The ratio of crystallinity and thermodynamical interactions of polycaprolactone with some aliphatic esters and aromatic solvents by inverse gas chromatography

Summary The retention diagrams of benzene, toluene, ethyl benzene, chloro benzene, n-propyl benzene, isopropyl benzene, methyl acetate, ethyl acetate, n-propyl acetate, n-butyl acetate and isoamyl acetate on the polycaprolactone were plotted at temperatures between 70 and 140^oC by inverse gas chromatography technique. Percent crystallinity of polycaprolactone were obtained at temperatures below melting point from the retention diagrams of benzene, toluene and ethyl benzene. It was concluded that the data obtained by inverse gas chromatography were comparable those of obtained by differential scanning calorimetry. Specific retention volume, V_g^o, Flory-Huggins polymer-solvent interaction parameters, ₁₂, the weight fraction activity coefficients of the solvents at infinite dilution, ₁, effective exchange energy parameters, X_eff were determined. Later, the partial molar heat of sorption, H_1,sorp and the partial molar heat of mixing, H₁ were obtained from the slope of the logarithm of specific retention volume, Ln V_g^o versus 1/T plot and from the slope of the logarithm of the weight fraction activity coefficients, ₁versus 1/T plot, respectively.     

Biosorption of Acid Red P-2BX by lichens as low-cost biosorbents

The aim of this study is to examine the dye biosorption properties of lichen species called Cladonia convoluta and Evernia prunastri. Since lichens are extensively found in the environment, their suitability as a cheap adsorbent has been investigated in this study. The optimal parameters for textile dye biosorption were also determined. The dried lichen biomass showed better dye biosorption capacity than ash lichen biomass. C. convoluta had better dye biosorption capacity than E. prunastri. Dye biosorption rate was found as 71.41% at optimal conditions. This study concluded that C. convoluta was a successful and cheap biosorbent for treatment of water contaminated by Acid Red P-2BX dye.     

Effect of Bicarbonate Salts and Sequential Using of Frying Oil on Acrylamide and 5-Hydroxymethylfurfural Contents in Coated Fried Chicken Meat

In this research, the effect of different bicarbonate salts (sodium and ammonium) and their doses (0, 1, 2, and 3 g/100 g raw material) in the coating batter formula use and the sequential use of frying oil (1st, 2nd, 3rd, and 4th) on 5-hydroxymethylfurfural and acrylamide contents in coated fried chicken meat. The addition of sodium bicarbonate was efficient for reducing acrylamide content, but it increased browning and 5-hydroxymethylfurfural content compared to the control. When increasing the doses of sodium and ammonium bicarbonate from 1 to 3 g/100 g of raw material, the acrylamide content of samples did not change significantly, although adding sodium bicarbonate significantly reduced the acrylamide content as a control. These research results showed that using about 1 g/100 g raw material sodium bicarbonate rather than ammonium bicarbonate and as little frying oil as possible use during the production of coated and fried meat results in lower contents of 5-hydroxymethylfurfural and acrylamide.     

Thermal Conductivity and Viscosity of Nanofluids Having Nanoencapsulated Phase Change Material

In this study, the thermal conductivity and viscosity of nanofluids, composed of a base fluid and nanoencapsulated phase change material (NEPCM), were investigated experimentally. The NEPCM was prepared by the encapsulation of n-nonadecane as phase change material with diethylenetriamine and toluene-2,4-diisocyanate using interfacial polymerization method. The NEPCM was characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC) analyses. In the preparation of the nanofluids containing NEPCM, two different base fluids, water and ethylene glycol (EG), were used. The concentration of NEPCM and the working temperature were selected as the main parameters. It was found that the viscosity of the nanofluids decreases with increasing temperature and increases with increasing solid concentration. The viscosity was also expressed as a function of the solid concentration and temperature. The thermal conductivity of the nanofluids was found to increase with increasing temperature. Thermal conductivity exhibited an increasing tendency with increasing solid concentration, but the changes in thermal conductivity according to base fluid are in the range of uncertainty of the measurement for both nanofluids with a solid volumetric fraction lower than 1.68%.     

Standardization problem of author affiliations in citation indexes

Academic effectiveness of universities is measured with the number of publications and citations. However, accessing all the publications of a university reveals a challenge related to the mistakes and standardization problems in citation indexes. The main aim of this study is to seek a solution for the unstandardized addresses and publication loss of universities with regard to this problem. To achieve this, all Turkey-addressed publications published between 1928 and 2009 were analyzed and evaluated deeply. The results show that the main mistakes are based on character or spelling, indexing and translation errors. Mentioned errors effect international visibility of universities negatively, make bibliometric studies based on affiliations unreliable and reveal incorrect university rankings. To inhibit these negative effects, an algorithm was created with finite state technique by using Nooj Transducer. Frequently used 47 different affiliation variations for Hacettepe University apart from “Hacettepe Univ” and “Univ Hacettepe” were determined by the help of finite state grammar graphs. In conclusion, this study presents some reasons of the inconsistencies for university rankings. It is suggested that, mistakes and standardization issues should be considered by librarians, authors, editors, policy makers and managers to be able to solve these problems.     

Ternary encoding based feature extraction for binary text classification

A novel framework for termset based feature extraction is proposed for binary text classification. The proposed approach is based on the encoding of the terms within a termset. The ternary codes ‘+1’ and ‘?1’ are used to represent the class that the term supports, whereas ‘0’ denotes no support to any of the classes. Four different encoding schemes are proposed where the term weights and the term occurrence probabilities in the positive and negative documents are used to define the ternary code of a given term. The ternary patterns are utilized to define novel features by splitting them into positive and negative codes where each code is treated as a different feature extractor. Use of the derived features individually and together with bag of words representation are both investigated. The histograms of the resultant features are also employed to study the improvements that can be achieved using a small number of additional features to augment bag of words representation. Experiments conducted on four benchmark datasets with different characteristics have shown that the proposed feature extraction framework provides significant improvements compared to the bag of words representation.     

Cobalt loaded organic acid modified kaolin clay for the enhanced catalytic activity of hydrogen release via hydrolysis of sodium borohydride

Inorganic acids such as hydrochloric acid (HCl), nitric acid (HNO₃) and sulphuric acid (H₂SO₄) are generally used in the acid modification of clays. Here, CoB catalyst was synthesized on the acetic acid-activated kaolin support material (CH₃COOH -kaolin- CoB) with an alternative approach. This prepared catalyst, firstly, was used to catalyze the hydrolysis of NaBH₄ (NaBH₄-HR). The structure of the raw kaolin, kaolin-CH₃COOH, and CH₃COOH-kaolin-CoB samples were characterized by X-ray diffraction spectroscopy (XRD), Fourier transforms infrared spectroscopy (FTIR), scanning electron microscope (SEM), and nitrogen adsorption. At the same time, this catalyst performance was examined by Co loading, NaBH₄ concentration, NaOH concentration, temperature and reusability parameters. The end times of this hydrolysis reaction using raw kaolin-CoB and CH₃COOH-kaolin-CoB were found to be approximately 140 and 245 min, respectively. The maximum hydrogen generation rates (HGRs) obtained at temperatures 30 °C and 50 °C were 1533 and 3400 mL/min/g_catalyst, respectively. At the same time, the activation energy was found to be 49.41 kJ/mol.