Surface characterization of PET nonwoven fabric treated by He/O2 atmospheric pressure plasma

The surface of polyethyleneterephthalate (PET) nonwoven fabric was modified by He/O₂ atmospheric pressure plasma treatment, varying plasma exposure time. The plasma treated PET surfaces have been analyzed to investigate the chemical nature and morphology of surface by X‐ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM), respectively. The change of wettability was measured depending on plasma exposure time. XPS results indicated the presence of oxygen‐based functional groups on the PET nonwoven fabric surface after plasma treatment and oxygen content increased as exposure time increased. The mean roughness increased after 30 s exposure and further increase in exposure to 60 s led to decrease of the roughness and then again increase. The root mean square roughness followed the similar trend to mean roughness. The average difference in height, Rz, increased after plasma exposure for 30 s, while it slightly decreased after 60 s exposure. Despite of redeposition, the Rz of 90 s exposed sample increased more than two times compared with those of 30 and 60 s exposed. Wettability increased progressively up to 10 times after 90 s exposure compared with the untreated. It is attributed to the increases of hydrophilicity and surface roughness. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Structure and processability of iodinated poly(vinyl alcohol). IV. Drawability of the films iodinated at solution before casting

The drawability of iodinated at solution before casting (IBC) polyvinyl alcohol films prepared by casting aqueous solutions of 10 wt % PVA containing 15.2, 39.8, 83.2, 117.0, and 140.1% was examined with a tensile tester at 20–60°C. The tensile behavior of IBC films showed that the yield and breaking loads were much lower, and the breaking elongation was even higher than those of the unoriented iodinated after casting (IAC) films as well as the untreated PVA films. The maximum draw ratios of the films with the weight gain of 15.2, 39.8, 83.2, 117, and 140.1% were 4.5, 5.5, 8.5, 8.0, and 7.5, respectively, which were achieved at 20°C in all. The crystallinity of all films increased by the maximum draw, regardless of crystallinity before drawing. The crystalline structure was recovered to the original PVA crystalline lattice by deiodination. Amorphous orientation and initial moduli increased with the maximum draw ratio, while the orientation of crystals was constant. The orientation and moduli increased up to the weight gain of 83.2%, whose highest draw ratio and initial modulus were 8.5 and of 7.1 GPa, respectively, and then decreased. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Polysaccharide‐based artificial extracellular matrix: Preparation and characterization of three‐dimensional,macroporous chitosan,and heparin composite scaffold

Scaffold‐guided tissue engineering based on synthetic and natural occurring polymers has gained many interests in recent year. In this study, the development of a chitosan‐heparin artificial extracellular matrix (AECM) is reported. Three‐dimensional, macroporous composite AECMs composed of heparin (Hep) and chitosan (Chito) were prepared by an interpolyelectrolyte complex/lyophilization method. The Chito‐Hep composite AECMs were, respectively, crosslinked with glutaraldehyde, as well as cocrosslinked with N,N‐(3‐dimethylaminopropyl)‐N′‐ethyl carbodiimide (EDC/NHS) and N‐hydroxysuccinimide (NHS). The crosslinking reactions were examined by FT‐IR analysis. In physiological buffer solution (PBS), the EDC/NHS‐crosslinked Chito‐Hep composite AECM showed a relative lower water retention ratio than its glutaraldehyde‐crosslinked counterparts. The EDC/NHS‐crosslinked Chito‐Hep composite AECMs showed excellent biocompatibility, according to the results of the in vitro cytotoxic test. This result suggested that the EDC/NHS‐crosslinked Chito‐Hep composite AECMs might be a potential biomaterial for scaffold‐guided tissue engineering applications. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Manufacturing and structural safety evaluation of a composite train carbody

This paper explains the manufacturing process of a composite train carbody with a sandwich composite structure for bodyshell and a stainless steel structure for the under frame. In addition, the structural behavior and safety of the composite carbody of the Korean tilting train was investigated by the static load tests. From the test results, the stiffness of the composite carbody met the specified design. In the aspect of strength, the maximum stress of the composite bodyshell was of 12.2% of strength of CF1263 carbon/epoxy.     

An interactive multiple-response simulation optimization method

This study proposes a new interactive multicriteria method for determining the best levels of the decision variables needed to optimize a stochastic computer simulation with multiple response variables. The method, called the Pairwise Comparison Stochastic Cutting Plane (PCSCP) method, combines good features from interactive multiple objective mathematical programming and response surface methodology. The major characteristics of the PCSCP method are: (1) it interacts progressively with the decision-maker (DM) to obtain her preferences, (2) it uses experimental design to explore the decision space adequately while reducing the burden on the DM, and (3) it uses the preference information provided by the DM and the sampling error in the responses to reduce the decision space. The mechanics of the method are illustrated with a numerical example. Some computational studies evaluating the method are also reported.     

Parasitic Bipolar Junction Transistors in a Floating-Gate MOSFET for Fluorescence Detection

In this letter, we examined whether the parasitic bipolar junction transistors (BJTs) in the MOSFET fabricated by the standard CMOS process can play a role as a fluorescence detector. To suppress the action of two vertical parasitic BJTs, the gate and n-well were tied in the parasitic BJTs, and the body node was connected to the drain. The proposed device was compared with the inherent and the parasitic diodes in the MOSFET. It had 100 times higher photocurrents than the diodes in the MOSFET. In addition, it was applied for the detection of the fluorescent signal, and could detect near 10 nM of Alexa 546. Therefore, CMOS-process-compatible parasitic BJTs can be used as a photodetector in an integrated fluorescence detector.     

Study of the Interfacial Reaction of Styrene/Maleic Anhydride Copolymerand (Amine)-Terminated Butadiene-Acrylonitrile Copolymer Using FTIR Imaging Techniques

The interfacial reaction between styrene/maleic anhydride copolymer (SMA) and amine-terminated butadiene-acrylonitrile copolymer (ATBA) was observed using Fourier transform infrared (FTIR) imaging spectroscopy. The anhydride and amine reacted to form an imide. Each component was detected using a characteristic wavenumber, which was 1601 cm -1 for SMA, 2237 cm -1 for ATBA, and 1701 cm -1 for the imide. FTIR images were taken as the reaction proceeded at 150, 160, 170, and 180°C. At low temperatures (150 and 160°C), diffusion-controlled kinetics were observed since interdiffusion between the reactants did not appear in the images. On the other hand, both the diffusion front and the reaction front are observed in the images at high reaction temperatures (170 and 180°C), which indicates that the kinetics became reaction-controlled rather than diffusion-controlled. Absorbance profiles were extracted from the images and used for the calculation of the extent of reaction. The data were analyzed using the Frederickson and Milner theory based on the assumption of diffusion-controlled kinetics, and this theory fit the low reaction temperature data.     

Solution copolymerization of methyl methacrylate and alkyl methacrylates in a continuous stirred tank reactor(CSTR)

Continuous solution copolymerization of methyl methacrylate with ethyl methacrylate or n-butyl methacrylate was carried out in a continuous stirred tank reactor. Solvent and initiator used were toluene and benzoyl peroxide, respectively. Reaction volume was 1.2 litters, residence time 3 hours and polymerization temperature 80°C. The copolymerization conversions were analyzed by UV spectrophotometry and confirmed by measuring the solid weights of copolymers obtained after evaporating solvent. The copolymerization of methyl methacrylate and alkyl methacrylates followed the second order kinetics. The simulated conversions and copolymerization rates were compared with the experimental results. The average time to reach dynamic steady-state was three and half times of the residence time.     

Robust Geodesic Regression

International Journal of Computer Vision - This paper studies robust regression for data on Riemannian manifolds. Geodesic regression is the generalization of linear regression to a setting with a...     

Development of a sequential robust–tolerance design model for a destructive quality characteristic

Robust design (RD) and tolerance design (TD) have received much attention from researchers and practitioners for more than two decades, and a number of methodologies for modeling and optimizing the RD and TD processes have been studied. However, there is ample room for improvement. Because most existing research considers RD and TD as separate research fields, the primary objective of this paper is to develop a sequential robust–tolerance design method to jointly determine the best factor settings and the closed-form solutions for the optimal specification limits. We then apply the proposed method to a destructive quality characteristic. Finally, a case study and sensitivity analyses are performed for verification purposes, and further studies are discussed.