The Synthesis of Covalent Triazine-Based Frameworks via Friedel–Crafts Reactions of Cyanuric Chloride with Thienyl and Carbazolyl Derivatives for Fluorescence Sensing to Picric Acid,Iodine and Capturing Iodine

A multifunctional thiophene-based covalent triazine framework (TTPATTh) with triphenylamine as core is synthesized by Friedel–Crafts reaction of cyanuric chloride with thienyl derivative for the first time. The yield of TTPATTh (99.59%) is far higher than that of the carbazole-based CTF (TTPATCz, 47.03%). TTPATTh and TTPATCz possess high BET surface areas with 1235 and 2501 m² g^–1 as well as high pore volumes with 1.60 and 2.23 cm³ g^–1, respectively. TTPATTh and TTPATCz have high thermal stability with high thermal decomposition temperatures of 514 and 598 °C in nitrogen atmosphere. With the introduction of triazine rings, the fluorescence sensing sensitivities of TTPATTh and TTPATCz to picric acid and iodine are improved significantly. Especially for TTPATTh, the K_sv values reach 5.95 × 10⁵ and 1.61 × 10⁴ L mol^–1, and LODs reach 1.02 × 10^–12 and 1.86 × 10^–12 mol L^–1. To the best of the knowledge, this is the most sensitive value among thiophene-based porous organic polymers to PA and I₂. Furthermore, TTPATTh and TTPATCz can also adsorb iodine in vapor phase, cyclohexane solution and aqueous solution, and release iodine by heating or in ethanol solution. The efficiency of controlling the release of iodine is higher than that in ethanol.     

持续发展是唯一出路

讨论了人类、环境与发展的关系，指出不适当的发展模式已使三者之间形成恶性循环，必须及时地改变发展模式。列举了中国面临的严重环境问题，指出只有走可持续发展的道路才是唯一出路。并提出为实施可持续发展应注意的６个主要问题。     

Kynar—500涂装工艺与涂层性能研究

介绍了Kynar－500涂料的涂装工艺，并对涂层的性能作了试验与分析。     

工业废渣磷石膏用作充填材料的研究

研制了以工业废渣磷石膏为基材的充填材料.改性后磷石膏的耐水性大大增强,抗压强度≥0.79 MPa、渗透系数≤1×10-5cm.s-1,并且具有合适的C、Φ值.     

Water-soluble and amphiphilic polymers

Summary Three PEO-PSt-PEO triblock polymers and their parent ho-nopolystyrene have been studied by means of light scattering technique in chloroform, toluene and ethyl acetate. It has been found that the weight average molecular weights calculated by using the equation Mapp- were unbelievable negative values; and the largest deviation appeared for the sample with PEO mole content of about 50%. Data of PSt-PEO-PSt triblock polymers in literature have been quoted and discussed.     

Hydrothermal products of the C3MS2-C12A7-MgO system

The autoclave products of reduced steel-slag of an electronic furnace mainly containing C₃MS₂ phase were detected. The hydrothermal products of this slag included calcio-chondrodite, brucite, and hydrogarnet phases. When suitable (CaO + MgO)/SiO₂ molar ratios were chosen, C₃MS₂ can react with SiO₂ to produce calcium silicate hydrates tobermorite, xonotlite, gyrolite, and truscottite phases with different saturated water vapor pressures. The phase brucite was present along with tobermorite, whereas phases Mg-xonotlite, Mg-gyrolite, and Mg-truscottite can rarely coexist with brucite. Hydrogarnet phase disappeared when Mg-truscottite was formed.     

几种表面活性剂在香精产品中的应用

本文阐述了几种表面活性剂在香精中应用的调配研究过程以及期间出现的不同现象,并对其进行了对比、比较.细述了这几种表面活性剂在应用过程中所出现的不同特征.     

普钙产品转化率的数值计算方法

对影响普钙产品转化率的各种因素进行了分析,利用MATLAB 软件包得到了转化率的计算公式,提出了确定未分解磷矿的比例和由倍半氧化物引起的有效磷退化幅度的方法,为生产系统的预测和调整提供了一种途径。     

A Non-Line-of-Sight mitigation localization algorithm for sensor networks using clustering analysis

Non-Line-of-Sight propagation of wireless signal has an impact on measured distances in range-based localization and will bias the final localization results. A new localization algorithm is proposed in this paper to mitigate Non-Line-of-Sight errors when there are more than enough anchor nodes deployed around the node to be located. This algorithm utilizes multi-round clustering analysis to filter the pre-located estimators which derive from all possible subsets of measured distances. In each round, the method density-based spatial clustering of applications with noise is adopted. Simulations show that the proposed algorithm can effectively improve localization accuracy not only when the measured distances with Non-Line-of-Sight error are minor but also under the condition that all of them suffer random Non-Line-of-Sight error.