A growth mark method for studying growth mechanism of carbon nanotube arrays

A novel and simple growth mark method was developed to make marks during the growth process of carbon nanotube arrays. These marks can be read out under scanning electron microscope or optical microscope. Based on this method, the growth rates at different temperatures and under different acetylene partial pressures were measured, from which the activation energy and the order of reaction were determined. Based on our experimental results, the growth of carbon nanotube arrays in our experimental condition could not be diffusion-limited. The measured activation energy could possibly be attributed to the heterogeneous decomposition of acetylene over the catalyst particle. Furthermore the marked array with special segmental structure may be found some applications in the future.     

The kinetics of B‐a and P‐a type copolybenzoxazine via the ring opening process

The structure of benzoxazines is similar to that of phenolic resin through thermal self‐curing of the heterocyclic ring opening reaction that neither requires catalyst nor releases any condensation byproduct. These polybenzoxazine resins have several outstanding properties such as high thermal stability and high glass transition temperature. To better understand the curing kinetics of this copolybenzoxazine thermosetting resin, dynamic and isothermal differential scanning calorimetry measurements were performed. Three models, the Kissinger method, the Flynn–Wall–Osawa method, and the Kamal method, were used to describe the curing process. Dynamic kinetic activation energies based on Kissinger and Flynn–Wall–Osawa methods are 72.11 and 84.06 KJ/mol, respectively. The Kamal method based on an autocatalytic model results in a total order of reaction between 2.66 and 3.03, depending on curing temperature. Its activation energy and Arrhenius preexponential are 50.3 KJ/mol and 7959, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 730–737, 2005     

金纳米线拉伸行为的分子动力学模拟

采用分子动力学方法模拟了不同截面尺寸金纳米线的拉伸力学行为。计算结果表明:相同长度的金纳米线弹性模量随着截面尺寸的减小而减小,而其屈服强度随着截面尺寸的减小而增大,并且发生屈服推迟现象。应力—应变曲线与形变过程相对应。在弹性变形阶段,纳米线形变不显著;随着应变量的增加,发现纳米线出现大量堆垛层错。     

Analysis of junction temperatures in high-power GaN-based LEDs

We presented the analysis of the incomplete conduction in bonding medium in high power GaN-based light-emitting diode (LED) packages. A numerical study was carried out with parametric model to understand the junction temperature variation due to bonding medium defects. Transient thermal measurement was performed to evaluate LED’s junction temperature. Thermal resistance from chip to lead frame was 20 K/W in our sample LED. It was suggested that only 60% of the surface area of the bonding medium was involved...     

Mathematical model of deoxidization with post stirring in a combined blowing converter

Dissolved oxygen in the steel at the terminal of the converter smelting process is the main cause for the formation of oxide inclusions, and the high terminal oxygen content worsens the steel cleanness. However, post stirring in a combined blowing converter can promote the carbon-oxygen reaction in the liquid steel and reduce the dissolved oxygen content at the terminal of the converter smelting process. Thus, the mathematical model of deoxidization in the post stirring process was obtained, and the rationa...     

混合交通下右转机动车信号配时方法

为了减少右转机动车与直行自行车之间的干扰,提高交叉口的运行效率,本文分析了两相位信号控制交叉口右转机动车与自行车之间的冲突规律以及自行车交通流的行驶特性,确定设置右转机动车信号的直行自行车流量临界值.以减少冲突和提高交叉口运行效率为目标,确定右转机动车相位绿灯起亮时刻和绿灯时长,并建立了相应的参数标定模型.以实际调查数据为基础,应用VISSIM模拟软件进行模拟验证,结果表明,设置右转机动车信号后,右转机动车延误和机非冲突明显减少.     

脂肪醇生物活性和理化性质的QSAR/QSPR研究

为了研究脂肪醇结构-性质(活性)的定量关系,用相对键长取代拓扑距离,结合距离矩阵,提出了距离调和拓扑指数Te,Te和醇的许多理化性质和生物活性具有良好的相关性.用Te及δ(醇中和羟基相连的碳原子的支化度)与脂肪醇的溶解度、辛醇/水分配系数、急性生物毒性、蒸发热、摩尔磁化率关联,复相关系数分别为0.9955,0.9951,0.9941,0.9964,0.9968,优于文献.同时与脂肪醇的气相色谱保留指数也相关得很好,相关系数为0.9956.结果表明,Te指数可用于醇多种理化性质和生物活性的预测.     

稳定路径的Ad hoc网络QoS路由算法

移动Ad hoc网络中节点移动或能量耗尽会使得建立的QoS路径断裂而需重构路由,造成通信中断,对实时业务造成严重影响,提出了一种基于路径稳定性的QoS路由算法.该算法采用网络探测技术,综合考虑链路和节点稳定性,选择一条最稳定的路径进行通信,并实时监测路径状态变化,有效降低通信中断的概率.仿真表明,该算法有效改善了分组传送成功率、时延抖动等网络性能.     

确定土壤背景值的Hazen概率法——以铜陵矿区Pb为例

本文选取已知土壤背景含量的铜陵矿区,基于Hazen概率曲线,探讨了土壤污染重金属元素Pb背景含量与污染叠加含量的区分方法.得到Pb元素的背景含量为28.5μg/g,与该区深层土壤样中Pb元素含量的平均值(34μg/g)比较接近.还得到了Pb元素污染叠加含量与背景含量的界线点51μg/g.基于Hazen概率曲线区分铜陵矿区土壤Pb元素背景含量与污染叠加含量的方法是有效的,有必要将该方法推广到土壤中其它重金属污染元素、其它地区作进一步研究.     

AHP综合排序算法分析及其改进

层次分析法(AHP)是分析多目标评价、多指标决策问题时的一种常用的算法工具,但是传统AHP在进行综合排序时,却存在一定的算法缺陷,AHP不能保持各方案之间的独立性,导致当某些方案的指标值或者备选方案数量发生变化时,即使在同一评价标准下,AHP法也不能始终保证方案的排序的一致.针对这一问题,分析了AHP产生排序不一致的具体原因,指出其算法会导致最底层相对重要值会随着方案的数量的增加逐渐减少.提出用各方案与理想方案之间的相对效用指标代替传统AHP的综合排序指标,以使其能够始终保持各方案排序的一致性.给出的算例验证新方法的有效性.