In situ dialysis for the determination of the state of trace elements in natural waters

A new method is described which enables determination of the concentration of truly dissolved forms of trace elements in natural waters without substantial influence of adsorption on the walls of apparatus and vessels. The method also simplifies further analysis of the ionic and molecular forms of trace elements. It consists in immersing a dialysis bag, filled with pure water, directly into the natural water in situ and allowing the dialysis and adsorption equilibriu to be established. Conditions for the use of this method are discussed and results of the determination of the dissolved fraction of 20 elements in river water, as compared with the results by filtration and ultrafiltration are presented. Neutron activation analysis was used for the elemental determinations.     

Seismic methods for study of soil building properties

Bulletin of Engineering Geology and the Environment - Information about distribution of elastic wave propagation velocities Vp, Vs in the subsurface zone of a soil mass can be obtained rapidly and...     

The bacterial population of piggery-waste anaerobic digesters

A survey was made of the anaerobic and facultatively anaerobic bacteria present in piggery waste, digesting piggery waste and domestic anaerobic sludge sludge used to start a piggery waste digester. An influence of the input waste was shown in that streptococci, the predominant facultatively anaerobic bacteria in the piggery waste, were the predominant bacteria in the digesting waste, and they replaced Enterobacter, predominant in the domestic sludge, when a piggery waste digestion had been established from this latter material. Cellulolytic or methanogenic bacteria could not be detected in the piggery waste but populations of these, and other hydrolytic bacteria, became established at different times during the buildup of digestion by gradual addition of piggery waste to water. The bacteria concerned in degradation of the waste constituents were all anaerobes.Production of methane from H₂/CO₂, formate and butyrate could be detected in mixed cultures from dilutions of digester contents, but the only methanogenic bacterium that could be isolated in pure culture was Methanobacterium formicicum, which uses H₂/CO₂ or formate only.     

The Italian national survey of indoor radon exposure

An investigation is being developed by the Camitato Nazionale per la Ricerca e per lo Sviluppo dell'Energia Nucleare e delle Energie Alternative, ENEA, to assess the indoor exposure of the Italian population. The programme, which started in 1982, includes regional and local surveys in all the administrative districts and intensive investigations of factors which influence indoor radon levels. The survey is organized by statistical areas of sampling to obtain representative samples of houses. The definition of the areas takes into account basic parameters e.g. geolithological environments, radon soil gas from underlying soils and rocks, specific activities of local building materials, climatic and seasonal variations, building technology, types of houses and town planning. The collected data may also be used for the compilation of radon risk maps to plan special monitoring and remedial actions if needed. Preliminary results concerning the above items are discussed.     

Glowing connections

This paper gives the results of a series of experiments and how they shed light on problems of electrical fires. Experimental glowing connections were made by allowing wires to make poor contact with another object in series in a circuit. Note: The information in this paper was presented in the course “Electrical fires” at the University of Wisconsin—Extension, Madison, Wisconsin, April 1982.     

Smoke development at different energy flux levels in an NBS smoke density chamber

An automatically controlled high-energy flux heater has been developed and utilized in an NBS Smoke Density Chamber.     

On the potential of combining neutron activation analysis and particle induced X-ray emission (PIXE) for micro- and microdistribution analysis of hard metals in human tissues

Tungsten carbide and cobalt are the main components of hard metal alloy while other metals such as chromium, niobium, tantalum, titanium and vanadium are sometimes added in smaller amounts. Exposure to hard metal dusts can induce a lung fibrosis with cobalt playing a major role. In order to provide information on the role that each metal may have in causing this disease, determination of the total content and the distribution of inhaled metals in lung tissue of hard metal workers is of paramount importance. However, samples such as transbronchial biopsy and bronchoalveolar lavage (BAL), often used in the medical diagnosis of pneumoconiosis, only allow for a small amount of material. This calls for sensitive and accurate analytical procedures for microdetermination and distribution of metals in pulmonary tissue and cellular material, such as macrophages. This work proposes a combination of sophisticated analytical techniques such as neutron activation analysis (NAA), currently applied to the determination of the total concentration of more than 30 elements in biological specimens, and PIXE analysis, particularly microPIXE, which has a great potential for microdistribution analysis in small biological samples. Principles and perspectives for the combined use of these techniques for the analysis of human tissue are outlined and discussed. NAA: determination of hard metals in lung tissue are carried out by neutron irradiation (2 × 10¹⁴ neutrons cm⁻² s⁻¹) in the HFR reactor of Petten. After neutron activation, radiochemical separations of ⁶⁰Co, ¹⁸⁷W, ¹⁸²Ta, ⁵¹Cr followed by computer-based high resolution gamma ray spectrometry allow the measurement of these elements in pulmonary tissues with sensitivities ranging from 10⁻⁴ μg (Cr) to 10⁻⁶ μg (W). PIXE: this technique is multielemental and of relatively high sensitivity (μg/g) even in small total sample masses of from 10 to 100 μg, thus allowing the analysis of parts of needle biopsies. Whereas PIXE has been successfully applied to many medical problems, its usefulness is limited in the total samples analysis for cobalt-related hard metal disease, due to the low levels of cobalt in tissue combined with severe element interferences from the generally more abundant metal, iron. Nevertheless, microPIXE, a special variety of the method scanning over the sample with a focussed ion beam of about 2 × 2 μm², could complement the NAA findings in total samples in the sense of achieving a microdistribution analysis of hard metals (including cobalt) in suitable thin tissue sections.The availability of specialized facilities at the JRC such as the powerful HFR reactor (Petten), the NAA laboratories (Ispra) and the microPIXE facility (Geel) could represent a European ‘reference pole’ for the study of metals in tissues of hard metal diseased subjects.     

Reliability of corrosion-damaged steel structures using interval probability theory

Engineering decisions concerning the performance of existing structures must be made in the presence of uncertainties. The remaining capacity of corroded steel structures provides a good example of different aspects of uncertainty. These include: an unknown or partially known extent of damage; a variability in loading and an uncertain reserve of structural capacity depending on the mode of failure. The theory of structural reliability has been developed to provide a method of analysis for structural safety. In this paper, methods are proposed to compute the component reliability of corrosion-damaged steel members. The application of a recently developed theory called interval probability theory for system reliability is illustrated using the data obtained from actual samples of corroded beams.     

Post-crash fire testing of titanium fuselages

The problem … maintain fuselage integrity and a survivable cabin environment during a post-crash fire. Its high melting point made titanium an attractive candidate for the large-scale test discussed here. Note: This paper is an adaptation of Report No. FAA-RD-71-3, “Titanium Fuselage Environmental Conditions in Post-Crash Fires,” prepared by the author for the Federal Aviation Administration. The report was also the basis for Mr. Sarkos’ presentation at the 75th Annual Meeting of the National Fire Protection Association in San Francisco on May 18, 1971.