Liquid-Liquid Extraction of Uranium(VI) from Aqueous Solution using 1-Hydroxyalkylidene-1,1-diphosphonic Acids

The extraction of uranium(VI) from aqueous solutions has been investigated using 1-hydroxyhexadecylidene-1,1-diphosphonic acid (HHDPA) and 1-hydroxydodecylidene-1, 1-diphosphonic acid (HDDPA), which were synthesized and characterized by elemental analysis and by FT-IR, ¹H NMR, ³¹P NMR spectroscopy. In this article, we propose a tentative assignment for the shifts of those two ligands and their specific complexes with uranium(VI). We carried out the extraction of uranium(VI) by HHDPA and HDDPA from [carbon tetrachloride?+?2-octanol (v/v: 90%/10%)] solutions. Various factors such as contact time, pH, organic/aqueous phase ratio, and extractant concentration were considered. The optimum conditions obtained were: contact time?=?20 min, organic/aqueous phase ratio?=?1, pH value?=?3.0, and extractant concentration?=?0.3 M. The extraction yields are more significant in the case of the HHDPA which is equipped with a hydrocarbon chain, longer than that of the HDDPA. Logarithmic plots of the uranium(VI) distribution ratio vs. pH_eq and the extractant concentration showed that the ratio of extractant to extracted uranium(VI) (ligand/metal) is 2:1. The formula of the complex of uranium(VI) with the HHDPA and the DHDPA is UO₂(H₃L)₂ (HHDPA and DHDPA are denoted as H₄L). A spectroscopic analysis showed that coordination of uranium(VI) takes place via oxygen atoms.     

Carbon nanotube purification: preparation and characterization of carbon nanotube paste electrodes

Paste electrodes have been constructed using single-wall carbon nanotubes mixed with mineral oil. The electrochemical behavior of such electrodes prepared with different percentages of carbon nanotubes has been compared with that of graphite paste electrodes and evaluated with respect to the electrochemistry of ferricyanide with cyclic voltammetry. Carbon nanotubes were purified by a treatment with concentrated nitric acid, then oxidized in air. In addition, electrochemical pretreatments were carried out to increase the selectivity of carbon nanotube electrodes. Performances of carbon nanotube paste and carbon paste electrodes were evaluated by studying such parameters as current peak, deltaEp, anodic and cathodic current ratio, and charge density toward several different electroactive molecules. Data interpretation based on the carbon nanotubes and carbon surface area is presented. Carbon nanotube paste and carbon paste electrodes were tested as H2O2 and NADH probes, and several analytical parameters were evaluated. The oxidative behavior of dopamine was examined at these electrodes. The two-electron oxidation of dopamine to dopaminequinone showed an excellent reversibility in cyclic voltammetry that was significantly better than that observed at carbon paste electrodes.     

An input-delay neural-network-based approach for piecewise ECG signal compression

We propose an input delay neural network (IDNN) based time series prediction algorithm for compressing electrocardiogram (ECG) signals. Our algorithm has been tested and successfully compared vis-à-vis other popular techniques for its compression efficiency and reconstruction capability.     

Multi-VDD Testing for Analog Circuits

We present industrial results of a quiescent current testing technique suitable for RF testing. The operational method consists of ramping the power supply and of observing the corresponding quiescent current signatures. When the power supply is swept, all transistors are forced into various regions of operation. This has as advantage that the detection of faults is done for multiple supply voltages and corresponding quiescent currents, enhancing in this form the detectability of faults. We found that this method of structural testing yields fault coverage results comparable to functional RF tests making it a potential and attractive technique for production wafer testing due to its low cost, low testing times and low frequency requirements.José Pineda de Gyvez received the Ph.D. degree from the Eindhoven University of Technology. He is currently a principal scientist at Philips Research Laboratories, The Netherlands. Dr. Pineda was Associate Editor in IEEE Transactions on Circuits and Systems Part I and also Associate Editor for Technology in IEEE Transactions on Semiconductor Manufacturing. His research interests are in the general areas of design for manufacturability and analog signal processing.Guido Gronthoud received the electrical engineering degree from the Delft University in 1975. From 1976 to 1980 he worked at the Delft University on the design of Microwave systems. From 1980 he works with Philips. He has been working in the fields of circuit simulation and modelling for IC designs, CAD development for PCB design and electronic circuits and systems reliability. Since 1998 he is working on test innovation of digital and mixed-signal circuits. His interests are Defect Oriented Test, fault modeling and Process Related Test. He has authored and co-authored technical papers.     

A generic architecture model based-methodology for an efficient design of hardware/software application-specific multiprocessor System-on-Chip

In this paper, we describe a methodology and flow for systematic design of application specific multiprocessor system-on-chip (mp-SoC). Our approach is based on a generic architecture platform which is used as a model throughout the design process. This model is modular, flexible and scalable, making it possible to cover a large application field. A complete design flow from system specification to register transfer level (rtl) consists of two principal stages. The first stage is architecture exploration where the system-level performance estimation method is required to find the best system architecture. The goal of this stage is to fix the optimal architectural parameters specific to the application. The second stage is the systematic design flow. The architectural parameters are used in this stage to produce thertl architecture. This paper focuses on the definition of the architecture model and the systematic design flow that was now automated. The feasibility and effectiveness of this approach are illustrated by several telecommunication applications.     

Multi-facial patches aggregation network for facial expression recognition and facial regions contributions to emotion display

Multimedia Tools and Applications - In this paper, an approach for Facial Expressions Recognition (FER) based on a multi-facial patches (MFP) aggregation network is proposed. Deep features are...     

Achieving Thermodynamic Stability of Single-Crystal Co-Free Ni-Rich Cathode Material for High Voltage Lithium-Ion Batteries

Ni-rich layered cathode materials are progressively considered as the standard configuration of high-energy electric vehicles by virtues of their high capacity and eliminated “range anxiety.” However, the poor cyclic stability and severe cobalt supply crisis would restrain their wide commercial applicability. Here, a cost-effective single-crystal Co-free Ni-rich cathode material LiNi_0.8Mn_0.18Fe_0.02O₂ (NMF), which outperforms widely commercial polycrystalline LiNi_0.83Co_0.11Mn_0.06O₂ (MNCM) and single-crystal LiNi_0.83Co_0.11Mn_0.06O₂ (SNCM) is reported. Surprisingly, NMF can compensate for the reversible capacity loss under the designed conditions of high-temperature and elevated-voltage, achieving a competitive energy density compared with conventional MNCM or SNCM. Combining operando characterizations and density functional theory calculation, it is revealed that NMF cathode with improved dynamic structure evolution largely alleviates the mechanical strain issue commonly found in Ni-rich cathode, which can reduce the formation of intragranular cracks and improve the safety performance. Consequently, this new Co-free NMF cathode can achieve a perfect equilibrium between material cost and electrochemical performance, which not only reduces the production cost by >15%, but also demonstrates excellent thermal stability and cycling performance..     

Tuning the Electronic Bandgap of Graphdiyne by H-Substitution to Promote Interfacial Charge Carrier Separation for Enhanced Photocatalytic Hydrogen Production

Graphdiyne (GDY), which features a highly π-conjugated structure, direct bandgap, and high charge carrier mobility, presents the major requirements for photocatalysis. Up to now, all photocatalytic studies are performed without paying too much attention on the GDY bandgap (1.1 eV at the G₀W₀ many-body theory level). Such a narrow bandgap is not suitable for the band alignment between GDY and other semiconductors, making it difficult to achieve efficient photogenerated charge carrier separation. Herein, for the first time, it is demonstrated that tuning the electronic bandgap of GDY via H-substitution (H-GDY) promotes interfacial charge separation and improves photocatalytic H₂ evolution. The H-GDY exhibits an increased bandgap energy ( ≈ 2.5 eV) and exploitable conduction band minimum and valence band maximum edges. As a representative semiconductor, TiO₂ is hybridized with both H-GDY and GDY to fabricate a heterojunction. Compared to the GDY/TiO₂, the H-GDY/TiO₂ heterojunction leads to a remarkable enhancement of the photocatalytic H₂ generation by 1.35 times under UV–visible illumination (6200 µ mol h⁻¹ g⁻¹) and four times under visible light (670 µ mol h⁻¹ g⁻¹). Such enhancement is attributed to the suitable band alignment between H-GDY and TiO₂, which efficiently promotes the photogenerated electron and hole separation, as supported by density functional theory calculations.     

Enabling High-Performance NASICON-Based Solid-State Lithium Metal Batteries Towards Practical Conditions

Solid-state lithium metal batteries (SSLMBs) are promising next-generation high-energy rechargeable batteries. However, the practical energy densities of the reported SSLMBs have been significantly overstated due to the use of thick solid-state electrolytes, thick lithium (Li) anodes, and thin cathodes. Here, a high-performance NASICON-based SSLMB using a thin (60 µm) Li_1.5Al_0.5Ge_1.5(PO₄)₃ (LAGP) electrolyte, ultrathin (36 µm) Li metal, and high-loading (8 mg cm⁻²) LiFePO₄ (LFP) cathode is reported. The thin and dense LAGP electrolyte prepared by hot-pressing exhibits a high Li ionic conductivity of 1 × 10⁻³ S cm⁻¹ at 80 °C. The assembled SSLMB can thus deliver an increased areal capacity of ≈1 mAh cm⁻² at C/5 with a high capacity retention of ≈96% after 50 cycles under 80 °C. Furthermore, it is revealed by synchrotron X-ray absorption spectroscopy and in situ high-energy X-ray diffraction that the side reactions between LAGP electrolyte and LFP cathode are significantly suppressed, while rational surface protection is required for Ni-rich layered cathodes. This study provides valuable insights and guidelines for the development of high-energy SSLMBs towards practical conditions.