Stable and Bright Pyridine Manganese Halides for Efficient White Light-Emitting Diodes

Highly efficient lead halide perovskites with tunable emission performance have become new candidate materials for light-emitting devices and displays; however, the toxicity of lead and instability of halide perovskites greatly limits their application. Herein, rapid and large-scale synthesis of highly emissive organic–inorganic manganese halide perovskites, (C₅H₆N)₂MnBr₄ and C₅H₆NMnCl₃, are presented by a one-pot solution-based method, of which (C₅H₆N)₂MnBr₄ displays a high absolute photoluminescence quantum yield (95%) in the solid-state. The developed (C₅H₆N)₂MnBr₄ perovskite noticeably exhibits high stability. Therefore both as-synthesized green and red emissive manganese-based phosphors with superior optical properties are used to fabricate blue light pumped white light-emitting diodes (WLEDs), displaying excellent quality white light with a high color rendering index value of 91 and a correlated color temperature of 5331 K. This study not only presents the robust large-scale production synthetic approach for organic–inorganic manganese halide perovskites, but also facilitates the development of high-performance phosphors for future lighting and display technologies.     

Performance evaluation of broadcasting strategies in cognitive radio networks

Broadcasting is an important phenomenon, because it serves as simplest mode of communication in a network, via which each node disseminates information to their neighboring nodes simultaneously. Broadcasting is widely used in various kind of networks, such as wireless sensor networks, wireless networks, and ad-hoc networks. Similarly, in cognitive radio networks (CRNs), broadcasting is also used to perform many tasks including neighbor discovery, spectrum mobility, spectrum sharing, and dissemination of message throughout the network. The traditional approach that has been used as broadcasting in CRNs is simple flooding in which a message is disseminated in the network without any strategy check. Simple flooding can cause major setbacks in the network, such as excessive redundant rebroadcasts, and collision drops which collectively are termed as broadcast storm problem. To reduce the effects of broadcast storm problem in wireless networks, we propose and compare four broadcasting strategies for cognitive radio networks in this paper. These four strategies are: (1) probability based, (2) counter based, (3) distance based, and (4) area based. Extensive NS-2 based simulations are carried out on different threshold values for each broadcasting strategy. After experimental evaluation, it is demonstrated that counter based broadcasting surpasses other broadcasting strategies by achieving maximum delivery ratio of 60% and by decreasing redundant rebroadcasts and collision drops up to 44 and 37% respectively.

     

Unlocking the Potential of Lithium Metal Batteries With a Sulfite-Based Electrolyte

Lithium metal batteries (LMBs) have the potential to significantly increase the energy density of advanced batteries in the future. Nonetheless, the dendritic lithium structures and low Coulombic efficiency (CE) of LMBs currently impede their applied implementation. Herein, a sulfite-based electrolyte (SBE/FEC), including 1.0 m lithium bis(fluorosulfonyl)imide in a blend of ethylene sulfite and diethyl sulfite, and 5 wt% fluoroethylene carbonate is proposed. SBE/FEC is a highly efficient inhibitor against the growth of lithium dendrites through the formation of robust solid electrolyte interphase (SEI) layer. Raman spectroscopy and theoretical calculation indicate that in SBE/FEC, a significant portion of FSI⁻ exists in associated complexes, playing a vital role in the creation of LiF-rich passivation. Besides, the sulfite solvents decompose and yield polysulfide complexes in the SEI layer. A direct correlation between the proportion of cation–anion complexes and the contact angle between electrolyte and separator is elucidated through molecular dynamics simulations. The SBE/FEC system exhibits high CEs (98.3%) with Li||Cu cells, along with a steady discharge capacity of ≈137 mA h g⁻¹ in Li||LiFePO₄ cell. This study presents an effective approach for enhancing LMBs with sulfite-based electrolytes, which can lead to high-energy-density next-generation rechargeable batteries.     

Sleep assistive dynamic bandwidth assignment scheme for passive optical network (PON)

In passive optical network (PON), in addition to efficient bandwidth management, a dynamic bandwidth assignment (DBA) scheme can also enhance the energy efficiency performance of the optical networks units (ONUs) during sleep mode. A few such green DBA schemes have been proposed in literature for EPON, however, ITU compliant PONs have not got attention. In this study, the role of a DBA scheme during the cyclic sleep mode for XGPON has been investigated. A sleep assistive (SA)-DBA scheme is proposed that not only improves the energy saving performance of cyclic sleep mode but also reduces the upstream delays and variance for all the type-2 (T2), type-3 (T3) and type-4 (T4) traffic classes. Although, the upstream delay of type-1 (T1) traffic class slightly increases, the average upstream delay of all the traffic classes remains below the set target delay limit of 56 ms.