Organic‐acid‐catalyzed sol–gel route for preparing poly(methyl methacrylate)–silica hybrid materials

In this study, a series of organic–inorganic hybrid sol–gel materials consisting of a poly(methyl methacrylate) (PMMA) matrix and dispersed silica (SiO₂) particles were successfully prepared through an organic‐acid‐catalyzed sol–gel route with N‐methyl‐2‐pyrrolidone as the mixing solvent. The as‐synthesized PMMA–SiO₂ nanocomposites were subsequently characterized with Fourier transform infrared spectroscopy and transmission electron microscopy. The solid phase of organic camphor sulfonic acid was employed to catalyze the hydrolysis and condensation (i.e., sol–gel reactions) of tetraethyl orthosilicate in the PMMA matrix. The formation of the hybrid membranes was beneficial for the physical properties at low SiO₂ loadings, especially for enhanced mechanical strength and gas barrier properties, in comparison with the neat PMMA. The effects of material composition on the thermal stability, thermal conductivity, mechanical strength, molecular permeability, optical clarity, and surface morphology of the as‐prepared hybrid PMMA–SiO₂ nanocomposites in the form of membranes were investigated with thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, gas permeability analysis, ultraviolet–visible transmission spectroscopy, and atomic force microscopy, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

CO毒化AB5型合金分形特征研究

研究了三种贮氢合金 L a Ni5、L a Ni4 .7Al0 .3、Ml Ni4 .5Al0 .5被 10 0× 10 - 6 CO毒化后的分形特征 ,求出这三种合金在含 10 0× 10 - 6 CO的氢中循环 ,分维分别为 0 .2 5 4 7、0 .170 9、0 .0 72 5。可以较好的解释合金被毒化的宏观现象。     

Performance of the polymer- and oxide-supported triphase catalysts and effect of ultrasound on their stabilities

In this study, several trialkylamines were immobilized on chloromethylated polystyrene (CMPS), silica gel, and alumina to prepare triphase catalysts for catalyzing the etherification reaction of allyl bromide (the organic reactant) and sodium phenolate (the aqueous reactant). The reactor was agitated mechanically or with the aid of ultrasonic vibration. Performances of the prepared catalysts were compared, and the effect of imposing ultrasound was investigated based on the activity, selectivity, and stability of the catalyst. Experimental results show that tri-n-propylamine is the best active species when CMPS is used as the support, while tri-n-butylamine is the best when SiO₂ and Al₂O₃ are employed as the supports. The CMPS-supported catalyst is far better than the SiO₂- and Al₂O₃-supported catalysts in activity and selectivity but not in stability. Imposing the ultrasound can effectively increase the reaction rate. Mechanical agitation at a low speed with the imposition of ultrasonic vibration not only results in a conversion slightly higher than the case with a high mechanical agitation speed without ultrasonic vibration, but also gives a constant stability for the CMPS-supported catalyst.     

等级化信息安全保障体系设计思想

一、前言等级化信息安全是我国信息安全的一项基本策略,实施等级化信息安全保护是实现“重点资产重点保护”,同时又“适度安全”的有效手段,其最终目的是实现安全和成本的综合平衡,达到提高信息安全建设质量,提高安全的综合性价比这一根本目的。正如任何一种新方法的提出必然面临如何有效实施的问题一样,自从2003年中办发27号文件以来,尽管国家相关部门已经陆续出台了等级化信息安全保障的相关文件、意见和实施指南,等级化在信息安全界的实施却比较困难。这是由于在实践中发现,目前出台的相关指南对于复杂的应用系统和网络系统在其操作性上…     

金属钝化剂的合成和应用

简要介绍了金属钝化剂的品种和合成方法及在PE、PP、PS等聚合物材料上的应用。     

对建设中国先进文化的几点认识

充分认识文化和先进文化的本质特征,领会“三个代表”重要思想中关于“代表中国先进文化前进方向”的深刻内涵,研讨我国先进文化建设面临的新课题,努力实践“三个代表”,积极发展先进文化。     

A high-efficiency CMOS +22-dBm linear power amplifier

Modern wireless communication systems require power amplifiers with high efficiency and high linearity. CMOS is the technology of choice for complete systems on a chip due to its lower costs and high integration levels. However, it has always been difficult to integrate high-efficiency power amplifiers in CMOS. In this paper, we present a new class of operation (parallel A&B) for power amplifiers that improves both their dynamic range and power efficiency. A prototype design of the new amplifier was fabricated in a 0.18-/spl mu/m CMOS technology. Measurement results show a PAE that is over 44% and the measured output power is +22 dBm. In comparison to a normal class A amplifier, this new design increases the 1-dB compression point (P1dB) by over 3 dB and reduces dc power consumption by over 50% within the linear operating range.     

A novel in situ synthesis of dicalcium phosphate dehydrate nanocrystals in biodegradable polymer matrix

In the paper, we found a novel method to synthesize dicalcium phosphate dehydrate (DCPD) nanocrystals by in situ reaction in biodegradable PDLLA matrix. Calcium hydrid was selected as calcium source of DCPD, which is different from general methods. The method is not only simple and effective to synthesize Ca–P particles, but also can avoid the aggregation of inorganic nanoparticles in the course of their being dispersed into polymer matrix.     

钢坯修磨金属切除率数学模型的研究

从分析修磨过程运动学和单个磨粒切削入手,建立了磨削深度与磨削过程诸参数(如工艺、材料性能、砂轮性能等)的关系表达式,从而建立起金属切除率与各单项参数的定量关系,为改善或提高修磨效率和修磨过程控制提供了有意义的根据。理论分析与实验结果吻合良好。