Selective removal of gallium (III) from aqueous solutions containing zinc or aluminum using sodium di-(n-octyl) phosphinate

Gallium was removed selectively from aqueous solutions containing zinc or aluminum using sodium di-(n-octyl) phosphinate as a ligand (NaL). At low pH or low mole ratios, the gallium was removed by complexation with the ligand as GaL(3(S)), while the zinc or the aluminum remained in the solution. Nearly complete separation of gallium was obtained. By increasing the amount of ligand or by increasing the pH, the zinc or aluminum remaining in the solution was then removed as a solid complex: ZnL(2(S)) or AlL(3(S)), respectively. At a pH between 1.5 and 2 and a mole ratio ligand to total metals of 0.75 for zinc solutions and 1.0 for aluminum solutions, more than 98% of the gallium was selectively removed with a high molar selectivity, alpha(Ga/Zn) and alpha(Ga/Al), respectively. Over 95% of gallium was recovered from the solid GaL(3(S)) complex by treatment of the complex with a 3M NaOH solution and diethyl ether. The gallium was concentrated in the aqueous solution to 4 times its initial concentration and the ligand was extracted into the ether phase. After evaporation of the ether, 95% of the ligand was regenerated in its sodium form as a solid.     

Detection of enteric viruses, Giardia and Cryptosporidium in two different types of drinking water treatment facilities

In this study, two types of drinking water treatment facilities (two conventional drinking water treatment plants (DWTPs) and two compact units (Cus)) were compared referring to their production capacity. Water samples were collected from three main points: (a) different water treatment steps (b) washings of sand filters and (c) distribution system at different distances from the water treatment plants. Both viruses and protozoa were concentrated from each water sample by adsorption and accumulation on the same nitrocellulose membrane filters (0.45 microm pore size). Enteroviruses were detected by plaque infectivity assay in BGM cells and HAV, HEV and Norovirus were detected by RT-PCR. Giardia and Cryptosporidium were detected by conventional staining methods and PCR. The results revealed that enterovirus load at the intake ranged between 10-15 PFU/L for the two compact units and between 4.5 and 75 PFU/L for the two conventional DWTPs. The virus load in distribution system of the first type DWTPs at 1 km from the plant was the same as that of the intake. Viruses in the other type of treatment plants CUs at 1, 5 and 7 km, were much reduced. Investigation of raw water sediments of the two DWTPs showed enterovirus counts between 12 and 17.5 PFU/L. Virus count was reduced in sand of filters after washing. Giardia cysts were equally detected by microscopy and PCR in only intake samples of EL-Hawamdia CU (33.3%) and Meet Fares DWTP (50%). Cryptosporidium oocysts were equally detected by microscopy and PCR in intake samples of Abo EL-Nomros CU (100%), EL-Hawamdia CU (66.7%) and Fowa DWTP (50%). At Meet Fares DWTP three positive intake samples for Cryptosporidium were detected by PCR, compared with only two positive samples by microscopy. Giardia cysts and Cryptosporidium oocysts were detected in raw water sediment and sand of filters before washing. Only one sample from Meet Fares DWTP sand of filters after washing was positive for both Giardia and Cryptosporidium. It can be concluded that the poor microbial quality of the water may be due to improper operational skills and management of the various water treatment plants (especially at the two high capacity treatment plants).     

Spatial competition and regulatory change in the grain handling and transportation system in western Canada

The grain handling and transportation system (GHTS) has been a defining component of the western Canadian economy since the early part of the last century. Only two major railways serve the grain handling industry, so the potential for the exercise of market power in transportation appears to be significant. In fact, spatially oriented regulations applicable to railways exist in Canada to mitigate this, but to date they have not often been used by shippers. While the reasons for this are not completely clear, we suggest that the regulations are now inadequate for the current state of the GHTS. Using a unique data set from the year 2000, we assess the effect on the grain handling industry of modifications to these regulations, and find that significant gains for shippers from these modifications are possible. These gains are computed to be on the order of C$10–15 million per year for grain shippers alone. We would like to thank conference and presentation participants (Transportation Research Board, Canadian Agricultural Economics Society, University of British Columbia, University of Leeds and California State University, Long Beach) as well as the anonymous reviewers who commented on the earlier versions of this paper. We would also like to acknowledge support from the Saskatchewan Department of Highways.     

Synthesis of ettringite: a way to deal with the acid wastewaters of aluminium anodising industry

Synthesis of ettringite from acid wastewaters of the aluminium anodising industry has been studied as a possible route of reducing the emissions to the environment, recovering at the same time resource materials as a useful marketable mineral. Wastewaters of different concentrations have been subjected to the process of synthesis suspending calcium oxide and calcium aluminate powders at different time and pH conditions. High caustic alkalinity (pH approximately 12) and low sulphate concentrations (<0.1 M) are the most suitable conditions to synthesise ettringite. The mineral characterisation has been performed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and differential thermal analysis (DTA), proving the high purity of the pursued solid product when hydrated in the appropriate sodium hydroxide concentrations. In such conditions, around 90% of the aluminium initially present in the wastewater solutions is recovered in the form of ettringite.     

Finite element modelling of plate girders with web openings

This paper is concerned with a finite element model to predict the behaviour and ultimate load of plate girders with web openings. The finite element package is used to model the plate girders with web openings. Accuracy of the model is assessed by applying it to plate girders tested earlier by other researchers. Comparison of analytical results with the available experimental results for yielding patterns, ultimate load values and load–deflection relationships show good agreement between the finite element and experimental results thus validating the accuracy of the proposed model. The proposed finite element method was extended to carry out a parametric study. The study covered parameters such as web slenderness and flange stiffness.     

Observations on the changes in nitrate concentrations along streams in seven upland moorland catchments in Northeast Scotland

River water has been sampled under baseflow conditions in both summer and winter at c. 250-m intervals along the length of each of seven rivers in northeast Scotland, and the nitrate contents have been determined. The resultant data have been examined in the context of the nitrogen saturation hypothesis. Capacity of the catchment soils to retain nitrate was generally minimal in winter. Although biological uptake of nitrate was evident in summer, in the upper part of each catchment substantial nitrate leaching still occurred. The phenomenon was most marked in water draining from hill peats, except where these were conspicuously waterlogged. The results are discussed in the context of possible nitrogen saturation effects on upper catchment slopes.     

Vs and Vp cross hole measurements by automatic generators

Bulletin of Engineering Geology and the Environment - The large extension, in the last few years, of propagation velocity measurements of shear and compression waves for the determination of...     

渗透结晶型防水涂料及其应用

介绍渗透结晶型防水涂料的性质、特征,以及在地下室工程中的应用     

浅谈城市火灾自动报警监控管理系统

阐述了城市火灾自动报警监控管理系统的组成、工作原理及主要功能 ,介绍了数据采集和现场网络视频图像显示功能的设计。