Polyol-Derived Alkoxide/Hydroxide Base Catalysts II: Transesterification Reactions

Biodiesel, fatty acid methyl ester (FAME), was produced by transesterification of canola oil with methanol in the presence of a series of alkoxide/hydroxide base catalysts produced from glycerol, 1,2-propanediol, 1,3-propanediol, xylitol, or sorbitol produced by dehydration reaction of sodium hydroxide in the presence of polyols. Transesterification reactions proceeded efficiently in the presence of sodium alkoxide catalysts prepared at three different mole ratios of sodium hydroxide to glycerol (1:1, 2:1, and 3:1). The production of methyl ester during the course of the reaction was determined repeatedly and the reaction progress was compared with that achieved in a reaction catalyzed by freshly prepared anhydrous sodium methoxide as a standard catalyst. Sodium alkoxide/hydroxide catalysts activity during the first 2 min of the reaction was in the order of: sorbitol < xylitol < sodium methoxide < 1,2-propanediol < 1,3-propanediol < glycerol regardless of the mole ratio of sodium hydroxide to glycerol. All catalysts showed a higher methyl ester accumulation at higher ratios of sodium hydroxide to polyol and had the following order 1:1 < 2:1 < 3:1 (sodium hydroxide:glycerol). Several of these catalysts were as powerful as sodium methoxide in catalyzing the transesterification reaction at the same mole concentration. All alkoxide/hydroxide catalysts resulted in a high FAME accumulation (>95 wt%) in a single transesterification batch reaction.     

Effect of micronisation and electromagnetic radiation on physical and mechanical properties of Canadian barley

The effect of micronisation (high‐intensity infrared heating) and microwave radiation of normal barley (NB), high‐amylose barley (HAB) and waxy barley (WB) on the physical and mechanical properties was studied. Samples were tempered to 42–45% moisture content and then subjected to infrared or microwave radiation to reduce the moisture content to approximately 10%. The grain surface temperature during radiation was maintained at 100 °C. The changes in physical and mechanical properties were compared with unprocessed samples. Thermal radiation increased slightly the volume of the kernels because of the diffusion of water vapour from inside to the outer surface. These changes resulted in a decrease in particle and bulk densities. Thermal radiation affected the Hunter colour values, as well. The mechanical properties including bio‐yield point, modulus of elasticity and breakage susceptibility were affected by micronisation and microwave heating.     

Design considerations for 60 GHz CMOS radios

With the availability of 7 GHz of unlicensed spectrum around 60 GHz, there is a growing interest in using this resource for new consumer applications requiring very high-data-rate wireless transmission. Historically, the cost of the 60 GHz electronics, implemented in the compound semiconductor technology, has been prohibitively expensive. A fully integrated CMOS solution has the potential to drastically reduce costs enough to hit consumer price points. System, circuit, and device-level barriers to a low-cost 60 GHz CMOS implementation are described, potential solutions are explored, and remaining challenges are discussed.     

DPCM picture transmission over noisy channels with the aid of aMarkov model

The problem of DPCM picture transmission over noisy channels is considered. It is well known that DPCM systems are very sensitive to channel errors. The goal in this work is to build robustness against channel errors. Three methods are proposed in this paper and are obtained by modeling the encoded signal as a Markov sequence. First, an optimum method for decoding correlated sequences is derived, and it is shown to require Viterbi decoding. Then, a modified MAP method (MMAP) for Markov sequences is described. A maximal signal-to-noise (MSNR) receiver for DPCM systems is also developed that minimizes the distortion power due to channel errors. The appropriate cost matrix for this receiver is computed. These methods are applied to DPCM picture transmission over noisy channels and are compared with a another method. The SNR graphs, as well as subjective examination of the received pictures, demonstrate that the proposed procedures are quite effective and superior to that method. Among the proposed methods, the MSNR receiver was found to be more effective than the others for a given order of the Markov model. It is observed that the proposed methods are most beneficial for low detail pictures.     

On the hysteretic behavior of trapezoidally corrugated steel shear walls

At present, corrugated plates have numerous applications such as web of plate girders and aerospace applications. Higher out‐of‐plane stiffness and initial elastic strength of the corrugated plates compared with flat plates are reasons for consideration. This study investigates the behavior of trapezoidally corrugated steel plate shear walls (TCSPSWs) under monotonic and cyclic loadings. Finite element analyses that include both material and geometric nonlinearities are employed for the examination. The results from finite element analysis are verified through tested specimen findings. Moreover, the behavior of the steel shear walls with the flat infill panels and the corrugated plate infill panels is compared. The results show that explicit dynamic analysis is the most suitable analysis for the TCSPSWs under quasi‐static loading. Furthermore, although strength of the TCSPSWs obtained from the finite element analysis and the test are fully coincident in elastic region, nonetheless, they are fairly coincident in elastic–plastic and plastic region. Copyright © 2012 John Wiley & Sons, Ltd.     

Double-walled microspheres loaded with meglumine antimoniate: preparation,characterization and in vitro release study

Objective: The objective of this study was to fabricate double-walled poly(lactide-co-glycolide) (PLGA) microspheres to increase encapsulation efficiency and avoid rapid release of hydrophilic drugs such as meglumine antimoniate.

Methods: In this study, double-walled and one-layered microspheres of PLGA were prepared using the emulsion solvent evaporation technique to better control the release of a hydrophilic drug, meglumine antimoniate (Glucantime®), which is the first choice treatment of cutaneous leishmaniasis. The effect of hydrophobic coating on microspheres' size, morphology, encapsulation efficiency and drug release characteristics was evaluated. Furthermore, the presence of antimony in meglumine antimoniate made it possible to observe the drug distribution within the microspheres' cross section by means of energy dispersive X-ray spectroscopy.

Results: Drug distribution images confirmed accumulation of the drug within the inner core of double-walled microspheres. In addition, these microspheres encapsulated the drug more efficiently up to 87% and demonstrated reduced initial burst and prolonged release compared to one-layered microspheres. These superiorities make double-walled microspheres an optimum candidate for sustained delivery of hydrophilic drugs.

Conclusion: Double-walled microspheres provide some advantages over traditional microspheres overcoming most of their limitations. Double-walled microspheres were found to be more efficient than their corresponding one-layered microspheres in terms of encapsulation efficiencies and release characteristics.     

Numerical investigation of the mechanism behind the deflagration to detonation transition in homogeneous and inhomogeneous mixtures of H2-air in an obstructed channel

The accidental release of hydrogen into enclosures can result in a flammable mixture with concentration gradients and possible deflagration-to-detonation transition (DDT). This numerical study aims to investigate the effect of obstacle spacing and mixture concentration on the DDT in a homogeneous and inhomogeneous hydrogen-air mixture. The paper focuses on the mechanisms behind the DDT in two mixtures with an average hydrogen concentration of 15% and 30%. Unlike the near-stoichiometric mixture, in the lean mixture, DDT only occurs in the inhomogeneous mixture. Depending on obstacle spacing, three different regimes of DDT were observed in the near-stoichiometric inhomogeneous mixture: i) Detonation was ignited when a strong Mach stem formed and propagated between the obstacles; ii) two explosion centers appeared when incident shock and Mach stem reflected from upper and lower obstacles, respectively; iii) Mach stem did not form but DDT occurred behind the flame front at the top of the obstacle.     

Demonstration of Shafranov Shift by the Simplest Grad–Shafranov Equation Solution in IR-T1 Tokamak

There are analytically different solutions for the inhomogeneous Grad–Shafranov equation (GSE). We presented one of methods of analytical solution to the GSE corresponds to source function linear in ψ. This solution is over constrained both in shape and in plasma current. We demonstrated that Shafranov shift for this solution is independent of plasma current.     

Recent Results of Edge Plasma Parameters Measurements in IR-T1 Tokamak by Probe

Langmuir probes (LP) are the most common diagnostics for the local measurement of very important plasma parameters such as plasma density, electron temperature, plasma potential and the electron energy distribution function (EEDF). In this paper the applicability of the first derivative Langmuir probe method in processing the electron part of the current-voltage (I–V) characteristics in IR-T1 Tokamak is reported. The EEDF at different radial positions in the edge region and Scrape off Layer (SOL) are derived and the values of the plasma potential, electron temperature and electron density are estimated. Results comparison between the first derivative method and Stangeby method shows a satisfactory agreement.     

Thin-Layer Drying of Flax Fiber: I. Analysis of Modeling Using Fick's Second Law of Diffusion

Thin-layer drying of moist flax fiber was performed at four temperatures of 30, 50, 70, and 100°C with a constant absolute humidity of 0.0065 kg water per kg dry air. The coefficients of diffusion of the fiber at different drying conditions were estimated by modeling the drying process using the one- to five-term solutions of the second Fick's law of diffusion. The models underestimated the drying process during the initial stages of drying and overestimated this process during the final stages. The estimated coefficient of diffusions ranged from 5.11 × 10^-9 to 1.92 × 10^-8 m²/s and linearly increased with the drying air temperature.