Osmium in environmental samples from Northeast Sweden. Part I. Evaluation of background status

Osmium (Os) concentrations and (187)Os/(188)Os isotope abundance ratios are presented for sedimentary materials, soils, humus, plants, mushrooms, mosses and lichens collected in the vicinity of the town of Lule?, Northeast Sweden, the data for biological specimens being the first reported. Contributions from sampling and varying exposure time to the observed environmental variability were evaluated. Sedimentary materials (from both fresh and brackish water) are most elevated in radiogenic (187)Os, followed by inorganic soil horizons, mushrooms and humus. The Os isotopic compositions of plants, mosses and lichens are much less radiogenic, with mean (187)Os/(188)Os lying within a relatively narrow 0.3-0.6 range. Significant temporal variations in Os concentrations and isotopic compositions of plant samples are attributed to integrative uptake of airborne Os with non-radiogenic composition. Measured Os concentrations in biological matrices increase in the order: small shrub leaves (blueberry and lingonberry)< or =spruce needles< or =mushrooms< or =tree leaves< or =pine needles相似文献   

Gut health benefits of kiwifruit pectins: Comparison with commercial functional polysaccharides

The role of kiwifruit pectin as a functional food ingredient capable of beneficial gut health effects in vitro was investigated. Six different pectins were obtained from the kiwifruit cultivar Actinidia deliciosa ‘Hayward’ (ZESPRI? GREEN) by selective re-solubilisation of the fruit fibre with different chemical treatments. The potential gut health benefit of kiwifruit pectin was tested with respect to its influence on bacterial adhesion to intestinal epithelial cells (Caco-2) in vitro. The most effective kiwifruit pectin (monoK pectin), obtained by re-solubilisation with monopotassium phosphate, was compared with three commercial functional polysaccharides - citrus pectin, guar gum and inulin. The monoK pectin was superior to inulin, a standard prebiotic in enhancing the adhesion of Lactobacillus rhamnosus and decreasing the adhesion of Salmonella typhimurium to Caco-2 cells. The adhesion of Bifidobacterium bifidum was significantly enhanced only by inulin and citrus pectin, while guar gum had no effect on adhesion of any of these bacteria.     

The impact of zeta potential on the physical properties of ferric--NOM flocs

The physical properties of natural organic matter (NOM) flocs, such as size, growth rate, and strength, were investigated using a laser diffraction particle sizing device. Conditions were set such that varying carbon coagulant ratio and zeta potential could both be investigated. Results demonstrated a link between zeta potential and coagulation and flocculation performance, with the production of strong flocs and low residual concentrations when the zeta potential was minimized. The overall strength of the connection points within the floc were determined by a combination of steric interactions, polymer bridging, van der Waals forces, and electrostatic forces. Hence, both dose ratio and zeta potential are important in understanding floc properties. Floc growth was dominated by dose ratio, whereas the response to elevated shear was strongly related to zeta potential. The steady-state floc size was a combination of both factors. This allowed the continued development of a qualitative model in order to engineer optimal floc properties when coagulating NOM.     

The relationship between closure pressures from fluid injection tests and the minimum principal stress in strong rocks

Closure pressures measured during injection tests such as mini-fracs are normally considered an accurate measure of the minimum in situ principal stress magnitude. This paper presents stress, strength and image log data from the Australian Cooper Basin, which suggests that in reservoirs with high in situ stress, high tensile strength and weak geological fabrics, interpreted closure pressures may be significantly greater than the minimum principal stress.Closure pressures interpreted from mini-frac injection tests in the Cooper Basin, suggest the minimum principal stress varies from 12.4–27.2 MPa/km (0.55–1.2 psi/ft). To better understand the reasons for this variation in closure pressure, image logs and mini-frac data from 13 treatment zones, and core from seven of these treatment zones, were analysed. The analysis revealed that treatment zones with high measured closure pressures (18.1 MPa/km; 0.8 psi/ft), high treating pressures (>31.6 MPa/km; 1.4 psi/ft) and high measured hydraulic fracture complexity existed in reservoirs with high tensile rock strength (>7 MPa; 1015 psi) and geological fabrics (planes of weakness) including natural fractures. Conversely, treatment zones with lower measured closure stress (19 MPa/km; 0.84 psi/ft) and low hydraulic fracture complexity occurred in reservoirs with lower tensile strength and/or no geological fabrics.We suggest that closure pressures in rocks with high tensile strength and weak geological fabrics may not be representative of the minimum principal stress magnitude in the Cooper Basin where they are associated with hydraulic fracture complexity. Rather, they reflect the normal stress incident on pre-existing weaknesses that are exploited by hydraulic fluid during the mini-frac injection.     

Antibiotic resistance gene abundances associated with waste discharges to the Almendares River near Havana, Cuba

Considerable debate exists over the primary cause of increased antibiotic resistance (AR) worldwide. Evidence suggests increasing AR results from overuse of antibiotics in medicine and therapeutic and nontherapeutic applications in agriculture. However, pollution also can influence environmental AR, particularly associated with heavy metal, pharmaceutical, and other waste releases, although the relative scale of the "pollution" contribution is poorly defined, which restricts targeted mitigation efforts. The question is "where to study and quantify AR from pollution versus other causes to best understand the pollution effect". One useful site is Cuba because industrial pollution broadly exists; antibiotics are used sparingly in medicine and agriculture; and multiresistant bacterial infections are increasing in clinical settings without explanation. Within this context, we quantified 13 antibiotic resistance genes (ARG; indicators of AR potential), 6 heavy metals, 3 antibiotics, and 17 other organic pollutants at 8 locations along the Almendares River in western Havana at sites bracketing known waste discharge points, including a large solid waste landfill and various pharmaceutical factories. Significant correlations (p < 0.05) were found between sediment ARG levels, especially for tetracyclines and β-lactams (e.g., tet(M), tet(O), tet(Q), tet(W), bla(OXA)), and sediment Cu and water column ampicillin levels in the river. Further, sediment ARG levels increased by up to 3 orders of magnitude downstream of the pharmaceutical factories and were highest where human population densities also were high. Although explicit links are not shown, results suggest that pollution has increased background AR levels in a setting where other causes of AR are less prevalent.     

Composition of milk from minor dairy animals and buffalo breeds: a biodiversity perspective

A comprehensive review is presented of the nutrient composition for buffalo, mare, and dromedary camel milks at the level of breed, and species‐level data for yak, mithun, musk ox, donkey, Bactrian camel, llama, alpaca, reindeer and moose milks. Average values of nutrients were calculated and compared. Interspecies values (g 100 g^?1) were 0.7–16.1 for total fat, 1.6–10.5 for protein, 2.6–6.6 for lactose, and 67.9–90.8 for water. Reindeer and moose milks had the highest fat and protein concentrations and the lowest lactose contents. Mare and donkey milks had the lowest protein and fat contents, in addition to showing the most appropriate fatty acid profile for human nutrition. Dromedary camel milk was most similar to cow milk in proximate composition. Moose milk was the richest in minerals, having values as high as 358 mg 100 g^?1 for calcium, 158 mg 100 g^?1 for sodium and 150 mg 100 g^?1 for phosphorus. Interbreed differences of 4 g 100 g^?1 were observed in total fat in buffalo, yak, mare and dromedary camel milks. Large interbreed differences were also present in the mineral contents in mare, buffalo and dromedary camel milks. By bringing together these compositional data, we hope to usefully widen the biodiversity knowledge base, which may contribute to the conservation and sustainable use of milk from underutilized dairy breeds and species, and to improved food and nutrition security, particularly in developing countries. Copyright © 2011 Society of Chemical Industry     

A user-guided personalization methodology to facilitate new smart home occupancy

Smart homes are becoming increasingly popular in providing people with the services they desire. Activity recognition is a fundamental task to provide personalised home facilities. Many promising approaches are being used for activity recognition; one of them is data-driven. It has some fascinating features and advantages. However, there are drawbacks such as the lack of ability to providing home automation from the day one due to the limited data available. In this paper, we propose an approach, called READY (useR-guided nEw smart home ADaptation sYstem) for developing a personalised automation system that provides the user with smart home services the moment they move into their new house. The system development process was strongly user-centred, involving users in every step of the system’s design. Later, the user-guided transfer learning approach was introduced that uses an old smart home data set to enhance the existing smart home service with user contributions. Finally, the proposed approach and designed system were tested and validated in the smart lab that showed promising results.

     

Influence of copper and aluminum substitution on high-temperature oxidation of the FeCoCrNiMn “Cantor” alloy

In this study, the oxidation behavior of FeCoCrNiMn (HEA + Mn) is compared to three modified HEAs manufactured by substituting Mn with Al, Cu, or Al + Cu. Oxidation tests were conducted between 600°C and 800°C for up to 500 h in synthetic air. Substitution of Mn leads to a significant improvement in the oxidation resistance for the three modified HEAs. For FeCoCrNiCu (HEA + Cu), a local attack of a Cu-rich phase was observed, leading to the formation of CuO blisters on the surface. The FeCoCrNiAl (HEA + Al) alloy was characterized by the formation of a thin Al₂O₃ surface layer for all temperatures. However, for the HEA + Al alloy the formation of AlN was observed after 300 h at 800°C, leading to a partial breakdown of the protective scale. FeCoCrNiCuAl (HEA + Cu + Al) by far showed the best oxidation resistance, characterized by the formation of a highly protective Al₂O₃ scale that effectively inhibited nitrogen penetration into the metal subsurface and local attack of the Cu-rich phase.     

Colour stability during production of printed ocular prostheses

Ocular prostheses have been used for centuries to restore patient confidence, psychosocial relationships and to improve quality of life. Methodology for producing accurate prostheses has improved with technological discoveries. Recently, hand painting ocular prostheses has been the go-to method for creating life like prostheses. However, digital printing a print to envelope around an acrylic prosthesis has been shown to decrease treatment and rehabilitation times, whilst still producing high-definition ocular prostheses. Despite these improvements, little is known about the colour stability of digitally printed ocular prostheses. To better understand the colour stability of digital prostheses 30 samples simulating ocular prostheses were created, containing 10 with blue iris, 10 combination/green iris and 10 with sepia (brown) irises. Colour measurements were taken using a data spectrophotometer, from two defined points, the iris and sclera for both pre-polymerisation and post-polymerisation to assess colour variance. Colour coordinate data was gathered and was analysed using a one-way analysis of variance test and a paired t-test, both with alpha = 0.05. Significant colour variations were found for each iris colour and for the sclera. The sclera showed the largest colour variation with a ΔE of 4.75, followed by the brown irises, the green irises and then blue irises with ΔE values of 3.29, 2.47 and 1.82, respectively. This is a significant decrease compared to current hand painting methods which have an average colour variance of ΔE = 20. This shows a large increase in colour stability which can drastically improve patient satisfaction and quality of life.