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排序方式: 共有362条查询结果,搜索用时 17 毫秒
21.
Asmaa Argoub Rachid Ghezini Cherifa Bachir Bouhadjar Boukoussa Amine Khelifa Abdelkader Bengueddach Peter G. Weidler Rachida Hamacha 《Journal of Porous Materials》2018,25(1):199-205
MIL-101@g-C3N4 nanocomposite was prepared by solvothermal synthesis and used for CO2 adsorption. The parent materials (MIL-101 and g-C3N4) and the MIL-101@g-C3N4 were characterized by X-ray diffraction, argon adsorption/desorption, Fourier transform infrared spectroscopy, thermal analysis (TG/DTA), transmission electronic microscopy, and Energy-dispersive X-ray spectroscopy. The results confirmed the formation of well-defined MIL-101@g-C3N4 with interesting surface area and pore volume. Furthermore, both MIL-101 and MIL-101@g-C3N4 were accomplished in carbon dioxide capture at different temperatures (280, 288, 273 and 298 K) at lower pressure. The adsorption isotherms show that the nanocomposite has a good CO2 adsorption affinity compared to MIL-101. The best adsorption capacity is about 1.6 mmol g?1 obtained for the nanocomposite material which is two times higher than that of MIL-101, indicating strong interactions between CO2 and MIL-101@g-C3N4. This difference in efficacy is mainly due to the presence of the amine groups dispersed in the nanocomposite. Finally, we have developed a simple route for the preparation of an effective and new adsorbent for the removal of CO2, which can be used as an excellent candidate for gas storage, catalysis, and adsorption. 相似文献
22.
A (Ni1/3Co1/3Mn1/3)CO3 precursor with an uniform, spherical morphology was prepared by coprecipitation using a continuously stirred tank reactor method. The as-prepared spherical (Ni1/3Co1/3Mn1/3)CO3 precursor served to produce dense, spherical Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 (0 ≤ x ≤ 0.15) cathode materials. These Li-rich cathodes were also prepared by a second synthesis route that involved the use of an M3O4 (M = Ni1/3Co1/3Mn1/3) spinel compound, itself obtained from the carbonate (Ni1/3Co1/3Mn1/3)CO3 precursor. In both cases, the final Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 products were highly uniform, having a narrow particle size distribution (10-μm average particle size) as a result of the homogeneity and spherical morphology of the starting mixed-metal carbonate precursor. The rate capability of the Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 electrode materials, which was significantly improved with increased lithium content, was found to be better in the case of the denser materials made from the spinel precursor compound. This result suggests that spherical morphology, high density, and increased lithium content were key factors in enabling the high rate capabilities, and hence the power performances, of the Li-rich Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 cathodes. 相似文献
23.
Soroosh Sharifi‐Asl Fernando A. Soto Tara Foroozan Mohammad Asadi Yifei Yuan Ramasubramonian Deivanayagam Ramin Rojaee Boao Song Xuanxuan Bi Khalil Amine Jun Lu Amin Salehi‐khojin Perla B. Balbuena Reza Shahbazian‐Yassar 《Advanced functional materials》2019,29(23)
LiCoO2 is a prime example of widely used cathodes that suffer from the structural/thermal instability issues that lead to the release of their lattice oxygen under nonequilibrium conditions and safety concerns in Li‐ion batteries. Here, it is shown that an atomically thin layer of reduced graphene oxide can suppress oxygen release from LixCoO2 particles and improve their structural stability. Electrochemical cycling, differential electrochemical mass spectroscopy, differential scanning calorimetry, and in situ heating transmission electron microscopy are performed to characterize the effectiveness of the graphene‐coating on the abusive tolerance of LixCoO2. Electrochemical cycling mass spectroscopy results suggest that oxygen release is hindered at high cutoff voltage cycling when the cathode is coated with reduced graphene oxide. Thermal analysis, in situ heating transmission electron microscopy, and electron energy loss spectroscopy results show that the reduction of Co species from the graphene‐coated samples is delayed when compared with bare cathodes. Finally, density functional theory and ab initio molecular dynamics calculations show that the rGO layers could suppress O2 formation more effectively due to the strong C? Ocathode bond formation at the interface of rGO/LCO where low coordination oxygens exist. This investigation uncovers a reliable approach for hindering the oxygen release reaction and improving the thermal stability of battery cathodes. 相似文献
24.
In this paper, we propose an Efficient Secure routing Scheme based on searchable encryption with vehicle Proxy Re-encryption, called ESSPR, for achieving privacy preservation of message in vehicular peer-to-peer social network (VP2PSN). Specifically, the proposed ESSPR scheme consists of six phases: system initializations phase, peer registration phase, document generation phase, document forwarding phase, vehicle proxy re-encryption phase, and document receiving phase. Based on rationale of QoS-based clustering strategy, public key encryption with keyword search, identity based aggregate signature, and proxy re-encryption, ESSPR provides privacy for keyword, privacy for resources, and authentication and data integrity of the demand’s source. In addition, ESSPR is robust against eavesdropping attack, wormhole attack, packet analysis attack, packet tracing attack, and replay attack. Through performance evaluation, we demonstrate the effectiveness of ESSPR in terms of delivery ratio, average delay, average fairness, and detection ratio under malicious peers proportions in VP2PSN. 相似文献
25.
26.
Wei WengZhengcheng Zhang Paul C. RedfernLarry A. Curtiss Khalil Amine 《Journal of power sources》2011,196(3):1530-1536
The derivatives of 1,3-benzodioxan (DBBD1) and 1,4-benzodioxan (DBBD2) bearing two tert-butyl groups have been synthesized as new redox shuttle additives for overcharge protection of lithium-ion batteries. Both compounds exhibit a reversible redox wave over 4 V vs Li/Li+ with better solubility in a commercial electrolyte (1.2 M LiPF6 dissolved in ethylene carbonate/ethyl methyl carbonate (EC/EMC 3/7) than the di-tert-butyl-substituted 1,4-dimethoxybenzene (DDB). The electrochemical stability of DBBD1 and DBBD2 was tested under charge/discharge cycles with 100% overcharge at each cycle in MCMB/LiFePO4 and Li4Ti5O12/LiFePO4 cells. DBBD2 shows significantly better performance than DBBD1 for both cell chemistries. The structural difference and reaction energies for decomposition have been studied by density functional calculations. 相似文献
27.
Amine Ammar Emmanuelle Abisset-Chavanne Francisco Chinesta Roland Keunings 《International Journal of Material Forming》2017,10(4):547-556
Permeability is the fundamental macroscopic material property needed to quantify the flow in a fibrous medium viewed as a porous medium. Composite processing models require the permeability as input data to predict flow patterns and pressure fields. In a previous work, the expressions of macroscopic permeability were derived in a double-scale porosity medium for both Newtonian and generalized Newtonian (shear-thinning) resins. In the linear case, only a microscopic calculation on a representative volume is required, implying as many microscopic calculations as there are representative microscopic volumes in the whole fibrous structure. In the non-linear case, and even when the porous microstructure can be described by a unique representative volume, a large number of microscopic calculations must be carried out as the microscale resin viscosity depends on the macroscopic velocity, which in turn depends on the permeability that results from a microscopic calculation. An original and efficient offline-online procedure was proposed for the solution of non-linear flow problems related to generalized Newtonian fluids in porous media. In this paper, this procedure is generalized to quasi-Newtonian fluids in order to evaluate the effect of extensional viscosity on the resulting upscaled permeability. This work constitutes a natural step forward in the definition of equivalent saturated permeabilities for linear and non-linear fluids. 相似文献
28.
Construction and analytical characterization of Prussian-Blue-based carbon paste electrodes and their assembly as oxidase enzyme sensors 总被引:2,自引:0,他引:2
This paper reports on the development and characterization of Prussian Blue-modified carbon paste electrodes. New methods of matrix modification with Prussian Blue are reported. Two different carbon pastes have been prepared, using mineral oil or solid paraffin, thus obtaining different types of sensors whose behavior toward the electrochemical reduction of hydrogen peroxide has been fully characterized. Results obtained with Prussian Blue-modified electrodes showed a long operational lifetime, an excellent stability in a wide range of pH (3-9), a high sensitivity, and a fast response time. In addition, the coupling of solid carbon paste modified with Prussian Blue and the enzymes glucose oxidase and choline oxidase led to the assembling of biosensors that showed an optimum working range at alkaline pH. 相似文献
29.
Youngchul Cho Nacer-Eddine Zergainoh Sungjoo Yoo Ahmed Amine Jerraya Kiyoung Choi 《Design Automation for Embedded Systems》2007,11(2-3):167-191
In multiprocessor system-on-chip, tasks and communications should be scheduled carefully since their execution order affects
the performance of the entire system. When we implement an MPSoC according to the scheduling result, we may find that the
scheduling result is not correct or timing constraints are not met unless it takes into account the delays of MPSoC architecture.
The unexpected scheduling results are mainly caused from inaccurate communication delays and or runtime scheduler’s overhead.
Due to the big complexity of scheduling problem, most previous work neglects the inter-processor communication, or just assumes
a fixed delay proportional to the communication volume, without taking into consideration subtle effects like the communication
congestion and synchronization delay, which may change dynamically throughout tasks execution. In this paper, we propose an
accurate scheduling model of hardware/software communication architecture to improve timing accuracy by taking into account
the effects of dynamic software synchronization and detailed hardware resource constraints such as communication congestion
and buffer sharing. We also propose a method for runtime scheduler implementation and consider its performance overhead in
scheduling. In particular, we introduce efficient hardware and software scheduler architectures. Furthermore, we address the
issue of centralized implementation versus distributed implementation of the schedulers. We investigate the pros and cons
of the two different scheduler implementations. Through experiments with significant demonstration examples, we show the effectiveness
of the proposed approach. 相似文献
30.