Synergistic effect of Pt or Pd and perovskite oxide for water gas shift reaction

The water gas shift (WGS) reaction over Pt and Pd catalysts supported on various perovskite oxides has been investigated at 573 K without catalyst pretreatment. The Pt and Pd catalysts on LaCoO₃ support showed high catalytic activity. Interaction between Pt or Pd and the support is considered to promote the WGS reaction: Pt/LaCoO₃ had high initial activity but deactivated immediately; Pd/LaCoO₃ was less active than Pt/LaCoO₃, but had superior stability. Catalysts were characterized using XRD, STEM, XPS, and H₂-temperature programmed reduction (TPR). Results of this study showed that reduction of the support decreased the CO conversion on Pt/LaCoO₃. On the other hand, Pd/LaCoO₃ showed stable activity for the WGS reaction. Therefore, Pd was added to Pt/LaCoO₃ for stabilizing the catalyst activity, and 0.5 wt.% Pd/1 wt.% Pt/LaCoO₃ catalyst showed higher activity and stability.     

Decision methodology of end-milling conditions using data-mining

The purpose of the present study is to apply data-mining methods to support the decision of reasonable cutting conditions. Although an enormous amount of information is listed in a catalog, it is not possible to know all of it. Seen from the viewpoint of the user, this enormous amount of information becomes a hindrance. For example, even if an expert worker does not look at a catalog, in end-mill processing, he can decide the appropriate processing condition efficiently from experience; however, this type of situation creates difficult problems for an unskilled worker or a skilled worker with little experience. The recommended cutting condition for every type of material is listed in a catalog together with the appropriate tool, but it takes much time and labor to search and examine the catalog to find the right tool, and this process is inefficient. The main subject of our research was to support the processing condition of the end-mill for each precision tool efficiently based on end-mill clusters. Our research applied the techniques of data mining, in particular, non-hierarchy clustering and hierarchy clustering, to catalog data. With these techniques, we applied multiple regression analysis and reached the following main conclusions. As a first step, we paid attention to the shape element of catalog data. In addition to using conventional mining processes, we grouped end-mills from the viewpoint of tool shape, which meant the ratio of dimensions, visually by applying the K-means method. We applied variable cluster analysis next to each cluster and extracted an predictor variable to represent each cluster, and we performed multiple regression analysis and derived a cutting condition decision formula. The cutting condition decision formula provided high accuracy. The accuracy was higher than the results achieved through mining of all data. A more highly precise processing condition decision formula was derived by doing mining again, excluding the peculiar data clusters such as small diameter end-mill. We understood what was effective for cutting condition decision to be factors related to blade length and the ratio of the full length, factors which have not been singled out through background knowledge or expert knowledge, but were noticed as an effect of catalog mining.     

Travel Time Reliability in Vehicle Routing and Scheduling with Time Windows

This paper presents calibration of the Vehicle Routing and scheduling Problems with Time Windows-Probabilistic (VRPTW-P) model which takes into account the uncertainty of travel times. Probe vehicle data of travel times were obtained from usual operation of pickup-delivery trucks in South Osaka area. The optimal solution of the VRPTW-P model resulted in reducing total cost, running times and CO₂, NOx and Particle Materials (PM) emissions compared with the usual operation. This is attributed to better routing of VRPTW-P to choose more reliable roads. Therefore, VRPTW-P can contribute to establish efficient and environmentally friendly delivery systems in urban area.     

Transmission line tower models in frequency domain

This paper proposes a transmission line tower model in frequency domain for back-flashover analysis, which has a uniform characteristic impedance and a uniform propagation constant. Most conventional tower models are constructed as a constant and uniform parameter transmission line that is independent of frequency. However, the authors' models have the frequency dependency of the characteristic impedance and the propagation constant to express the frequency characteristic of the transmission line tower. Two models, a cylinder model and a four-frames model, were investigated to simulate the tower. Their surge responses were computed by numerical electromagnetic field analysis based on the moment method. From the results, the two-port circuit constants were calculated in the frequency domain, and the characteristic impedance and the propagation constant are derived from them. The complex artificial oscillations appeared in frequency dependency of the parameters because the parameters were calculated numerically. The equations with analytical form were obtained by approximating with a smooth curve to the oscillations. It is possible for the equations to represent the transmission line constants as a function of geometrical parameters such as the tower height and the radius. Close agreement was found between the surge response computed by the numerical electromagnetic field analysis and the result calculated by inverse Laplace transformation of the analytical equations. To prove the model, the experimental results were compared with the computed ones of the cylinder model that has arms, and it was shown that the new model agrees closer with the experiment than conventional transmission line models.     

Effect of partial shading on photoproduction of hydrogen by Chlorella

The photoproduction of hydrogen by the green alga Chlorella pyrenoidosa was studied in 650-ml bubble columns made of glass with 7 cm diameter. Hydrogen was produced by adding sodium dithionite as an oxygen scavenger directly to an algal suspension. When a part of the wall of the bubble column was shaded with a sheet of plastic film impervious to light, the production rate and total volume of hydrogen increased as compared to those in the columns without partial shading. This relationship between the hydrogen photoevolution rate and the proportion of lighted region is contrary to normal photochemical reactions. This phenomenon is considered to be related to the regulation by light of the activity of the enzymes and/or the photosynthetic electron transport systems, which was examined by measuring fluorescence induction curves of dark-adapted Chlorella cells and also the distribution of light intensity within the bubble column bioreactors.     

Resonator filters using shear horizontal-type leaky surface acoustic wave consisting of heavy-metal electrode and quartz substrate

The authors have succeeded in exciting a new type of leaky surface acoustic wave (LSAW) having only a shear horizontal (SH) component that has a large electromechanical coupling factor, a large reflection coefficient, and excellent temperature stability, by combining interdigital transducers (IDTs) and reflectors made of heavy-metal films such as gold (Au), tantalum (Ta), and tungsten (W) on the ST-cut 90/spl deg/ X propagation (direction perpendicular to the X-axis) quartz substrate. This LSAW does not have a propagation decay. The square of the electromechanical coupling factor is 2.1-2.7 times larger than, the reflection coefficient is 30 times larger than, and the temperature characteristic is the same as those of a Rayleigh wave on an ST-cut X propagation quartz substrate. The authors applied this SH LSAW to resonators and resonator filters. As a result, we succeeded in developing the low loss and very small-sized resonators and resonator filters (1/5-1/4 of conventional device sizes) with IDTs with a small number of finger pairs and very small reflectors, for the first time.     

A Gait Phase Measurement System Using Treadmill Motor Current

The article describes the development of a gait phase time-based split-belt treadmill measurement system. Conventional methods of measuring gait phase, such as the foot switch and force plate, require significant preparation and are costly. In this article, we propose a simple, cheap, and accurate gait phase measurement system that utilizes only the treadmill motor current value. Comparison of this algorithm with conventional methods reveals that the proposed algorithm is as accurate as the foot switch. Moreover, the proposed algorithm can estimate stance phase within a 0.2?s error of the measured value of the force plate in most cases (four out of five healthy subjects). This accuracy is higher than that of the foot switch which is widely used in the clinical field.     

Group behavior of agents with an emotional model

Recently, there has been much interest in the study of the formation of groups of agents that cause interactions between agents and invent new functions. We gave some agents an action rule based on the interactions of human feelings by using a circumplex model. It had been decided that the parameters of feelings in this model should have only two axes. In this report, eight basic action dimensions and pure feelings on four corresponding axes were given to agents as a model of feelings and actions based on the multiple factor analysis theory of R. Plutchik, and the behavioral characteristics of the group of agents were examined.