Thermohydraulic performance of a new internal twisted ribs automobile exhaust heat exchanger for waste heat recovery applications

The performance of the thermoelectric-based waste heat recovery (WHR) system in an automobile greatly depends on the amount of heat extracted by the exhaust heat exchanger (EHE). In the present study, the thermohydraulic performance of the EHE having twisted ribs and the pressure drop across the entire heat exchanger have been experimentally investigated. The experiments were repeated for the various geometric parameters such as twist ratio (4-8), angle of attack (30°-90°), and pitch ratio (6-10) on the Reynolds number within the range of 2300 to 25,000. The heat transport and fluid flow characteristics were compared with an internally smooth EHE using the thermohydraulic performance parameter. The maximum heat transfer rate was improved at 164.22%. However, the specification of the twisted rib for superior performance has been obtained at twist ratio of 4 and pitch ratio of 8 with 60° angle of attack. The highest thermohydraulic performance parameter value revealed as 1.93 at the same configuration. With the change in twist ratio, the pitch ratio, angle of attack, and the heat transfer rate increased by 39.52%, 60.85%, and 40.70%, respectively. Thus, the efficient heat transfer with the twisted rib would improve the extent of WHR in automobiles.     

Composite materials manufactured from wood particles modified through a reactive extrusion process

Wood‐based composites such as particleboard and medium‐density fiberboard are currently made with formaldehyde‐containing adhesives. Since the government is continuously developing and implementing very stringent regulations to eliminate formaldehyde emissions into the environment, alternative approaches must be developed to replace these adhesives. This study examined the concept of using a reactive extrusion process as a means of developing a new, formaldehyde‐free binding system for wood composite products. The surfaces of wood particles were modified by grafting maleated polyolefins through a continuous reactive extrusion process. Chemical changes resulting from this treatment were followed by studying the Fourier transform infrared (FTIR), ¹³C nuclear magnetic resonance (NMR), and X‐ray photoelectron spectroscopy (XPS) spectra. The modified wood particles were compression‐molded into panels, which were tested for mechanical properties. FTIR, ¹³C NMR, and XPS data revealed that the chemical reactions have taken place between the hydroxyl groups of wood particles and maleated polyolefins. The mechanical property test results indicated that the composite panels compared favorably with current standard requirements for conventional particleboard. POLYM. COMPOS., 26:534–541, 2005. © 2005 Society of Plastics Engineers     

A new framework for managing IT-enabled business change

Abstract. Although information systems and technology (IS/IT) investments have always caused varying degrees of business change, the main purpose of many of today's IS/IT implementations is to change the business and/or organization in some significant way. However, most organizations' approaches to managing IS/IT developments have changed little in the last 15–20 years and are heavily dependent on methodologies of IS/IT development and associated project management principles. The philosophy being adopted by many organizations today is that there are few IS/IT projects (some infrastructure investments only) that do not cause business changes and therefore they are really 'business projects involving IS/IT'. This exploratory research set out to devise a new framework for 'IT and change' management, which is more appropriate to today's realities than traditional approaches. The initial framework was derived from 'first principles', then adapted and further developed by applying and testing it in a range of real projects in organizations. This paper summarizes the results of that work.     

Diagnosis of pulmonary infections in immunocompromised patients by fiber-optic bronchoscopy with bronchoalveolar lavage and serology

Fiber-optic bronchoscopy (FOB) and bronchoalveolar lavage (BAL) were performed on 67 occasions in 57 immunocompromised patients with symptoms consistent with pulmonary infection. Diagnosis was achieved more often in renal transplant patients than in patients with hematological malignancies (85% versus 28%). Culture (bacteria, virus, fungi), staining and microscopy (bacteria, fungi, Pneumocystis carinii (PC)) and antigen detection by indirect immunofluorescence (cytomegalovirus (CMV), respiratory viruses, PC, Legionella) were used for diagnosis. On 20 occasions transbronchial biopsies with histopathologic examination were performed. In addition, serology comprising the herpes group (HHV-6) and respiratory viruses was done. A microbial diagnosis was obtained on 45% of occasions. The most common pathogens found were CMV (31%) and PC (25%). On 22 (33%) occasions a rapid diagnosis of 1 or more microbial agents was obtained within 24 h by conventional staining or indirect immunofluorescence. The clinical relevance of findings of CMV, HHV-6, and Epstein-Barr virus in BAL by polymerase chain detection on 18, 6 and 3 occasions is discussed. On 4 occasions pathogenic bacteria were found. It was not possible to relate findings of coagulase-negative staphylococci, alpha-streptococci and Candida albicans to the pulmonary infection.     

SYNTHESIS OF ACTIVATED CARBON FROM JATROPHA SEED COAT AND APPLICATION TO ADSORPTION OF IODINE AND METHYLENE BLUE

This article provides evidence that jatropha seed coat residues can be used as a carbon source for preparing activated carbons that have good adsorption properties for iodine and methylene blue. Activated carbons were prepared using three different methods of activation, physical, chemical, and physico-chemical, for a range of activation temperatures (600°, 700°, 800°, and 900°C) and activation hold times (1, 2, and 3 h). The highest BET surface area (1479 m² g^?1) and the highest iodine adsorption (1511 mg g^?1) were obtained with physico-chemical activation at a temperature of 900°C and a hold time of 2 h. This activated carbon gave higher BET surface area and iodine adsorption than commercial activated carbon (1169.1 m² g^?1 and 1076 mg g^?1). The activated carbons prepared by physico-chemical activation at 900°C and 2 h were then tested for adsorption of methylene blue at a range of concentrations of methylene blue (100, 200, 300, 400, and 500 mg L^?1). It was found that a Langmuir isotherm gave a better fit (R ² = 0.999) to the observed adsorptions than a Freundlich isotherm (R ² = 0.884). For the adsorption kinetics, a pseudo-second-order model gave a better fit (R ² > 0.998, Δq _e  = 3.7%) than a pseudo-first-order model (R ² ≈ 0.95, Δq _e  = 85.6%). These results suggest that chemisorption is the rate-controlling step for the adsorption of methylene blue. The experimental results show that jatropha seed coat is a lignocellulosic waste precursor for preparation of activated carbon that is an alternative source for preparation of commercial-grade activated carbons.     

Facile synthesis route of graphene-like structures from multiwall carbon nanotubes

Graphene-like nanostructures were synthesized from multiwall carbon nanotubes through chemical exfoliation route in mild conditions. For this purpose multiwall carbon nanotubes were synthesized by Chemical Vapor Deposition method using Al-Fe-Co catalyst and treated with KMnO₄. The obtained nanostructures were characterized by Raman spectroscopy, XRD, FTIR, EDX, SEM and TEM methods. FTIR results show that, treating the carbon nanotubes with KMnO₄ decorates their surface with oxygen containing functional groups. XRD and Raman spectroscopy results reveal that the outermost layers of the nanotubes were exfoliated during the treatment. The formation of graphene-like nanostructures was confirmed by SEM and TEM methods. The novelty of this work is the first time use of this type of mild and cheap condition for obtaining graphene-like nanostructures from MWCNTs without any other intermediate treatment.     

A third-order sliding mode controller for nonlinear multivariable systems

This paper proposes a third-order sliding mode controller for nonlinear multivariable systems with uncertain parameters and subject to external disturbances. The controller achieves fast convergence rate, high tracking accuracy, and a reduced level of chattering. The stability of the controller and its global ultimately uniform convergence is proved by the Lyapunov stability theory. Simulation results on a single inverted pendulum system are given to illustrate the effectiveness of the proposed control scheme by comparing it with methods such as a second-order supertwisting controller, a third-order supertwisting controller, and an integral terminal third-order sliding mode controller.     

Folate-encoded and Fe3O4-loaded polymeric micelles for dual targeting of cancer cells

Diblock copolymers of poly(ethylene glycol) (PEG) and poly(?-caprolactone) (PCL) bearing a tumor-targeting ligand, folate, were self-assembled into micelles. Superparamagnetic iron oxide (SPIO) nanoparticles and an anticancer drug doxorubicin (DOX) were coencapsulated within the micelles less than 100 nm in diameters. These SPIO-DOX-loaded micelles were superparamagnetic at room temperature, but turned ferrimagnetic at 10 K, consistent with magnetic properties of primary SPIO nanoparticles. Cell culture experiments demonstrated the potential of these polymeric micelles as an effective dual targeting nanoplatform for the delivery of anticancer drugs. Folate attachment to micelles resulted in the recognition of the micelles by tumor cells over-expressing folate receptors, leading to facilitation in cellular uptake of micelles, and the transport efficiency of the SPIO-loaded and folate-functionalized micelles into the tumor cells can be further enhanced by applying an external magnetic field to the cells.     

Neighborhood frequency does affect performance in the Reicher task: Encoding or decision?

Three experiments using the Reicher task show that performance on low-frequency words is disrupted if the incorrect alternative forms a higher frequency word. This neighborhood frequency effect occurs for both energy and pattern masks and for different sets of items. When the upcoming word is primed and its accessibility is enhanced, the neighborhood frequency effect is eliminated. Experiments 4a and 4b tested the neighborhood frequency effect using a same–different task and a signal-detection analysis. Neighborhood frequency affected the decision criterion but not the sensitivity of the perceptual system. Experiment 5 showed that many words with a frequency in the range from 1 to 5 per million are not recognized out of context. These results are consistent with the hypothesis that frequency effects in the Reicher task are caused by a bias in the decision system and can be simulated with the stochastic activation–verification model. (PsycINFO Database Record (c) 2010 APA, all rights reserved)