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61.
对国内引进的、用于粉末冶金的步进梁式炉的运动,以图解法和解析法进行了分析,并对运动参数进行了理论推导和计算。本研究结果,对解决步进粱式炉的运动故障以及进行新型设计提供了有效的理论分析和计算依据。 相似文献
62.
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64.
N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠的合成及性能研究 总被引:1,自引:1,他引:0
用 N,N′-二羟乙基乙二胺、氯乙酸钠合成了 N,N′-二羟乙基乙二胺二乙酸钠(中间体),中间体再与硬脂酰氯反应制备了一种新型 Gemini 两性表面活性剂 N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠。对产物合成条件进行了考察,优化的反应条件为:n(硬脂酰氯):n(中间体)=2.5,溶剂 V(水):V(氯仿)=1:2,pH=9.0~10.0,反应温度15~20℃,反应时间5 h。通过红外光谱和质谱分析确定了产物结构,并测试了产物的表面性能。结果表明,在25℃时,该产物的临界胶束浓度为0.24 mmol/L,临界胶束浓度下的表面张力为35.7 mN/m;即时泡沫高度为250 mm,5 min 后泡沫高度为220 mm;乳化时间为22.48 min(甲苯-水物系)和4.65 min(正己烷-水物系),亲水-亲油平衡值为5.4,等电点为 pH 3.3~6.5。 相似文献
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66.
中式快餐发展战略与人才培养 总被引:2,自引:0,他引:2
本文讨论了我国快餐业的发展现状,进一步研究中式快餐发展战略,以及中式快餐业有关人才的培养现状和满足发展各类人才培养途径。 相似文献
67.
Organic‐acid‐catalyzed sol–gel route for preparing poly(methyl methacrylate)–silica hybrid materials
Jui‐Ming Yeh Kuan‐Yeh Huang Chung‐Feng Dai B. G. Chand Chang‐Jian Weng 《应用聚合物科学杂志》2008,110(4):2108-2114
In this study, a series of organic–inorganic hybrid sol–gel materials consisting of a poly(methyl methacrylate) (PMMA) matrix and dispersed silica (SiO2) particles were successfully prepared through an organic‐acid‐catalyzed sol–gel route with N‐methyl‐2‐pyrrolidone as the mixing solvent. The as‐synthesized PMMA–SiO2 nanocomposites were subsequently characterized with Fourier transform infrared spectroscopy and transmission electron microscopy. The solid phase of organic camphor sulfonic acid was employed to catalyze the hydrolysis and condensation (i.e., sol–gel reactions) of tetraethyl orthosilicate in the PMMA matrix. The formation of the hybrid membranes was beneficial for the physical properties at low SiO2 loadings, especially for enhanced mechanical strength and gas barrier properties, in comparison with the neat PMMA. The effects of material composition on the thermal stability, thermal conductivity, mechanical strength, molecular permeability, optical clarity, and surface morphology of the as‐prepared hybrid PMMA–SiO2 nanocomposites in the form of membranes were investigated with thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, gas permeability analysis, ultraviolet–visible transmission spectroscopy, and atomic force microscopy, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
68.
Sodium sulfonate‐terminated dendritic poly(ester‐amine) (SPEA) was synthesized by sulfonation of acrylic double bond‐terminated dendritic poly(ester‐amine) (APEA) with sodium hydrogen sulfite (NaHSO3) in mixture of diglycol and 2‐butanone under normal pressure. The structure of SPEA was characterized by IR, 1H‐NMR, and elemental analysis. SPEA was water‐soluble. 1.0–40.0% (mass) SPEA aqueous solutions appeared as dilatant fluid. When pH value varied from 1.5 to 12.0, the viscosity of 1–5% (mass) SPEA aqueous solutions changed very small, and the electric conductivity almost kept stable within pH 3.0–10.0. The relationship between the viscosity and the concentration of SPEA water solutions was similar to that of NaCl water solutions. The surface tension of SPEA water solutions was lower than that of polyethylene glycol 2000 water solutions with the same concentration. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
69.
A novel fully conjugated polymer containing 1,10‐phenanthroline (DAPcDOD) was first synthesized by the polycondensation of 2,7‐dimethyl‐2,4,6‐octatriene‐1,8‐dial with 5,6‐diamine‐1,10‐phenanthroline. Three polymeric complexes were first prepared by the reaction of DAPcDOD with NiSO4, CoCl2, and FeSO4, respectively. The structures of the polymer and the complexes were characterized by IR, 1H‐NMR, and elemental analysis. The magnetic behaviors of these complexes were measured as a function of magnetic field strength (0–50 kOe) at 5 K and as a function of temperature (5–300 K) at a magnetic field strength of 30 kOe. The results show that DAPcDOD–Ni2+ and DAPcDOD–Co2+ were soft ferromagnets, whereas DAPcDOD–Fe2+ exhibited the features of an antiferromagnet. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
70.
Degumming of hemp fiber by high temperature alkali cooking was investigated, and the effect of temperature and dosage of alkali on the constituents, structure, and thermal degradation of hemp fiber was also discussed in this work. The morphology, structure, and thermal degradation of hemp fiber after high temperature cooking were investigated through SEM, FTIR, WAXD, and TG analysis. The results indicated that the high temperature cooking process was effective for removing hemicelluloses and lignin and could also improve the thermal stability of cellulose. Crystallinity index of the treated hemp fiber was increased, which was related to the cooking temperature and NaOH dosage. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献