冬凌草硒多糖的制备及其抗氧化活性分析

以济源冬凌草为原料,水提得到冬凌草多糖,对多糖进行结构修饰制得冬凌草硒多糖.采用UV、FTIR、SEM、TGA、HPLC对冬凌草多糖以及硒多糖结构进行表征;通过1,1-二苯基-2-三硝基苯肼(DPPH)自由基法、2,2-联氮-二(3-乙基-苯并噻唑-6-磺酸)二铵盐(ABTS)自由基法、羟基自由基法以及还原能力测定4种方法对冬凌草多糖及其硒多糖的抗氧化活性进行探究.结果表明,冬凌草硒多糖中硒含量为1.35 mg/g.硒化修饰后,冬凌草多糖的基本骨架得到保留,单糖种类未发生改变,但分解温度降低、稳定性下降,多糖形貌也发生明显变化,球状与条状形貌增多,片状形貌减少.在体外抗氧化性实验中,当冬凌草硒多糖质量浓度为1.6 g/L时,对DPPH自由基、ABTS自由基、羟基自由基清除率分别为68.69％、86.90％、45.12％,均强于冬凌草多糖.     

A Strategy of Liquid-Grafted Slippery Sponges with Simultaneously Enhanced Absorption and Desorption Performances for Crude Oil Spill Remediation

Crude oil spill accidents pose a worldwide environmental threat. Oleophilic and hydrophobic absorbents that can selectively absorb oil from water have shown promising application potential in oil spill remediation. Simultaneous optimization of the absorption and desorption speed of absorbents towards oil is highly desirable for their recyclable usage, but remains a great challenge, because these two properties are generally conflicting. Here, a facile and ingenious strategy is proposed to tackle the above challenge via surface modification of porous sponges with highly flexible linear polydimethylsiloxane (LPDMS) brushes. The LPDMS brushes feature liquid-like properties at room temperature owing to its extremely low glass transition temperature, and act as a covalently-grafted lubrication layer throughout the 3D network channels of the sponge, which can minimize contact angle hysteresis and reduce friction between oil and sponge channel. Compared to the prevalent cross-linked polydimethylsiloxane (CPDMS) modification strategy, sponges modified with LPDMS brushes not only shows significantly enhanced absorption speed, but also exhibits superior desorption dynamics towards viscous crude oils. The design strategy of slippery sponges with liquid-like molecules may open a new avenue for developing advanced absorbents with simultaneously enhanced absorption and desorption performances for liquid separation and purification applications.     

淬火温度对铸造Fe—B—Ti合金组织和性能的影响

通过不同的热处理淬火温度改变铸造Fe—B—Ti合金的组织，探讨了铸造Fe—B—Ti合金不同组织与性能的关系。试验结果表明：淬火温度较低时，硼化物变化较小，网状分布趋势明显；淬火温度较高时，硼化物断网和团聚化趋势明显加快。淬火温度1050℃时，硼化物网状特征消失，基本上都变成了团块状、颗粒状和杆棒状分布。随着淬火温度升高，硬度和韧性增加，超过1000℃，硬度和韧性变化不明显。淬火温度1050℃时，综合性能良好。     

大型风电球墨铸铁件的生产实践

以轮毂为例,介绍对大型风力发电机球墨铸铁件生产工艺进行的试验研究。通过优化铸型工艺,采用适当的浇注系统和低温石墨化退火工艺,选择合理的化学成分,控制球化处理与孕育处理,可生产出各项性能指标合格的风电铸件。     

基于数值模拟的等效拉延筋设计与优化

拉延筋在汽车覆盖件拉深成形中起着十分重要的作用。利用拉延筋可以在较大范围内调节和控制板料的变形程度和变形分布,抑制破裂、起皱、面畸变等多种冲压质量问题的产生。在很多情况下,拉延筋的设置合理与否将决定覆盖件拉深的成败。文章借助eta/DYNAFORM软件,模拟某轿车B柱加强板在无/有拉延筋的模具上进行拉深的全过程,通过模拟结果分析比较,确定拉延筋的合理布局及数量,最后结合正交实验法,优化拉延筋的结构参数。     

稀土元素Ce对纯铜导电性及力学性能的影响

在纯铜中加入稀土元素Ce,研究不同含量Ce及不同保温时间对纯铜的导电性、抗拉强度、硬度、耐磨性等的影响.研究发现在纯铜中加入Ce起到净化、去杂质的作用,改善纯铜的导电性;也可使晶粒细化,改善纯铜的抗拉强度及其它力学性能.且熔炼时加入稀土后的保温时间要适当.在试验的条件下保温时间以30 min为宜,稀土Ce的最佳加入量w为0.02%.     

地下环境中电子设备的腐蚀与防护

程环境中电子设备所承受的湿度、温度、腐蚀性气体、空气沉积物、微生物等环境应力因素及其腐蚀效应，概述总结了电子设备腐蚀机制及主要类型，并提出电子设备设计与使用中抑制腐蚀的措施.     

钛合金冷坩埚电磁约束铸造工艺研究

针对液态下化学性质相对活泼的钛合金,采用冷坩埚技术对电磁约束铸造工艺过程进行了试验研究,考察了工艺条件对成形坯件表面质量和内部组织的影响.结果表明:试样抽拉速度变化对表面质量和宏观组织的影响明显,加热功率虽然对组织变化影响不大,但对表面质量影响较为显著.通过优化工艺,可以获得既有较光滑铸造表面又具有一次定向凝固组织的钛合金铸件.讨论了铸造过程裂纹和组织缺陷的形成机理,获得到了表面光滑无裂纹,宏观组织为柱状晶的钛合金大尺寸圆坯.     

CSP技术连铸薄板坯气瓶钢中夹杂物研究

系统研究了珠钢电炉炼钢－钢包炉－CSP薄板坯连铸工艺生产气瓶钢的薄板坯中夹杂物在厚度方向分布规律以及夹杂物的种类，这些分析结果为进一步提高薄板坯的洁净度提供理论依据。     

Defect classification using a new feature for pulsed eddy current sensors

The objective of this study is to identify defects such as surface cracks, subsurface defects and metal losses using feature based pulsed eddy current sensors. A new feature, termed as the rising point, related to the propagation time of electromagnetic waves in metallic targets is proposed for defect classification. Experimental studies of the validation, robustness of the new feature of rising time are reported. In addition to other features, defects can be detected and quantified robustly and lift-off can also be derived from the rising time. Conclusion and further work are derived on the basis of the findings.