941.
Our earlier experimental studies of the solid-phase reduction of disseminated lump ores demonstrate that an oxide lattice transforms into a metal lattice via the saturation of the oxide crystal lattice by charged oxygen vacancies. Low-charge metal cations appear in the oxide crystal lattice, and they are related to oxygen vacancies by the condition of local electrical neutrality. As oxygen vacancies are accumulated (i.e., during reduction), the number of oxygen vacancy-low charge cation complexes in the initial oxide increases. The total composition of the oxide phase in the range of a crystal lattice of a certain type changes continuously from the initial oxide to the end product of reduction, i.e., to the lower oxide or a metal. Therefore, it is necessary to determine the thermal characteristics of not only all possible stoichiometric compounds in the
M-O system but also
MO
x oxides of variable compositions. Equations for calculating the standard heat capacities of complex stoichiometric oxides and oxides of variable compositions in the Fe-O-Ti system are derived using a mathematical model developed earlier, and these characteristics are calculated.
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