ZrO2对CaO-SiO2系玻璃析晶的影响

通过DSC曲线研究了不同含量的ZrO2对CaO-SiO2系玻璃析晶的影响,根据JMA方程计算动力学参数(如析晶活化能E、频率因子ν、晶化指数n)。从计算结果可以看出,随着ZrO2含量的增加,析晶活化能E减少,而频率因子ν和晶化指数n增加。当ZrO2含量为7%时,E值最小:235.58kJ/mol;n值最大:4.70。说明ZrO2在CaO-SiO2玻璃体系是有效的晶核剂。     

Preparation and characterization of polyelectrolyte copolymers containing methyl methacrylate and 2-hydroxyethyl methacrylate. I. Polymers based on methacrylic acid

Acidic polyelectrolyte copolymers containing 2-hydroxyethyl methacrylate (HEMA), methyl methacrylate (MMA), and methacrylic acid (MAA) were prepared by free radical polymerization to high conversion in solution. Copolymer yields were obtained by gravimetry (all in the 30–50% range), relative molecular weights estimated by intrinsic viscosity measurements (all in the 50–70 cc/g range), tacticity by ¹³C nuclear magnetic resonance (NMR) spectroscopy (all polymers predominantly syndiotactic with some atactic content), and composition by acid/base titrations in conjunction with ¹H-NMR spectroscopy (all close to the monomer charge ratios). Acid strengths or apparent pKa's were examined as a function of extent of ionization. Measurements performed in water indicated that the compact/extended coil transformation in predominantly syndiotactic polymethacrylic acid occurs also in copolymers of similar tacticity containing moderate to high concentrations of MAA. The apparent pKa of such polymers containing only small amounts of MAA did not vary with extent of ionization, indicating a low degree of interaction between the acid groups. In copolymer pairs containing similar amounts of MAA but differing HEMA and MMA contents, the polymer containing more HEMA appeared the stronger acid, presumably due to a better solvation of that polymer which would increase the net spatial charge–charge separation and decrease cooperative effects that lead to suppressed ionization.     

聚丙烯工程化研究

采用纳米填充、交联和转晶的复合技术对聚丙烯进行了改性，优选了纳米碳酸钙为填料。当β成核剂用量为0．5％、助交联剂为3％时，复合材料的综合性能达到最好，接近普通工程塑料的各项力学性能。红外光谱分析和熔体质量流动速率的测定表明，复合材料体系产生了微交联；DSC分析发现，PP材料的聚集态结构中含有β球晶。     

Factors influencing magnetic polymer microspheres prepared by dispersion polymerization

Magnetic iron oxide (Fe₃O₄) was prepared by a coprecipitation method. Core–shell composite magnetic polymer microspheres with carboxyl groups were synthesized by the dispersion polymerization of styrene and acrylic acid in the presence of magnetic oxide, and dibenzoyl peroxide was used as an initiator. The synthesized magnetic polymer microspheres were characterized with X‐ray diffraction, transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, and so forth. The results indicated that the product was single‐phase Fe₃O₄, and its average size was about 10 nm. The configuration of the microspheres, which contained carboxyl groups, was spherical, and the average size was about 2 μm. The results of vibrating sample magnetometry tests showed that the magnetic powders produced by different surfactants had different saturation magnetizations. When poly(ethylene glycol) with a weight‐average molecular weight of 4000 was used as a surfactant, the saturation magnetization of the samples reached 69.2 emu/g. The factors that affected the shape, magnetism, size, and distribution of the microspheres were also studied. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

An SVD-based adaptive robust speech steganography using MDCT coefficient

Multimedia Tools and Applications - Speech is one of the essential ways of communication. The study of speech steganography provides great value in information security. To improve imperceptibility...     

A novel ADRC‑based design for a kind of fexible aerocraft

The paper presents a novel control design, which is based on the idea of active disturbance rejection control (ADRC), for a kind of fexible aerocraft whose controlled variable cannot be measured directly. Since the original frame of ADRC cannot be directly applied, the paper puts forward a new extended state observer (ESO) and the corresponding ADRC law. In order to assign the poles of the closed-loop system to ideal positions such that the vibration can be quickly suppressed, an elastic damping term is added into feedback law. The advantages of the new ESO for efectively estimating both the rigid mode and elastic mode from the measurements are discussed. Moreover, the analysis on the stability, the relative stability and the steady state of the closed-loop system is given. Finally, the efectiveness and robustness of the proposed ADRC are verifed by simulations.     

油井井下自动定量加药装置的研究及应用

基于传统加药方式存在着药液浪费严重,不能连续发挥药效,人工劳动强度大等不足之处,提出了对井下自动定量加药装置的研究。该装置的设计方案包括总体方案设计、机械结构设计、电机控制系统设计、工作可靠性设计四个部分,施工工艺包括工作参数设置和管柱连接二方面内容。应用结果表明,该装置可以根据现场情况实现井下定时、定量加药,能有效地减少管柱的结垢及腐蚀,克服了传统加药方式存在的不足。     

基于Kanai-Tajimi模型的地震作用荷载新型识别方法

目的研究一种识别地震作用荷载的方法,为地震作用荷载的识别与相应结构的动力特性、损伤的识别提供一种新的途径,进一步为结构的安全性、损伤进程和耐久性等研究提供理论参考.方法利用Kanai-Tajimi模型将单位强度白噪声过程模拟为未知的地震作用,并将其作用在结构上,然后根据数值模拟计算得到的结构体系响应作为观测量,采用Kalman滤波对未知荷载状态加以识别.结果最终可以利用结构的加速度响应反演得出地震作用的等效荷载,在人工添加5%观测噪声的条件下,最大误差率为7%左右,而在人工添加10%观测噪声的条件下,最大误差率为8%左右.结论通过算例的验证,说明笔者所采用的方法精度较高,获得了较好的识别效果.     

Bone Tissue Response to the Bone-like Tissue Coating on Titanium

The objective of this study was to investigate the effects of mineralized bone nodules, formed in vitro by bone marrow stromal cells(BMSCs), on the new bone formation in bone defect and on implant surface. The mineralized bone nodules were generated by culture of Lewis rats BMSCs on titanium disks in osteogenic induction medium. The gap-healing animal model was used to create the bone defect facing the disk. The titanium disks in the presence of B group or in the absence of NB group bone nodules were randomly placed into one of the rat distal femurs. This self-control design was used to compare the bone formation in defects and on titanium surface, by Micro-CT, fluorescence staining, histological and histomorphometric analysis. The new bone formation parameters in bone defect area of B group were significantly higher than those of NB group at 2 weeks, including bone volume fraction, trabecular thickness and bone area ratio. The bone nodules pre-stained with Alizarin red disappeared mostly at 2 weeks, while the red fluorescence reappeared in the newly formed bone away from the disk surface. For the bone-implant contact, B group showed lower values than NB group at 2 weeks, but no significant difference was found at 4 weeks. Our results indicate that the mineralized bone nodules can be resorbed in vivo and promote the early osteogenesis in the bone defects, and bone nodules may be applicable for new bone generation in bone defect or modification of tissue engineering scaffold.     

基于改进Kendall-f算法的发电机定子温度分析

在线监测发电机定子温度可有效发现定子部分过热性故障,如何从检测的温度数据中提取反映定子故障预警的信息是目前国内外研究的热点。该文采用可变窗改进Kendall-f算法处理监测温度数据,提取其变化趋势特征信息;采用偏度分析提取监测温度异常值,从而正确诊断定子过热性故障,仿真分析及实验结果表明该方法有效提高了定子温度监测与预警的准确率。