HAuCl₄ is reduced much more slowly to gold nanoparticles by the nona(triazolyl-acetylferrocenyl dendrimer than by the nona(triazolylferrocenyl) dendrimer due to the shift of redox potential in the new heterodifunctional dendrimer compared to that of the parent ferrocenyl dendrimer.     

Back-end soft and hard defect monitoring using a single test chip

The objective of this paper is to present a mixed test structure designed to characterize yield losses due to hard defect and back-end process variation (PV) at die and wafer level. A brief overview of the structure, designed using a ST-Microelectronics’ 130 nm technology, is given. This structure is based on a SRAM memory array for detecting hard defects. Moreover each memory cell can be configured in the Ring Oscillator (RO) mode for back-end PV characterization. The structure is tested in both modes (SRAM, RO) using a single test flow. The test data analysis method is presented and applied to experimental results to confirm the ability of the structure to monitor PV and defect density.     

Use of microfibrillated cellulose and dendritic copper for the elaboration of conductive films from water- and ethanol-based dispersions

In this study, microfibrillated cellulose (MFC) and dendritic copper were used as binder and conductive phase for the elaboration of self-standing conductive films and coatings. A filtration technique was used to prepare MFC/Cu films from particle dispersions in water and ethanol. In aqueous slurries copper oxidized and an additional corona treatment or the use of zinc particles as sacrificial anode were necessary to obtain films with conductivities ranging from 70 to 2500 S m^?1, respectively. In ethanol-based MFC/Cu slurries, copper was subjected to limited oxidation. However, the low packing density of conductive particles (below the percolation threshold) led to resistive films which, after densification by calendering, displayed extremely high conductivities, up to 70000 S m^?1. Aqueous MFC/Cu slurries were successfully used for the deposition of conductive coatings on copy paper by Mayer rod coating and screen printing, which were subsequently treated by corona discharge and calendering. The obtained coatings displayed intermediate conductivity (i.e. 95 and 570 S m^?1 for rod coating and screen printing, respectively), which can be further increased using zinc particles or ethanol-based formulations.     

Pullulan–STMP hydrogels: a way to correlate crosslinking mechanism,structure and physicochemical properties

Rheological and swelling properties of hydrogels based on pullulan crosslinked with sodium trimetaphosphate (STMP) are explained according to various polymer and crosslinking agent concentrations using ³¹P-nuclear magnetic resonance study. This method has allowed determining the amount of all the species present in the medium when varying both pullulan and STMP concentrations. We have clearly demonstrated with a good agreement by both ³¹P-NMR and rheology that a critical STMP concentration occurs which is function of pullulan concentration. This typical crosslinking agent concentration delimitates the maximum of gel structure together with the minimum of swelling.     

The European project trust—reconfigurable terminals and supporting networks

To date, research into reconfigurable mobile communications has predominantly focussed on the software radio concept, and specifically on the hardware technologies required to move physical layer processing into a programmable environment [1, 2, 3]. Although an interesting and necessary challenge, this only represents a fraction of the overall support and technology required to realise the potential of the concept. Other necessary developments include network/terminal cooperation for seamless inter-standard handoff, QoS management for software download and reconfiguration, a secure software download mechanism, terminal software and mobile radio network architecture supporting terminal reconfiguration, management for software downloads, configuration management, capability negotiation, radio resource management and spectrum allocation policies etc… This paper describes results from the EuropeanIst Trust (Transparently Reconfigurable UbiquitouS Terminal) [4] project concerning user and operator requirements, the proposed overall system environment, security issues, concerted radio resource management, and expected time frame for the development of reconfigurable terminals.     

Computational methods for determining the latest starting times and floats of tasks in interval-valued activity networks

In project management, three quantities are often used by project managers: the earliest starting date, the latest starting date and the float of tasks. These quantities are computed by the Program Evaluation and Review Techniques/Critical Path Method (PERT/CPM) algorithm. When task durations are ill known, as is often the case at the beginning of a project, they can be modeled by means of intervals, representing the possible values of these task durations. With such a representation, the earliest starting dates, the latest starting dates and the floats are also intervals. The purpose of this paper is to give efficient algorithms for their computation. After recalling the classical PERT/CPM problem, we present several properties of the concerned quantities in the interval-valued case, showing that the standard criticality analysis collapses. We propose an efficient algorithm based on path enumeration to compute optimal intervals for latest starting times and floats in the general case, and a simpler polynomial algorithm in the case of series-parallel activity networks.     

On the relevance of non-standard theories of uncertainty in modeling and pooling expert opinions

Wu, Apostolakis and Okrent¹ have recently analyzed the current status of emerging alternatives to classical probabilistic methods in the modeling and pooling of expert opinions in safety analysis of engineering systems. They have pointed out some difficulties faced by these theories, due to their relative lack of maturity. This paper pursues the investigation so as to clarify some aspects of belief functions and possibility theories, and also to point out the need for further research. A comparison between the mathematical models of expert opinion pooling offered by Bayesian probabilities, belief functions and possibility theory is carried out. It is proved that the Bayesian approach that these authors advocate suffers from the same numerical stability problems as possibilistic and evidential rules of combination in the presence of strongly conflicting information due to their strong structural similarities. The problem of dependence between experts is briefly addressed. The other main point of this paper is that a single combination rule cannot reasonably address all situations where expert opinions must be pooled. It is suggested that the framework of possibility and evidence theories offers a more flexible framework for representing and combining subjective uncertain judgments than the one of subjective probability alone although some progress is required to reach the maturity of the Bayesian theory.     

Application of ultrafiltration to the preparation of defined hydrolysates of bovine haemoglobin

Many uses of protein hydrolysates have been developed and applied to areas such as nutritional therapy, culture media, and the isolation of biologically active peptides. All these applications need carefully controlled and characterized hydrolysates. In order to produce such a type of hydrolysate, it is possible to use haemoglobin which is a very well defined and constant protein source. Enzymic hydrolysis of haemoglobin by pepsin was carried out at pilot-plant scale in an ultrafiltration reactor with mineral membranes. The object was to obtain a reproducible, decolorized, salt-free enzymic hydrolysate. Two types of membranes were tested having 10000 dalton (M5 type) and 20000 dalton (M4 type) cut-offs. Little significant difference was observed in the final products when both types of membranes were used. Reproducibility of hydrolysates was verified by amino acid analysis and gel filtration chromatography. The haemoglobin hydrolysates produced contained more than 90% protein and are especially suitable for fine applications.     

Preliminary investigations of weak non-adiabatic effects in materials from simulations on model clusters

According to earlier work, excited electronic states, despite their very small concentrations in wide-gap systems, might be involved in the initiation of energetic materials. To get further insight into the non-adiabatic electronic behaviour under intense mechanical perturbations, a simple approach is suggested, using finite clusters as models for materials. Preliminary calculations are carried out for isolated clusters undergoing vibrations. Electronic populations in excited states obtained from these simulations are much larger than expected on the basis of statistical mechanics. Therefore, an extension of the present scheme to the canonical NVT ensemble would be desirable.     

Resonant tunneling diodes as sources for millimeter andsubmillimeter wavelengths

High quality resonant tunneling diodes have been fabricated and tested as sources for millimeter and submillimeter wavelengths. The devices have shown excellent I-V characteristics with peak-to-valley current ratios as high as 6:1 and current densities in the range of 50-150 kA/cm² at 300 K. Used as local oscillators, the diodes are capable of state of the art output power delivered by AlGaAs-based tunneling devices. As harmonic multipliers, a frequency of 320 GHz has been achieved by quintupling the fundamental oscillation of a klystron source