Poly(3-octylthiophene) as semiconductor for schottky barrier: Effects of doping and storage time

Schottky diodes of aluminium/poly(3-octylthiophene)(P30T)/indium-tin oxide with large active area are prepared by using the proposed new casting technique. Their rectifying behavior and junction characteristics are dependent on whether the P30T is doped and on the storage time, but independent of the thickness of the P30T layer. The present technique can also be applied in a fabrication of electronic devices with other soluble conjugated polymers.     

环境中氚和碳-14

本文介绍了加拿大恰克河实验室有关氚和碳－14在环境中行为和评价的研究。     

大庆长垣外围油田的开发问题

本文在对大庆长垣外围油田的地质情况、油藏类型综合分析评价的基础上,论述了开发这些油田的一系列有关问题。     

双跨换热器传热管在静水中阻尼特性的研究

本文对双跨换热器传热管在静水中的结构阻尼与粘滞阻尼作了简介,并对在总阻尼中占主导地位的挤压膜阻尼作了较深入的讨论。Mulcahy 于80年代初提出的挤压膜阻尼数学模型是较为完善的,其缺陷是未计入管子振幅的影响,本文对它进行了修正。为了验证理论分析的结果,笔者对双跨传热管在静水中的挤压膜阻尼作了实验研究,得出挤压膜阻尼与中间支承板厚度、管子-中间支承板间隙以及管子振幅之间的关系。     

纳米碳酸钙制备过程中添加剂作用机理探讨

采用鼓泡碳化法 ,在最佳反应温度、反应物浓度的条件下 ,考察了添加剂对产物形状及粒径大小的影响 ,得到了直径为 2 0～ 30nm、长径比在 2 0左右且分散性能良好的针状纳米碳酸钙 ,并对添加剂作用机理进行了分析。     

高架桥梁上部结构整体降低施工中的抗风险对策

在高架道路、桥梁改建中,往往遇到需调整桥面标高的情况。以上海市南北高架与内环线高架相连的鲁班路立交SE匝道为例,介绍利用旧桥承台基础,在其上搭设支架和液压系统,然后解除立柱的垂直约束和水平约束,将桥梁上部结构整体分步降低到设计标高。重点介绍针对施工中安全风险点,采取的支撑体系、液压体系、降低顺序原则、上部结构牵拉系统、监测系统等具体措施。     

研究生生态型学术文化建设的探讨

本文立足学术文化研究的现状和意义,引入生态学相关理论构建了生态型学术文化模型,并在此基础上建立了相应的评价体系,针对研究生生态型学术文化作了综合评价,从而导出其“五维一体、协调发展”的优化模式。     

Quantitative analysis of Ni effect on CCT diagrams of novel air-cooled bainite steels using artificial neural network models

The quantitative effect of Ni content on continuous cooling transformation （CCT） diagrams of novel air-cooled bainite steels was analyzed using artificial neural network models. The results showed that Ni may retard the high- and medium-temperature transformation and martensite transformation. The results conform to the materials science theories.     

Highly Efficient Orange and Green Solid‐State Light‐Emitting Electrochemical Cells Based on Cationic IrIII Complexes with Enhanced Steric Hindrance

Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂ sb]PF₆ in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W^–1) at 2.5 V, and 7.1 % and 26.2 lm W^–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells.     

Structure and properties of CE/CTBN/EP blends: II. Effect of EP on the mechanical properties and thermostability of the CE/CTBN system

Carboxyl‐terminated butadiene‐acrylonitrile rubber (CTBN) has often been used to improve the toughness of cyanate ester (CE) resin while sacrificing modulus and thermostability. In this paper, the addition of the appropriate amount of epoxy resin (EP) to the CE/CTBN system is shown to not only increase the modulus and thermostability of the blend, but also improve the toughness. The values of impact strength showed a maximum for the CE/CTBN/EP 100/5/5 blend. The temperature of 10 % weight loss (T₁₀) improves from 376 °C for CE/CTBN 100/5 to 407 °C for the CE/CTBN/EP 100/5/2.5 blend. It is proposed that addition of the appropriate amount of EP can decrease the mobility and increase the stability of CTBN via the reaction between the terminal carboxyl group of CTBN and the hydroxyl group of EP. But a very high EP concentration will decrease the crosslinking density of CE, consequently reducing the mechanical properties and thermostability of the blends. Copyright © 2004 Society of Chemical Industry