Water vapor adsorption in activated carbon modified with hydrophilic organic salts

Five different kinds of hydrophilic organic salts were used to modify commercial activated carbon in order to prepare hydrophilic carbon materials. Properties of the samples were analyzed by surface area analyzer and SEM-EDX. The hydrophilic organic salts with different properties were introduced into activated carbon and significantly affected the properties of the samples.During adsorption experiments, the water vapor adsorption amount in modified samples increases by 0.57-17.12 times in temperature range from 303 to 323 K and at relative pressure below 0.50. Water molecules combined with surface hydrophilic groups through H-bonding exhibit good thermo stability. The effects of temperature, oxygen content and properties of the hydrophilic organic salts on water vapor adsorption were studied. It is indicated that water vapor adsorption in modified samples is mainly affected by the surface oxygen content. The carboxylate radicals in the hydrophilic organic salts greatly affect the micropore structure of the modified samples, while the metal ions in them exhibit limited influence. Different adsorption capacity of modified samples can be explained with the electronegativity of elements presented by Pauling.     

基于渐开线齿轮范成仪的改进设计

根据渐开线廓范成仪的功能和原理,把老式范成仪的手动操作改为电子控制自动操作,使操作精确方便,经实际使用效果很好,为制造自动式渐线线齿轮范成仪提供参考.     

军民融合式装备保障闭环管理研究

针对军民融合式装备保障中经常存在的局部或片面思想,以及总体装备保障质量与效益不高等问题,以系统管理理论为指导,分析了军民融合式装备保障中的闭环管理原理,对影响实现闭环管理的关键环节进行了探讨,并从军民融合战略闭环管理体系建立、优化工作流程与管理职责、装备保障信息资源开发与利用等方面,提出了实现军民融合式装备保障闭环管理的措施与对策建议。     

基材清洗工艺对SiO2/PET膜基结合强度的影响

采用磁控溅射工艺,在PET表面沉积Si O2薄膜,利用SEM观察镀膜的表面形貌,通过附着力测试仪检测Si O2/PET膜基的结合强度,研究基材PET表面清洗工艺对Si O2/PET膜基结合强度的影响。结果表明:结合强度因PET基材表面清洗工艺的不同而不同,其中经等离子清洗的膜基结合强度最大,达0.14MPa,分别较深度清洗、一般清洗和不清洗的膜基结合强度高7.83%,27.27%,55.56%;等离子清洗工艺参数对膜基结合强度有较大影响,随着清洗时间的增加、氩气流量的增大和清洗功率的提高,膜基的结合强度均呈现出先增大后减小的变化趋势。     

Non-Fourier heat conduction in a thin gold film heated by an ultra-fast-laser

Based on the dual-phase-lagging(DPL)heat conduction model,the Cattaneo-Vernotte(CV)model and the improved CV model we investigate the one-dimensional heat conduction in gold films with nano-scale thickness exposed to an ultra-fast laser heating.The influence of system parameters on the temperature field is explored.We find that for all the non-Fourier heat conduction models considered in this work,a larger Knudsen number normally leads to a higher temperature.For the DPL model,the large ratio of the phase lag of temperature gradient to the phase lag of heat flux reduces the maximum temperature and shortens the time for the system to reach its steady state.The CV model and the improved CV model lead to the similar thermal wave behavior of the temperature field,but the thermal wave speeds for these two models are different,especially for large Knudsen numbers.When the phase lag of temperature gradient is smaller,the difference between the DPL model and the improved CV model is not significant,but for the large phase lag of temperature gradient the difference becomes quite significant,especially for the large Knudsen number.In addition,the effect of the surface accommodation coefficient,which is a parameter in the slip boundary condition,on the temperature field of the gold film heated by ultra-fast laser pulses is investigated based on the DPL model.     

加固新增设备钢结构厂房的有限元分析

由于目前越来越多的工业厂房需要增加新的使用功能,而增加的设备荷载已经超过原结构的正常使用承载能力,故需对原钢结构进行加固。本文采用钢梁底部附加预应力筋和钢梁底部加设支撑方法。为了验证此两种加固方法的可行性,并分析出最优方案,本文以山西某电力设备有限公司新建工业区工程项目为例采用了有限元分析软件ANSYS12.0对两种加固方案进行数值模拟。对两种方法在施加相同的荷载作用下对结构的受力性能进行分析。结果表明,预应力筋加固法不仅能极大的满足结构的应力变形要求,而且省工省料,施工难度小,重量更轻,所以预应力筋法比增设支撑法更合适。预应力筋加固法是未来钢结构加固方法的趋势。     

MBR-CANON工艺处理生活污水的快速启动及群落变化

为研究全程自养脱氮工艺(CANON)处理生活污水的可行性,在常温膜生物反应器（MBR）中,保持进水氨氮不变,采用逐渐缩短水力停留时间(HRT)的策略在限氧条件下快速富集氨氧化菌(AOB),之后减小曝气量并进一步缩短HRT富集厌氧氨氧化菌(anammox),并通过DGGE技术分析不同阶段的种群变化．结果表明：CANON工艺在78 d内成功启动,总氮去除率达80％,总氮去除负荷RNR达0.95 kg·m-3·d-1;将该工艺应用于生活污水的处理,实现了COD和氨氮的同时高效去除;微生物群落发生了较大变化,稳定运行的反应器中氨氧化细菌为亚硝化单胞菌属(Nitrosomonas),厌氧氨氧化菌为Candidatus Kuenenia stuttgariensis．MBR-CANON工艺可以有效应用于常温生活污水的脱氮．     

A new two-staged model to predict corrosion degree of steel bars in cracked concrete area

In order to quantitatively describe the local corrosion process of steel bars in cracked concrete area, a new two-staged utility model is established, and the effect of transverse cracks on the reinforcement corrosion is analyzed from the angle of long-term service performance evaluation for reinforced concrete structure. Moreover, based on the principle of spectral analysis for environmental action of concrete, an equivalent relationship is established between the corrosion rate in the natural environment and that under the standard temperature and relative humidity condition according to the principle of equivalent annual corrosion depth. Comparison between the inspection results from some references and the calculated values by the twostaged utility model validates the feasibility of the proposed model. The model was applied to Chinese Railway Track System(CRTS)Ⅱ ballastless track slab with transverse dummy joints, from which satisfactory results of corrosion degree of steel bars were obtained.     

Leaching Stability of Simulated Waste Forms for Immobilizing An3＋ by Gd2Zr2O7 with Nd3＋

In order to investigate the anti-leaching capability of pyrochlore Gd2Zr2O7 immobilized An3+, trivalent neodymium was used as the simulacrums for radioactive wastes with trivalence, Gd2-xNdxZr2O7(0.0x 2.0) series samples were successfully synthesized by high temperature solid reaction and using Gd2O3, Zr O2 powders as starting materials. The experiments of long-term chemical stability were conducted in synthetic seawater at 40 and 70 ℃. The XRD diffractive data and extraction ratio of as-received samples were collected with the help of X-ray diffraction(XRD) instrument and inductively coupled plasma mass spectrometry(ICPMass). The results indicate that the phases of as-received compounds keep the single phase of pyrochlore. The extraction ratio of Gd3+, Zr4+ and Nd3+ in waste forms is increasing with the increase of immersion time in synthetic seawater. The extraction ratio of waste forms at 70 ℃ is higher than at 40 ℃. The highest extraction ratio of Gd3+, Zr4+ and Nd3+ after 42 days is near 0.025 8, 0.003 8 and 0.045 2 μg·m L-1, respectively.     

逐步增加定数截尾下Weibull 分布恒加试验的Bayes估计

基于逐步增加定数截尾样本,对累积失效模型(简称CE模型)下,Weibull分布恒定应力加速寿命试验(简称恒加试验)进行了Bayes统计分析,利用Gibbs抽样给出了该模型的Bayes估计。最后,通过模拟例子表明Bayes估计有效而实用。