A TIME-DISCRETE APPROACH TO THE MODELLING OF GRINDING MILL MIXING PROPERTIES

When a grinding mill is not operated in open circuit, residence time distributions (RTD) cannot be directly deduced from tracer concentration measurements at the mill discharge using a conventional tracer impulse experiment. Two methods are proposed for RTD determination from an arbitrary set of input and output tracer concentration/time measurements. The first one provides directly the discretized RTD by a direct deconvolution approach. The second one assumes that the RTD is the impulse response of an autoregressive-moving average model (ARMA). The use of each method is demonstrated using industrial data and a comparison to alternative methods is given.     

Evaluation of quantitative procedures for X-ray microanalysis of environmental particles

Scanning electron microscopy combined with energy-dispersive X-ray spectrometry is particularly suited to characterizing morphology and elemental composition of individual microparticles. Although not straightforward, quantitative X-ray microanalysis of low-Z-containing particles is achievable using atmospheric thin-window X-ray detectors. A critical aspect of light element analysis is the choice of substrate material. In this work, particles were deposited on specially developed boron substrates. Three case studies were investigated successively in the order of increasing difficulty. Firstly, hundreds of calcium carbonate (CaCO(3)) particles ranging in size from 0.3 to 10 microm were analyzed. Three quantitative procedures were tested: the "k-ratio" method, conventional ZAF correction, and Monte Carlo simulations. Average relative errors obtained by the reverse Monte Carlo quantitative program named CASINO were better than 2.5 wt %, carbon included. Secondly, further evaluation was carried out on a finely crushed biotite mineral, containing more than nine elements. Finally, airborne particulate matter, consisting of a complex heterogeneous mixture of particles, was investigated. By applying the Monte Carlo quantitative procedure, the observed particles were easily classified into particle types. Pure compounds (e.g., CaSO(4).2H(2)O, SiO(2), CaCO(3), etc) were directly assigned according to stoichiometry. In some cases (marine-derived particles), a partial reactivity of atmospheric particles was demonstrated by quantitative analysis.     

European isotopic signatures for lead in atmospheric aerosols: a source apportionment based upon 206Pb/207Pb ratios

To investigate the capability of the lead isotope signature technique to support a source apportionment study at a Continental scale, atmospheric particulate matter was collected at Cap Gris-Nez (Eastern Channel, northern France), over one year (1995-1996). Four days retrospective trajectories of air masses were available during each sampling experiment. Twenty-eight samples, for which the origin of aerosols was unambiguously determined, were selected for isotopic measurements. Considering the Enrichment Factors, EF(Crust) of lead and its size distribution, we show that lead is mostly from anthropogenic origin and mainly associated with [0.4 < diameter < 0.9 microm] particles. The extent to which various Continental sources influence the lead abundance in aerosols is exhibited by considering both the lead concentration and the origin of air masses. Lead concentration is higher by a factor of approximately seven, when air masses are derived from Continental Europe, by comparison with marine air masses. Taking into account these concentrations and the vertical movements of air masses, we compare the different isotopic compositions using a statistical non-parametric test (Kolmogorov-Smirnov). We produce evidence that, for most of the cases, air masses originating from Continental Europe exhibit a more radiogenic composition (1.134 < 206Pb/207Pb < 1.172) than air masses coming from the United Kingdom (1.106 < 206Pb/207Pb < 1.124). Generally, lead isotopic compositions in aerosols are clearly distinct from the gasoline signatures in European countries, strongly suggesting that automotive lead is no longer the major component of this metal in the air. Gasoline and industrial isotopic signatures could explain the origin of lead in our aerosol samples. A source apportionment based upon 206Pb/207Pb ratios, suggests that the difference between British (206Pb/207Pb = 1.122 +/- 0.038) and Continental (206Pb/207Pb = 1.155 +/- 0.022) signatures may be largely explained by differences in the petrol lead content of aerosols (23-62% in Great Britain vs. 10-36% in Continental Europe).     

Assessment of pollution aerosols sources above the Straits of Dover using lead isotope geochemistry.

We assess the capability of lead isotopes to study the transport of pollution aerosols above the Straits of Dover by collecting atmospheric aerosols above the Eastern Channel and the Southern Bight of the North Sea. During the same period, we characterized the lead isotopic signature of the main industrial sources on the French coast near the Straits of Dover. Urban and automobile-derived aerosols were also collected. Due to the phasing out of lead in gasoline, the urban isotopic composition (206Pb/207Pb = 1.158 +/- 0.003) has become more radiogenic, although it is highly variable. On a regional scale, major industrial emissions have a well-defined isotopic composition (1.13 < 206Pb/207Pb < 1.22), more radiogenic than the petrol-lead signature (1.06 < 206Pb/207Pb < 1.12). These results together with those measured near the main coastal highway show that the automobile source has become a minor component of particulate lead in air. On a local scale, Dunkerque, the most urbanized and industrialized area along the Straits of Dover, may transiently control elevated lead concentrations. Except for the occurrence of local and regional range transport episodes, lead concentrations in the Straits of Dover can be related to remote or semi-remote pollution source emissions. Combining air mass retrospective trajectories and related lead abundances and isotopic compositions, it can be shown that lead aerosols originating from eastern Europe have an isotopic signature (1.145 < 206Pb/207Pb < 1.169) different from the isotopic composition of west-European lead aerosols (1.111 < 206Pb/207Pb < 1.142). The influence of remote North American sources is suggested, with caution, due to uncertainties in meteorological calculations.     

Current measurements by SAR along-track interferometry from a Space Shuttle

We present one of the first studies on ocean current retrievals from interferometric synthetic aperture radar (InSAR) data acquired during the Shuttle Radar Topography Mission (SRTM) in February 2000. The InSAR system of SRTM was designed for high-resolution topographic mapping of the Earth's land surfaces, using two SAR antennas on a Space Shuttle with a cross-track separation of 60 m. An additional along-track antenna separation of 7 m resulted in an effective time lag of about 0.5 ms between the two images, which could theoretically be exploited for target velocity retrievals. However, the feasibility of ocean current measurements with SRTM has been questionable, since the time lag was much shorter than the theoretical optimum (about 3 ms at X-band) and the signal-to-noise ratio over water was quite low. Nevertheless, some X-band InSAR images of coastal areas exhibit clear signatures of tidal flow patterns. As an example, we discuss an image of the Dutch Wadden Sea. We convert the InSAR data into a line-of-sight current field, which is then compared with results of the numerical circulation model KUSTWAD. For tidal phases close to the conditions at the time of the SRTM overpass; we obtain correlation coefficients of up to 0.6 and rms differences on the order of 0.2 m/s. Furthermore we find that SRTM resolves current variations down to spatial scales on the order of 1 km. This is consistent with predictions of a numerical InSAR imaging model. Remaining differences between SRTM- and KUSTWAD-derived currents can be attributed mainly to residual motion errors in the SRTM data as well as to a limited representation of the conditions at the time of the SRTM overpass in the available KUSTWAD results.     

An All-Digital RF Signal Generator Using High-Speed $DeltaSigma$ Modulators

An all-digital RF signal generator using DeltaSigma modulation and targeted at transmitters for mobile communication terminals has been implemented in 90 nm CMOS. Techniques such as redundant logic and non-exact quantization allow operation at up to 4 GHz sample rate, providing a 50 MHz bandwidth at a 1 GHz center frequency. The peak output power into a 100 Omega diff. load is 3.1 dBm with 53.6 dB SNDR. By adjusting the sample rate, carriers from 50 MHz to 1 GHz can be synthesized. RF signals up to 3 GHz can be synthesized when using the first image band. As an example, UMTS standard can be addressed by using a 2.6 GHz clock frequency. The measured ACPR is then 44 dB for a 5 MHz WCDMA channel at 1.95 GHz with output power of -16 dBm and 3.4% EVM. At 4 GHz clock frequency the total power consumption is 120 mW (49 mW for DeltaSigma modulator core) on a 1 V supply voltage, total die area is 3.2 mm² (0.15 mm² for the active area).     

Quantitative determination of low-Z elements in single atmospheric particles on boron substrates by automated scanning electron microscopy-energy-dispersive X-ray spectrometry

Atmospheric aerosols consist of a complex heterogeneous mixture of particles. Single-particle analysis techniques are known to provide unique information on the size-resolved chemical composition of aerosols. A scanning electron microscope (SEM) combined with a thin-window energy-dispersive X-ray (EDX) detector enables the morphological and elemental analysis of single particles down to 0.1 microm with a detection limit of 1-10 wt %, low-Z elements included. To obtain data statistically representative of the air masses sampled, a computer-controlled procedure can be implemented in order to run hundreds of single-particle analyses (typically 1000-2000) automatically in a relatively short period of time (generally 4-8 h, depending on the setup and on the particle loading). However, automated particle analysis by SEM-EDX raises two practical challenges: the accuracy of the particle recognition and the reliability of the quantitative analysis, especially for micrometer-sized particles with low atomic number contents. Since low-Z analysis is hampered by the use of traditional polycarbonate membranes, an alternate choice of substrate is a prerequisite. In this work, boron is being studied as a promising material for particle microanalysis. As EDX is generally said to probe a volume of approximately 1 microm3, geometry effects arise from the finite size of microparticles. These particle geometry effects must be corrected by means of a robust concentration calculation procedure. Conventional quantitative methods developed for bulk samples generate elemental concentrations considerably in error when applied to microparticles. A new methodology for particle microanalysis, combining the use of boron as the substrate material and a reverse Monte Carlo quantitative program, was tested on standard particles ranging from 0.25 to 10 microm. We demonstrate that the quantitative determination of low-Z elements in microparticles is achievable and that highly accurate results can be obtained using the automatic data processing described here compared to conventional methods.     

Development of 400 microm pellets by extrusion-spheronization: application with Gelucire 50/02 to produce a "sprinkle" form

The aim of this study was to develop monodimensional, spherical particles of 400 µm by extrusion-spheronization. An Alexanderwerk GA65 cylinder extruder with two counter-rotating rollers associated with a Caleva model 15 spheronizer were used. The study was made with an auxiliary substance of fatty consistency and with amphiphilic properties: Gelucire 50/02. The plasticity of the mass can be deduced using a piston extruder. Pellet quality can be determined by particle-size analysis and shape estimation by microscopy. Modifications to the cylinders and the extruder itself are required for feasibility studies of extruded materials of 400 µm. The horizontal plate of the spheronizer had to be adapted to take into account the small size of the extruded materials. For the chosen auxiliary substance, Gelucire 50/02, the formulation of the wet mass to be extruded and the conditions required to obtain this mass were defined. The results show the feasibility of 400 µm pellets with Gelucire 50/02. At least 90% of the pellets have a particle size of between 250 µm and 500 µm and particle shape is acceptable. In this form the dose can be adapted to individual patients. After proving the feasibility of 400 µm spheroids of Gelucire 50/02, the association of a drug with it was considered.