Kinetics of chlorination of tantalum pentoxide in mixture with sucrose carbon by chlorine gas

The mechanism and kinetics of β-Ta₂O₅ chlorination, mixed with sucrose carbon, have been studied by a thermogravimetric technique. The investigated temperature range was 500 °C to 850 °C. The reactants and reaction residues were analyzed by scanning electronic microscopy (SEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller method for surface area (BET). The effect of various experimental parameters was studied, such as carbon percentage, temperature, chlorine partial pressure, and flow, use of the multiple sample method, and carbon previous oxidation. The carbon percentage and previous treatment have an effect on the system reactivity. The temperature has a marked effect on the reaction rate. In the 500 °C to 600 °C temperature interval, the apparent activation energy is 144 kJ/mol of oxide, while at higher temperatures, the activation energy decreases. With high chorine partial pressures, the order of reaction is near zero. The kinetic contractile plate model, X=kt, considering carbon oxidation as the controlling stage, is the one with the best fit to the experimental data. A probable mechanism for the carbochlorination of β-Ta₂O₅ is proposed: (1) activation of chlorine on the carbon surface, (2) chlorination of Ta₂O₅, (3) oxidation of carbon, and (4) recrystallization of β-Ta₂O₅.     

无磷洗涤剂的现状及存在问题

含磷洗涤剂中含的“磷”主要是STPP，作用很大但对环境的危害也很大，它是造成地表水体出现富营养化的重要原因之一，所以许多地方政府都在实行“禁磷”——禁止销售、使用含磷洗涤剂。现在我国使用的无磷洗涤剂中代磷助剂主要有3种，其中4A沸石用量最大，但它会对环境带来新的问题。主要介绍了含磷洗涤剂的危害及无磷洗涤剂的应用现状，指出了我国禁磷后将面临的问题。     

Traction-based Completed Adjoint Double Layer Boundary Element Method in elasticity

This paper is concerned with a traction-based Completed Adjoint Double Layer Boundary Element Method to solve for the surface traction of a system of rigid particles embedded in an elastic matrix. The main feature of the method is a single layer representation of the displacement field, which leads to a system of second-kind integral equations for the traction field, the extreme eigenvalue of which could be deflated, allowing iterative solution strategies to be effectively applied. The method is therefore most suitable for large-scale simulations of particulate solids. The method is benchmarked against some known analytic solutions, including the difficult stress singularity problems at sharp edges. The effectiveness of the method in dealing with a large number of inclusions is also demonstrated with an elongational deformation problem involving up to 25 inclusions.Research supported by the Australian Research Council (to NP-T and X-JF) and the National Natural Science Foundation of China (X-JF).     

Web-based systems design: a study of contemporary practices and an explanatory framework based on “method-in-action”

This paper reports the findings of a detailed study of Web-based systems design (WBSD) practices in Ireland based on data collected over a 3-year period (2002–2005), the objectives of which were to (1) contribute towards a richer understanding of the current “real-world” context of WBSD by characterising the profile of a typical project (team size, timeframe, nature of requirements, etc.) and identifying the key challenges, constraints, and imperatives (i.e. “mediating factors”) faced by Web-based system designers, and (2) understand how those contextual parameters and mediating factors influence the activity of WBSD as regards the selection and enactment of whatever design practices are therefore engaged (i.e. the use of methods, procedures, etc.). Data was gathered through a survey which yielded 165 usable responses, and later through a series of semi-structured qualitative interviews. Using grounded theory, an explanatory conceptual framework is derived, based on an extension of the “method-in-action” model, the application of which to WBSD has not been previously investigated in depth. It is proposed that this framework of WBSD issues is valuable in a number of ways to educators, researchers, practitioners, and method engineers.     

Synthesis, characteristics and oxygen-sensitive properties of SrMgxTi 1 − xO3 nanocrystals

SrMg_xTi_{1 - x}O₃ nanocrystals (x = 0.1–0.6) were synthesized by the stearic acid gel method. Powder samples were characterized by X-ray diffraction and X-ray photoelectron (XP) spectroscopy. The results showed that the lattice parameter a and the O 1s XP spectrum changed not only with the Mg content x but also with the grain size d of the samples. The conductivity of a thick film specimen fabricated on an aluminium oxide wafer was investigated in a nitrogen—oxygen atmosphere.