Boiling from metal surfaces immersed in liquid nitrogen and liquid hydrogen

A study of bubble nucleation in liquid nitrogen and liquid hydrogen has been made in a 120 mm bubble chamber using a high speed cine camera.The initiation and growth of bubbles from artificially prepared cavities was studied. These cavities, produced in both copper and brass surfaces, had mouth radii ranging from 50 μm to 190 μm with depths varying from 110 μm to 500 μm. The liquids were superheated by either heating the surface containing the cavities or by reducing the pressure of the liquid, or by combining both of these methods.The heat fluxes required for initiation of boiling were greater than those required to sustain nucleation from a given site. The growth rate of the bubbles at constant liquid pressure was dependent on a number of factors. It changes as a bubble grew out of the thermal or superheated layer above the metal surface. After an initial period of more rapid growth the vapour volume increased linearly with time. The growth rate was dependent on the liquid used; being slower in liquid hydrogen than in liquid nitrogen. Formulae were obtained which predicted the observed variations in growth rate and departure volume.No nucleation was observed from the test surfaces for a pressure drop alone; the surfaces had to be heated before nucleation would occur. It is thought that this was due to the existence of a zero contact angle for cryogenic liquids on solid surfaces.     

Radionuclide biokinetics database (RBDATA-EULEP): an update

The main activity of the RBDATA-EULEP project is the development of an electronic database of information on the biokinetics of radionuclides after intake by inhalation, ingestion or injection. It consists of linked tables of publications and experiments, with details and comments on the materials, procedures and results. By March 2004 it contained information on more than 1600 experiments from 600 publications. It will be extended and Internet access will also be provided.     

Design and display of enhancing information in desktop information-rich virtual environments: challenges and techniques

Information-rich virtual environments (IRVEs) have been described as environments in which perceptual information is enhanced with abstract (or symbolic) information, such as text, numbers, images, audio, video, or hyperlinked resources. Desktop virtual environment (VE) applications present similar information design and layout challenges as immersive VEs, but, in addition, they may also be integrated with external windows or frames commonly used in desktop interfaces. This paper enumerates design approaches for the display of enhancing information both internal and external to the virtual worlds render volume. Using standard Web-based software frameworks, we explore a number of implicit and explicit spatial layout methods for the display and linking of abstract information, especially text. Within the VE view, we demonstrate both heads-up-displays (HUDs) and encapsulated scenegraph behaviors we call semantic objects. For desktop displays, which support information display venues external to the scene, we demonstrate the linking and integration of the scene with Web browsers and external visualization applications. Finally, we describe the application of these techniques in the PathSim visualizer, an IRVE interface for the biomedical domain. These design techniques are relevant to instructional and informative interfaces for a wide variety of VE applications.     

Nonaqueous potentiometry of coal-derived asphaltenes and model nitrogen-containing compounds in acetophenone and nitrobenzene

A series of 34 nitrogen-containing compounds with a wide range of basicities was examined under differential nonaqueous potentiometric conditions in acetophenone and nitrobenzene. These compounds could be resolved into five classes based on pK_aand half-neutralization-potential (HNP) values. Asphaltenes isolated from the vacuum still overhead (VSO) and vacuum still bottoms (VSB) fractions of the H-coal process were titrated under similar conditions. The titration results of both asphaltenes indicated the presence of two classes of nitrogen-containing compounds, a titratable class of the pyridine-ring or aniline type and a nontitratable class.     

Long spacings of six alkyl esters of two octadecenoic acids

X-ray powder diffraction data are presented for some normal alkyl esters of two octadecenoic acids. The crystal long spacings observed for esters of elaidic acid are shown to be linearly related to the length of the carbon chain of the ester group. Little difference in crystal long spacings was observed between esters ofcis andtrans acids. Melting points of alkyl esters of elaidic acid are reported.     

Determination of Pb complexation in oxic and sulfidic waters using pseudovoltammetry

Pseudovoltammetry was used to evaluate the actual Pb complexation occurring in natural water samples of varying oxygen and sulfide concentration. In pseudovoltammetry, the potential at which metal-ligand complexes are broken up to form the metal amalgam is used to determine the complexes' thermodynamic stability constants (KTHERM; corrected for metal and ligand side reaction coefficients) via the Nernst expression. This methodology removes the need for any metal additions and for subsequent modeling using fitting criteria, which provide only conditional stability constant data (KCOND). Using known organic ligands, a chelate scale ranging from log KTHERM = 4 to log KTHERM = 20 was developed as a template for comparison with samples collected from two stations of different salinities and at several depths in the Chesapeake Bay. These samples were observed to contain up to five different ligand compounds of unknown structural composition (log KTHERM > 8) with the strongest ligand fraction exceeding log KTHERM > 39 (the maximum observable thermodynamic stability constant due to the reduction of Na+). One possible explanation for the observed complexation is the existence of lead sulfide clusters. This was supported by laboratory experiments using electrochemistry and ICR-FTMS, which confirmed the formation of electrochemically inert multinuclear clusters with high stability constants (e.g., M3S3, log KTHERM = 62.9). However, in all field samples, (sub)nanomolar levels of acid-leachable sulfide were recovered at pH 5.0-6.2, which could be attributed to dissociation of lead sulfide complexes with moderate acidity. Recovery of sulfide increased from < 10% of the total dissolved Pb concentration (Pbdiss) in surface waters to 100% of the Pbdiss in the sulfide-rich bottom waters at the higher salinity location.     

An analysis of a puncture wound case with medical intervention

A worker noted a small wound to his thumb when leaving a work site that was undergoing decontamination because of past operations with plutonium (Pu) and americium (Am). Direct surveys of the wound site confirmed the presence of contamination. The chelating agent Ca-DTPA was administered via a nebuliser within an hour after discovery of the wound. External measurements were made of the wound site and wound dressings; 24-h urinary excretion data were collected periodically and the Pu and Am urine content was determined. Zn-DTPA was administered on three occasions. The ICRP Pu systemic model was modified to consider the enhanced urinary excretion following administration of the chelating agents. The analysis indicated that the wound resulted in an initial deposition of 400 Bq 238Pu, 2240 Bq (239/240)Pu and 1060 Bq 241Am. About 70% of the initial wound activity was removed by surgical procedures and less than 1% of the wound activity was removed by chelation therapy. This paper compares the observed urinary excretion data with that indicated by a simulation of the kinetics of the transfer from the wound site and the kinetics of the chelating agent and Pu.     

Lessons learned from interlaboratory comparisons of bioassay data interpretation

When a set of bioassay data is given to two different dosimetrists, it is likely that these data will be interpreted differently, that different methods and dosimetric models will be applied and therefore different numerical values will be obtained. Thus, it is important for laboratories dealing with internal dosimetry to undergo performance testing procedures such as interlaboratory comparisons of bioassay data interpretation. Several intercomparison exercises have already been organised at national and international levels. The largest one so far was the 3rd European Intercomparison Exercise on Internal Dose Assessment, which has been organised in the framework of the EULEP/EURADOS Action Group, 'Derivation of parameter values for application to the new model of the human respiratory tract for occupational exposure'. The most important lesson learned from these intercomparison exercises was the need to develop agreed guidelines for internal dose evaluation procedures to promote harmonisation of assessments between organisations and countries.     

Application of avidin-biotin technology and adsorptive transfer stripping square-wave voltammetry for detection of DNA hybridization and avidin in transgenic avidin maize

The proteins streptavidin and avidin were electrochemically detected in solution by adsorptive transfer stripping square wave voltammetry (AdTS SWV) at a carbon paste electrode (CPE). AdTS SWV was used to quantify biotinylated oligonucleotides, DNA hybridizations, and avidin in extracts of transgenic avidin maize. The detection limits of denatured and native streptavidin were 6 pM and 120 nM, respectively. The results demonstrated that streptavidin/avidin AdTS SWV is a sensitive and specific method for quantifying DNA and proteins in biological samples such as foods and tissue extracts, including genetically modified crops (avidin maize) and other plants in neighboring fields.     

Estimation of the protein content of US imports of milk protein concentrates

Recent declines in milk prices in the United States have sparked renewed concern that imports of milk protein concentrates (MPC) are increasingly entering the United States with very low tariff rates and is having an adverse impact on the US dairy industry. Milk protein concentrates are used in the United States in many different products, including the starter culture of cheese, or in nonstandard cheeses such as baker's cheese, ricotta, Feta and Hispanic cheese, processed cheese foods, and nutritional products. One of the difficult aspects of trying to assess the impact of MPC imports on the US dairy industry is to quantify the protein content of these imports. The protein content of MPC imports typically ranges from 40 to 88%. The purpose of this study is to develop a methodology that can be used to estimate the protein content of MPC on a country by country basis. Such an estimate would not only provide information regarding the quantity of protein entering the United States, but would also provide a profile of low- and high-value MPC importers. This is critical for market analysis, since it is the lower valued MPC imports that more directly displaces US-produced skim milk powder.