热分析在PVA纤维预处理中的应用

用差热、热重法对原丝的热性能及由不同预处理方法所引起的PVA纤维的热行为变化进行了研究;并通过模拟脱水条件,用不同升温速率,求出了经不同预处理纤维的脱水反应活化能。结果表明,PVA原丝在230℃有一软化点,三种预处理都不同程度地影响了原丝的热效应变化;纤维在180～340℃主要为脱水反应;原丝及经脱水剂、O_3和O_3综合脱水剂处理的纤维,其脱水反应的表观活化能分别为:164.3kJ/mol,92.9kJ/mol,130.5kJ/mol和117.6kJ/mol。     

房地产中介服务业存在的问题和改进建议

本文就房地产中介服务业在政府机构管理、行业经营方面存在的问题进行了总结,同时提出一些改进建议,对于房地产中介服务业规范经营、健康发展具有很好的指导意义。     

BKX-Ⅰ型并联机床的谐响应分析

应用有限元分析软件(ANSYS),对BKXⅠ型并联机床进行谐响应分析,分别得到了机床各节点沿机床的虚拟轴X、Y和Z向的位移谐响应曲线。在此基础上,还分析了该机床的谐响应规律,并明确了谐响应的特点,为改善此类机床的动态特性提供了一定的参考依据。     

Comparative study of the elimination of toluene vapours in twin biotrickling filters using two microorganisms Bacillus cereus S1 and S2

BACKGROUND: To investigate the microbial degradation performance of organic pollutants in the atmosphere using a biotrickling filter, two microorganism strains, Bacillus cereus S1 and Bacillus cereus S2, were selected, identified and inoculated into a twin biotrickling filter for comparison. RESULTS: Both strains showed good performance towards the degradation of model organic pollutants when gas flow rates ranged from 100 to 600 L h⁻¹. For S1, the total maximum removal efficiency (RE) of toluene was maintained nearly 100% not only at gas flow rates of 100 L h⁻¹ corresponding to empty bed residence time (EBRT) 199.44 s, but also at gas flow rates of 200 L h⁻¹ (EBRT = 99.72 s) and 300 L h⁻¹ (EBRT = 66.48 s). However, S2 had a much lower degradation capability; near 100% removal efficiency was obtained only at the gas flow rate of 100 L h⁻¹ although both bacteria belong to the same Bacillus cereus. With further increase in gas flow rate, the total REs for both S1 and S2 decreased slightly at first and then dropped sharply to 46% and 35%, respectively, at an EBRT of 33.24 s, corresponding to a gas flow rate of 600 L h⁻¹. Starvation for between 2 and 10 days resulted in the re‐acclimation times of both strains ranging between 1.0 and 15.5 h. CONCLUSION: Strain S1 would be a better choice for inoculation into a biotrickling filter than strain S2, because of its much higher toluene removal capacity and rapid recovery to full performance. Copyright © 2008 Society of Chemical Industry     

正交实验优选盐生藻多糖的提取工艺

以盐生藻为原料,盐生藻多糖得率为指标,运用稀酸、稀碱和蒸馏水为提取剂提取盐生藻多糖,得出合适的提取剂为稀酸.进一步的正交实验表明,盐生藻多糖的最适提取工艺为:提取75min,pH=4,固液比为1∶70,温度为95℃.     

Restraining the associations of anthracene fluorophore by chemically linking to poly(methyl methacrylate)

Associations (dimer or aggregate) of anthracene (An) fluorophores tend to interrupt the monomer emission and reduce the quantum yield (Φ_PL); therefore, poly(methyl methacrylate) (PMMA) chain was used in this study to chemically link to anthracene and to block the mutual associations among the anthracene fluorophores. With this aim, the target polymers were prepared by anionic polymerizations with 9,10‐dibromoanthracene/s‐butyllithium as initiating system to proceed polymerizations of methyl methacrylate (MMA) directly or in the presence of 1,1‐diphenylethylene (DPE). Use of DPE before addition of MMA produces stable initiating anionic species and avoids potential side reactions during polymerization; however, it also introduces four β‐phenylene rings around the central anthracene ring, which interfere with the corresponding emission pattern and reduce the Φ_PL (32%) value due to potential interactions between phenylene rings and anthracene. On the contrast, polymerization without participation of DPE results in polymer with central anthracene ring directly connected to two PMMA chains, which gives clean vibronic emission pattern with limited association emissions and enhanced Φ_PL (52%) value. Physical blending of anthracene by PMMA is less efficient to restrain the associations and results in a film of lower Φ_PL (20%). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

《建设工程施工合同》中有关造价控制条款的阐析

仅从造价控制的角度分析、归纳施工合同中涉及费用的条款，以便更好地应用。     

长庆油田陕北区原油破乳剂的筛选和复配

实验考察了8种市售水溶性破乳荆对长庆油田陕北区有代表性的宝塔区、安塞和子长原油(均为低硫中间基-石蜡基原油)的脱水效果(加量100mg／L，脱水温度55℃，时间3h)。目前长庆采油一厂使用的YT-100和延炼集团使用的GT-940对这3种原油的脱水效果均较好，但对子长原油的脱水率不高，分别为69．7％和58．9％。在由所选性能较好的破乳刺组成的4种二元复配物中，GT-940 HQ96-1对3种原油的脱水效果均高于单剂，最佳配比分别为4：1，4：1，3：2；其余3种复配物则对原油有选择性，其中GT-940 YT-100相近(97．5％)；YT-100 HQ96-1仅能改善子长原油的脱水效果，配比为4：1时脱水率最高(76．4％)；SP-169 HQ96-1仅能改善宝塔区原油的脱水效果．配比3：2和2：3时脱水率最高(92．9％)。表5参6。     

CB-60/CB-70还原态重整催化剂的应用

介绍了福建炼油化工有限公司重整装置CB -60 /CB -70重整催化剂 (还原态 )分段组合装填的应用情况 ,列出了还原态催化剂和氧化态催化剂开工的不同特点。通过开工初期标定的数据与CB -6/CB -7催化剂的对比 ,说明CB -60 /CB -70催化剂有良好的活性和选择性 ,尤其是选择性、产氢率优于CB -6/CB -7,且使开工步骤得到了简化