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81.
The image and van der Waals contributions to the metal/oxide work of adhesion are compared through the extent to which they follow the known prevalent trends, i.e. the increase in work of adhesion (a) with narrowing oxide band gap and (b) with increasing conduction electron density of the metal. The van der Waals interaction is shown to follow both trends, while the image term is suggested to be significant only for dense metals in contact with very ionic oxides. The relative contribution of these long-range interactions to the overall metal/oxide work of adhesion is found to be maximized for systems involving metals with low electronic densities and oxides with wide band gaps. At variance, high metallic electronic densities and narrow oxide gaps likely favour short-range interactions arising from charge transfer. 相似文献
82.
Nicolas Mackiewicz Thomas Bark Bertrand Cao Jacques A. Delaire Didier Riehl Wai Li Ling Stéphanie Foillard Eric Doris 《Carbon》2011,49(12):3998-4003
We report the synthesis, characterization and optical limiting behavior of a nanohybrid built by grafting C60-fullerenes on carbon nanotubes (CNTs). The nonlinear optical limiting properties of the CNT-C60 complex were investigated at wavelengths where C60 does not absorb. We found that the nanohybrid had superior performances to those of CNTs and fullerenes, either taken individually or as a mixture. This enhanced optical limitation of the nanohybrid suggests not only cooperative but also synergistic effects between the two carbon forms. A mechanism involving higher excitonic states of the CNTs formed by Auger recombination of low energy excitons is proposed. 相似文献
83.
We describe the design of a microwave oscillator using resonant tunneling diodes. The devices are fabricated from Al0.3Ga0.7As-GaAs double barrier hetero-structures grown by molecular beam epitaxy. Design criteria improving current drivability are established from a theoretical study of tunneling transmission probabilities. Very high peak current densities up to 3.104 A/cm2, favorable for high frequency operation as an oscillator, have been achieved experimentally. The devices exhibit stable oscillations at liquid nitrogen temperature and at room temperature when the tunnel diode oscillator is constructed with a stabilizing network. 相似文献
84.
Zhanbing He Chang Seok Lee Jean-Luc Maurice Didier Pribat Paul Haghi-Ashtiani Costel Sorin Cojocaru 《Carbon》2011,49(14):4710-4718
Plasma-enhanced chemical vapor deposition, without a nickel-containing gaseous precursor, was used to synthesize continuous nickel (Ni) nanorods inside the hollow cavity of carbon nanofibers (CNFs), thus forming vertically aligned Ni/CNF core/shell structures. Scanning and transmission electron microscopic images indicate that the elongated Ni nanorods originate from the catalyst particles at the tips of the CNFs and that their formation is due to the effect of extrusion induced by the compressive force of the graphene layers during growth. Different from previous work, each vertically-aligned core/shell structure reported is totally isolated from its neighbors. Continuous Ni nanorods are found to separate into smaller ones with increasing growth time, which was ascribed to (i) the limited amount of Ni available in the tip of the CNF, (ii) the polycrystalline nature of the Ni nanorods and (iii) the combined effects of the compressive stresses on the side of the Ni nanorods and of the tensile stress along their axis. 相似文献
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Jean-François Vinchant Franck Mallecot Didier Decoster Jean-Pierre Vilcot 《电信纪事》1989,44(3-4):149-154
The authors developed a model on optical guided structures with complex refractive indices, on 9 desktop-computer. This model allows to predict the coupling efficiency of photodetectors monolithically integrated with optical waveguides. An oscillatory behaviour of the absorption coefficient versus the absorbing layer thinkness has been pointed out. Comparisons with experimental resuylts obtained with device made in different laboratories show a good agrement 相似文献
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