Nanocellulose-based fibres derived from palm oil by-products and their in vitro biocompatibility analysis

Abstract

Fibres with nanocellulose isolated from oil palm empty fruit bunches (OPEFBs) were produced. Nanocellulose and PVA-nanocellulose fibres were prepared by wet spinning in an acetone coagulation bath without drawing. The addition of nanocellulose was varied from 10% to 30%, to reveal the beneficial effects of nanocellulose content on the properties of produced spun-fibres. Higher concentration of nanocellulose increased the stiffness of spun-fibres. PVA and PVA-bacterial cellulose fibres were also produced as a control and for comparison, respectively. The nanocellulose fibre formed a compact structure, while PVA fibres had hollow structures. The effect of the produced spun-fibres on the biocompatibility of calf pulmonary artery endothelial cells was assayed by an MTT test. Based on the MTT assay the addition of nanocellulose increased the percentage of cell viability of the obtained spun-fibres slightly. These results point towards the use of sustainable sources of nanocellulose as a beneficial and biocompatible fibre material.     

Thermal performance study of a vacuum integrated solar storage collector (ISSC) with compound parabolic concentrator (CPC)

This paper deals with the energy performance of a new integrated solar storage collector (ISSC) with compound parabolic concentrator (CPC) conceived in the Thermal Process Laboratory in CRTEn Borj Cedria (North of Tunisia). The novelty in this system is the use of transparent vacuum insulation in the annulus between double half-Cylindrical Plexiglass, and the use of automated nocturnal insulation system, which suppresses heat loss during night. Also, the system is equipped with a mobile support permitting to have many collector orientations toward south, east-south, and west-south in order to maximize the incident solar flux. The experimental study of the ISSC system showed that the thermal loss coefficient of ISSC system is equal to 6.16 W/K for ISSC without nocturnal insulation and without vacuum, 4.69W/K for ISSC without nocturnal insulation and with vacuum, and 4.00 W/K for ISSC with nocturnal insulation and with vacuum. The thermal efficiency of the solar collector is equal to 42.92% for ISSC system fixed without vacuum, 45.95% for ISSC system fixed with vacuum, and 50.56% for ISSC system mobile with vacuum. In order to determine the long-term performance of the vacuum ISSC with CPC, the TRNSYS simulations were carried out by using the component modules modeling the ISSC with CPC concentrator (type 74 and type 60f). Comparison between experimental and predicted results for the temperature difference inside the storage tank during 3 days of January showed reasonable agreement. The numerical results for the ISSC system showed that the annual total energy collected (solar) and auxiliary energy were about 4670 and 1561 MJ, respectively. The annual total auxiliary energy represents about 33.4% of the annual total energy collected (solar). During the summer months (June, July, and August), no auxiliary is needed and the solar fraction (SF) is equal to 100%, where as the annual average SF is about 75%.     

Chemical composition and antimicrobial activity of the essential oils from four Ruta species growing in Algeria

Antimicrobial properties of plants essential oils have been investigated in order to suggest them as potential tools to overcome the microbial drug resistance and the increasing incidence of food borne diseases problems. The aim of this research is to study the antibacterial and antifungal effects of four traditional plants essential oils, Ruta angustifolia, Ruta chalepensis, Ruta graveolens and Ruta tuberculata, against standard bacterial and fungal strains. The chemical compounds of the oils were examined by GC/MS. Results revealed a powerful antifungal activity against filamentous fungi. Aspergillus fumigatus and Cladosporium herbarum are the most sensitive strains to these oils with MIC values less than 3.5 μg ml⁻¹ for certain oils, reaching 7.8 μg ml⁻¹ for other. GC/MS essay exhibited ketones as the most abundant constituent of these oils except for R. tuberculata essential oil which has a completely different composition, monoterpenes alcohols being the most abundant. These compositions explain their potential antifungal activity.     

Aflatoxins: Occurrence in red chilli and control by gamma irradiation

Chilli is one of the valuable spices commercialised globally, added as condiments in various cuisines and is easily susceptible to aflatoxin contamination (produced mainly by Aspergillus flavus) during pre- and post-harvesting stages. The important factors such as temperature, moisture content and humidity affect the growth of fungi producing aflatoxins. Chillies contaminated with aflatoxins could be carcinogenic and thus can pose a threat to the general population leading to the loss of international trade market. Therefore, to overcome this problem, there is a need for some effective and novel technologies such as gamma irradiation. Gamma irradiation minimises the toxicological effects of aflatoxins by inhibiting the growth as well as the proliferation of Aspergillus species. In this work, the natural occurrence of aflatoxins including the contribution of gamma irradiation on either eliminating or controlling the aflatoxins in red chilli is reviewed.     

Superadditive effects of multiple lesions in a connectionist architecture: Implications for the neuropsychology of optic aphasia.

Neuropsychological disorders have traditionally been understood in terms of a focal lesion to a single component of a cognitive architecture. Optic aphasia (OA) defies explanation in this way. In OA, naming of visual stimuli is impaired in the absence of general visual agnosia or anomia. OA has been explained by positing multiple semantic systems or multiple functional pathways to visual naming. M. J. Farah (1990) instead sketched a parsimonious account based on multiple lesions—to pathways mapping visual input to semantics and semantics to naming responses—and the assumption that the effects of the lesions are superadditive. The authors demonstrate superadditive effects of damage in a connectionist architecture and model other phenomena associated with OA. Multiple lesions with superadditivity provide a novel class of explanations for neuropsychological deficits that previously seemed to imply the existence of highly specialized processing components. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Iminosugar‐Based Galactoside Mimics as Inhibitors of Galactocerebrosidase: SAR Studies and Comparison with Other Lysosomal Galactosidases

Several families of iminosugar‐based galactoside mimics were designed, synthesized, and evaluated as galactocerebrosidase (GALC) inhibitors. They were also tested as inhibitors of lysosomal β‐ and α‐galactosidases in order to find new potent and selective pharmacological chaperones for treatment of the lysosomal storage disorder, Krabbe disease. Whereas 1‐C‐alkyl imino‐L ‐arabinitols are totally inactive toward the three enzymes, 1‐C‐alkyl imino‐D ‐galactitols were found to be active only toward α‐galactosidase A. Finally, 1‐N‐iminosugars provided the best results, as 4‐epi‐isofagomine was found to be a good inhibitor of both lysosomal β‐galactosidase and GALC. Further elaboration of this structure is required to achieve selectivity between these two galactosidases.     

Grid-Tied PV-BES system based on modified bat algorithm-FLC MPPT technique under uniform conditions

Neural Computing and Applications - Grid-connected photovoltaic (PV) systems play an important role in reducing emissions resulting from conventional fossil-fuel-based power plants. However, in...     

The Fatty Acid Profile and Phenolic Composition of Descurainia sophia Seeds Extracted by Supercritical CO2

Oil and phenolics were extracted from Descurainia sophia (Sophia) seeds by a supercritical CO₂ system. Extractions were conducted in two sequential steps, first using 100 % CO₂ and then adding 10 % ethanol as co‐solvent. The extracts were collected in each step using two separate collectors operating at different pressures. The extraction run was 3 and 4 h for the first period, and 2 h for the second period. The majority of the oil was collected in the first extraction period while phenolic compounds were obtained in the second extraction period. A combined mode of static/dynamic extraction (3 h running and 1 h soaking in CO₂) was also used in the first extraction period, which enhanced the total extraction yield (29.3 ± 0.5 %) and was comparable to the 4 h extraction yield (31.4 ± 0.1 %). The total fatty acid (FA) content of oil in collector 1 (0.94 g) was nearly twice that in collector 2 (0.60 g). The oil contained 14 FAs with α‐linolenic being predominant (48.5 %), with a total 91.1 % unsaturated FAs, a ω3/ω6 ratio of 2.7, and an erucic acid content of 6.2 %. More than 10 phenolic compounds were detected by HPLC in the Sophia seed extracts of which sinapic acid was the dominant compound. Sophia seed extracts showed high levels of antioxidant activity. These results suggest that Sophia seed oil and phenolics have the potential for functional food and pharmaceutical applications.