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51.
Sebastian Wilken Dorothea Scheunemann Staffan Dahlström Mathias Nyman Jürgen Parisi Ronald Österbacka 《Advanced Electronic Materials》2021,7(5):2001056
Suppressing charge recombination is key for organic solar cells to become commercial reality. However, there is still no conclusive picture of how recombination losses are influenced by the complex nanoscale morphology. Here, new insight is provided by revisiting the P3HT:PCBM blend, which is still one of the best performers regarding reduced recombination. By changing small details in the annealing procedure, two model morphologies are prepared that vary in phase separation, molecular order, and phase purity, as revealed by electron tomography and optical spectroscopy. Both systems behave very similarly with respect to charge generation and transport, but differ significantly in bimolecular recombination. Only the system containing P3HT aggregates of high crystalline quality and purity is found to achieve exceptionally low recombination rates. The high-quality aggregates support charge delocalization, which assists the re-dissociation of interfacial charge-transfer states formed upon the encounter of free carriers. For devices with the optimized morphology, an exceptional long hole diffusion length is found, which allows them to work as Shockley-type solar cells even in thick junctions of 300 nm. In contrast, the encounter rate and the size of the phase-separated domains appear to be less important. 相似文献
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Frederik Kotz Patrick Risch Dorothea Helmer Bastian E. Rapp 《Advanced materials (Deerfield Beach, Fla.)》2019,31(26)
3D printing has emerged as an enabling technology for miniaturization. High‐precision printing techniques such as stereolithography are capable of printing microreactors and lab‐on‐a‐chip devices for efficient parallelization of biological and biochemical reactions under reduced uptake of reactants. In the world of chemistry, however, up until now, miniaturization has played a minor role. The chemical and thermal stability of regular 3D printing resins is insufficient for sustaining the harsh conditions of chemical reactions. Novel material formulations that produce highly stable 3D‐printed chips are highly sought for bringing chemistry up‐to‐date on the development of miniaturization. In this work, a brief review of recent developments in highly stable materials for 3D printing is given. This work focuses on three highly stable 3D‐printable material systems: transparent silicate glasses, ceramics, and fluorinated polymers. It is further demonstrated that 3D printing is also a versatile technique for surface structuring of polymers to enhance their wetting performance. Such micro/nanostructuring is key to selectively wetting surface patterns that are versatile for chemical arrays and droplet synthesis. 相似文献
54.
Frederik Kotz Norbert Schneider Andreas Striegel Andre Wolfschläger Nico Keller Matthias Worgull Werner Bauer Dieter Schild Marcel Milich Christian Greiner Dorothea Helmer Bastian E. Rapp 《Advanced materials (Deerfield Beach, Fla.)》2018,30(22)
Fused silica glass is one of the most important high‐performance materials for scientific research, industry, and society. However due to its high chemical and thermal resistance as well as high hardness, fused silica glass is notoriously difficult to structure. This work introduces Glassomer, a solid nanocomposite, which can be structured using polymer molding and subtractive technologies at submicrometer resolution. After polymer processing Glassomer is turned into optical grade fused silica glass during a final heat treatment. The resulting glass has the same optical transparency as commercial fused silica and a smooth surface with a roughness of a few nanometers. This work makes high‐performance fused silica glass components accessible to high‐throughput fabrication technologies and will enable numerous optical, photonic and medical applications in science and industry. 相似文献
55.
Anna Dorothea Schulze Melanie Janina Christine Stade Janine Netzel 《Creativity & Innovation Management》2014,23(1):57-75
Research on social conflicts in innovation processes has been rare, leaving an important research gap, as conflicts often arise in innovation processes and are even part of a researcher's everyday life. This study examines innovation and the variables of innovation success in the life sciences; it tests a conflict management model and examines the impact of both conflict type and conflict management style on innovation performance. This study surveyed 152 basic and applied researchers on their conflict management style through a multi‐method approach incorporating both survey and qualitative methods. The substantive aspects and relational effectiveness of conflict management styles were compared, considering their number of publications and patents, problem solution quality, project newness, conflict de‐escalation and communication. Applied researchers showed significantly more domination than did basic researchers, and a dominating conflict management style was significantly related to project newness. Moreover, problem solving was not always the most successful conflict management style. These findings have important practical implications for conflict management training and can help managers and researchers strengthen their co‐operation and improve productivity. 相似文献
56.
Traditionally, the quality of orthogonal planar drawings is quantified by either the total number of bends, or the maximum number of bends per edge. However, this neglects that in typical applications, edges have varying importance. In this work, we investigate an approach that allows to specify the maximum number of bends for each edge individually, depending on its importance. We consider a new problem called FlexDraw that is defined as follows. Given a planar graph G=(V,E) on n vertices with maximum degree 4 and a function $\operatorname{flex}: E \longrightarrow\mathbb{N}_{0}$ that assigns a flexibility to each edge, does G admit a planar embedding on the grid such that each edge e has at most $\operatorname{flex}(e)$ bends? Note that in our setting the combinatorial embedding of G is not fixed. FlexDraw directly extends the problem β-embeddability asking whether G can be embedded with at most β bends per edge. We give an algorithm with running-time O(n 2) solving FlexDraw when the flexibility of each edge is positive. This includes 1-embeddability as a special case and thus closes the complexity gap between 0-embeddability, which is $\mathcal{NP}$ -hard to decide, and 2-embeddability, which is efficiently solvable since every planar graph with maximum degree 4 admits a 2-embedding except for the octahedron. In addition to the polynomial-time algorithm we show that FlexDraw is $\mathcal{NP}$ -hard even if the edges with flexibility 0 induce a tree or a union of disjoint stars. 相似文献
57.
This study attempted to examine whether chronic schizophrenic patients could effectively engage in the manipulative strategy of impression management in an evaluative interview situation. The data supported the expectation that schizophrenic mental patients can effectively present themselves as "sick" or "healthy," whichever is more suited to their needs and goals. Thus, when the patients' open ward status was questioned, they convincingly presented themselves in the interview as "healthy" and eligible for open ward living; when their residency status was questioned, they convincingly presented themselves as "sick" and ineligible for discharge. These findings were interpreted as supporting assumptions of patient effectiveness in implementing goals. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
58.
Dorothea Ehlers Michael Pfister Wolf -Rainer Bork Peter Toffel-Nadolny 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1995,201(3):278-282
Based on the results of GC-MS analysis, an HPLC procedure was developed for the determination of coumarin, dihydrocoumarin, melilotic acid (o-dihyd-rocoumaric acid), methyl melilotate, ethyl melilotate, 5-hydroxymethylfurfural ando-coumaric acid which are characteristic compounds of tonka beans. The presence of melilotic acid and ethyl melilotate in tonka beans has not been reported previously. Following HPLC analysis of tonka bean extracts produced in the laboratory and one sample of commercially available tonka bean absolute, evidence was provided that solvents used for production are decisive for the kind and amount of the compounds detected. 相似文献
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