Modeling and analysis of an unreliable flow line composed of parallel-machine stages

This paper focuses on flow lines composed of multiple parallel-machine stages. The system is similar to a classical flow line, the only difference being that a given stage may consist of parallel machines. A method for modeling and analyzing this type of flow lines is presented. The technique used amounts to replacing each parallel-machine stage by a single equivalent machine in order to obtain a classically-structured flow line with machines in series. Equations for computing the parameters of equivalent machines are submitted. These parameters can then be used to carry out performance diagnosis of the corresponding stage, or as input data for existing analysis methods to evaluate the production performance of flow lines. The method presented in this paper has been successfully implemented and tested in the industry over the past few years.     

Fabrication and performance of InP-based heterostructure barriervaractors in a 250-GHz waveguide tripler

High-performance InGaAs-InAlAs-AlAs heterostructure barrier varactors (HBV's) have been designed, fabricated, and RF tested in a 250-GHz tripler block. The devices with two barriers stacked on the same epitaxy are planar integrated with coaxial-, coplanar-, and strip-type configurations. They exhibit state-of-the-art capacitance voltage characteristics with a zero-bias capacitance C₃⁰ of 1 fF/μm² and a capacitance ratio of 6:1. Experiments in a waveguide tripler mount show a 9.8-dBm (9.55-mW) output power for 10.7% conversion efficiency at 247.5 GHz. This is the highest output power and efficiency reported from an HBV device at J-band (220-325 GHz)     

Détection d’obstacles routiers par stéréovision : l’approche « v-disparité »

This paper presents an innovating real time method for detecting road obstacles by on board stereovision. After having exposed the stakes of the obstacles detection, having presented the state of the art and having identified the problems to be solved, the developed approach is described. It is based on the analysis of the “v-disparity” image, which provides a suitable representation of the geometric content of the road scene. The method is then evaluated with respect to the problems generally affecting stereovision approaches. The theoretical good properties of the “v-disparity” algorithm — genericity, effectiveness, robustness, and computational efficiency — are thus experimentally confirmed. Thanks to the performances obtained, the described algorithm is used for on board driving assistance applications.     

Oxidative Metabolism of Ferrocene Analogues of Tamoxifen: Characterization and Antiproliferative Activities of the Metabolites

Ferrociphenols have been found to have high antiproliferative activity against estrogen‐independent breast cancer cells. The rat and human liver microsome‐mediated metabolism of three compounds of the ferrocifen ( FC ) family, 1,1‐bis(4‐hydroxyphenyl)‐2‐ferrocenyl‐but‐1‐ene ( FC1 ), 1‐(4‐hydroxyphenyl)‐1‐(phenyl)‐2‐ferrocenyl‐but‐1‐ene ( FC2 ), and 1‐[4‐(3‐dimethylaminopropoxy)phenyl]‐1‐(4‐hydroxyphenyl)‐2‐ferrocenyl‐but‐1‐ene ( FC3 ), was studied. Three main metabolite classes were identified: quinone methides ( QM s) deriving from two‐electron oxidation of FC s, cyclic indene products ( CP s) deriving from acid‐catalyzed cyclization of QM s, and allylic alcohols ( AA s) deriving from hydroxylation of FC s. These metabolites are generated by cytochromes P450 (P450s), as shown by experiments with either N‐benzylimidazole as a P450 inhibitor or recombinant human P450s. Such P450‐dependent oxidation of the phenol function and hydroxylation of the allylic CH₂ group of FC s leads to the formation of QM and AA metabolites, respectively. Some of the new ferrociphenols obtained in this study were found to exhibit remarkable antiproliferative effects toward MDA‐MB‐231 hormone‐independent breast cancer cells.     

In-situ fabrication of polyacrylate-silver nanocomposite through photoinduced tandem reactions involving eosin dye

A silver-acrylate nanocomposite was prepared using a novel one-pot strategy involving eosin dye as visible sensitizer and an amine derivative as radicals' source. The mechanism highlighted by steady state photolysis and time-resolved absorption spectroscopy lies on the initial formation of a strong ion-pair complex between eosin and Ag⁺. Upon visible irradiation, the excited triplet state of the metal complex efficiently abstracts a hydrogen atom from the amine and produces an α-aminoalkyl radical. In acrylate monomer matrix, such a strong reactive species initiates a free radical photopolymerization and also provides the reduction of the silver cation. Through this ‘in-situ’ fabrication method, the kinetics formation of the nanocomposite and its detailed structural analysis are characterized by UV-visible, real-time FTIR absorption spectroscopy and by transmission electron microscopy.     

Conducting polyaniline composite: From syntheses in waterborne systems to chemical sensor devices

The development of a conducting composite from its one-step synthesis in aqueous dispersed medium to the characterization of its chemical sensor performance is detailed. Composite films of polyaniline and polyacrylate were processed from the crude dispersion with no need for post-formulation. The synthesis has been optimized to be as simple, cheap and transferable as possible. The composite composition is tunable, i.e. the nature of the dopant was varied and its effect on kinetic parameters was observed. Ab initio calculations have been performed on a series of six ionic systems to gain a deeper insight into the contribution of both the stability of the anilinium salts in the composite polymerization. The conductivities of all composites were recorded from room temperature to 150 °C and the thermal stability versus dopant highlighted. The conducting films were then studied as active layers in a chemical sensor. The results showed that these composites, easily synthesized and processed, are ammonia sensitive and exhibit a fast response when exposed to air pollution.