Synthesis and characterization of dehydroabietic acid derivatives suitable for surfactant synthesis

The syntheses of derivatives of dehydroabietic acid suitable for further manipulation into surfactants are presented. The compounds are produced at very high yields and purity. They contain several different functional groups, e.g., carboxylic acid, amine, ester, alcohol, and an aromatic group. The functional groups are useful as the linking unit to the hydrophilic part in synthesizing surfactants.     

Molecular thermodynamics of solutions in the normal and critical regions — II. Activity coefficients for the ArN2, C2H6C2H4 and C3H6CO2 systems

Activity coefficients for the ArN₂, C₂H₆C₂H₄, and C₃H₆CO₂ systems are calculated from published vapour-liquid equilibrium compositions at various pressures and temperatures. The activity coefficients are correlated using a two parameter model based on the principles of molecular thermodynamics. The method is used both in the normal liquid and critical regions. The parameters of the model are shown to be reasonably independent of the temperature for the three systems.     

Characterisation of three different impellers using the LDV-technique

A characterisation of three commonly used impellers was made in this study by measuring local mean velocities and the fluctuations of these velocities with the LDV technique. The data was used to estimate volumetric flow, velocity fluctuations and turbulent intensity in the impeller region of the tank. The impellers investigated were a high flow impeller, a pitched blade turbine and a Rushton turbine. The cylindrical vessel used was made of Perspex, had a dished bottom (DIN 28013), was equipped with four baffles and had an inner diameter of 0.45 m. It was found that the bulk velocities could be scaled with the tip-speed of the impeller (ND). The flow rate at constant impeller speed increased in the order high flow impeller — Rushton turbine — pitched blade turbine. The corresponding order for the turbulence fluctuation is: high flow impeller — pitched blade turbine — Rushton turbine. The velocity profile of the flow out from the high flow impeller was furthermore, not as smooth as could be expected.     

Surface properties of surfactants derived from natural products. Part 1: Syntheses and structure/property relationships—Solubility and emulsification

Several novel and some previously known, mostly sugar-based, surfactants have been synthesized and some of their surface properties have been characterized and compared with those of commercial nonylphenol ethoxylates. The surfactant solubility in water, ethanol, and dodecane was studied. The properties of these compounds as emulsification agents in systems composed of the surfactant with water/isopropyl myristate, water/rapeseed oil, and water/dodecane are presented. The aqueous solubility of the surfactants follows the general trend expected from their hydrophilic-lipophilic balance according to Griffin (HLBG), but it is also clear that the nature of the headgroup and the structure of the nonpolar part affect the solubility in a manner not aptured in the standard HLBG concept. An ester or amine group as the connecting unit between the hydrophile and the hydrophobe produces a more water-soluble surfactant than the corresponding amide derivative. Some effective emulsifiers were found. For instance, the surfactants with a dehydroabietic nonpolar group appear to be promosing emulsifiers. Most sugar-based surfactants were able to form macroemulsions of up to around 2 wt/vol% of oil. The stability of many of these amulsions was very high, extending for months.     

Expectations and Experiences With MyLabourParty: From Right to Know to Right to Participate?

Social media are often argued to change political communication, decreasing the distance between politicians and citizens, and increasing citizens' influence on policymaking. This paper presents findings from a study of how the Norwegian Labour Party uses social media, focusing on the community platform MyLabourParty. Interviews with politicians and a survey with citizens as respondents were conducted to examine the experiences of online political discussions. Findings show that citizens and politicians expect MyLabourParty to strengthen citizen participation. Yet, citizens still experience communication asymmetry and politicians may find it challenging to participate to the extent citizens expect. Means for bridging the gap between expectations and experiences are called for, in particular redefinition of the offering, changes of user‐practices, and system improvements.     

DMTO – a method for Discrete Material and Thickness Optimization of laminated composite structures

This paper presents a gradient based topology optimization method for Discrete Material and Thickness Optimization of laminated composite structures, labelled the DMTO method. The capabilities of the proposed method are demonstrated on mass minimization, subject to constraints on the structural criteria; buckling load factors, eigenfrequencies, and limited displacements. Furthermore, common design guidelines or rules, referred to as manufacturing constraints, are included explicitly in the optimization problem as series of linear inequalities. The material selection and thickness variation are optimized simultaneously through interpolation functions with penalization. Numerical results for several parameterizations of a finite element model of a generic main spar from a wind turbine blade are presented. The different parameterizations represent different levels of complexity with respect to manufacturability. The results will thus give insight into the relation between potential weight saving and design complexity. The results show that the DMTO method is capable of solving the problems robustly with only few intermediate valued design variables.     

A simple chromatographic method for purification of egg lecithin

Egg lecithin was purified from the CdCl₂-lecithin complex by column chromatography on Alumina. The yield from 5 eggs was 2.8 g. The purified lecithin had correct chemical values for pure lecithin and a fatty acid composition similar to lecithin prepared by other methods. The method probably can be adapted for purification of other lipids containing the phosphocholine moiety and for purification of synthetic lecithin.     

Constrained regression in chemical engineering practice

Absolute equality constraints in multiple regression are shown to introduce only minor modifications in the normal equations by a subset of the regression parameters. It is essential that these are ordered such that the subset is observable through the constraints. The constraints are shown to give greater residuals about the regression, but the precision in the parameter estimation is improved.In general power function curve fitting, a quadratically convergent iterative computation of the optimal exponents uses the normal equations as equality constraints. The correlations between the coefficients and the exponents in a sum of power functions become very high, when the number of terms increases such that their individual observability is being greatly reduced. The effect is shown to be a very poor precision in the parameter estimation and a heavy oscillation in the coefficients.The algorithms suggested are illustrated by curve fitting of some binary equilibrium data, where the relative volatility model gives a superior fit to the data.     

Hydrocarbon synthesis over sulfide catalysts. Break-down of the Anderson-Schulz-Flory distribution

The kinetics of hydrocarbon synthesis over sulfide-based catalysts was studied. It appears that the formation of methane follows another reaction path than that of higher hydrocarbons. This might explain the very high selectivities for ethane and propane as compared with conventional Fischer-Tropsch catalysts. Reference is made to testing of the catalysts at industrial conditions.