Effect of Preparation Methods and Condition of Precursors on the Phase Composition of Yttria-Stabilized Zirconia Powders

An yttria-stabilized zirconia powder, free of monoclinic phase, may be prepared by an oxalate method in an ethanol solution at strong acidity. This study demonstrates that the control of pH in the preparation of precursors has a significant effect on the ability of precursors to crystallize and hence plays an important role in determining the formation and fraction of various crystalline phases in the resulting yttria-stabilized zirconia powder. With the increase of pH, a precursor with a certain crystalline form may be transformed into an amorphous precursor, and a monoclinic phase appers in the phase composition of the resulting powder. The results of XRD analysis and Raman spectroscopy are discussed.     

Probabilistic analysis of uncertainties in seismic hazard assessment

Sources and current methods of analysis of uncertainty from randomness, fuzziness and ignorance or incomplete knowledge in seismic hazard assessment problem are briefly discussed at beginning; understandings of the authors are then presented in the following order. All three types of uncertainty come from incomplete knowledge. Probabilistic method can be applied to all of them, objective probability for random factors and subjective probability for the other two types of uncertain factors. Discrete subjective probability mass functions for incomplete and fuzzy factors can be obtained from logic-tree and membership functions respectively. Fractile curves may be used to show the scattering of any uncertainty factor, but a unified probabilistic treatment may be applied to any combination of all three types of uncertainty.     

Effect of precyclic loading on stress-corrosion-cracking initiation in an X-65 pipeline steel exposed to near-neutral pH soil environment

A study was carried out to understand the effect of precyclic loading on stress-corrosion-crack initiation in an X-65 pipeline steel exposed to a near-neutral-pH soil environment. The test specimens were precyclically loaded before corrosion exposure to represent a service history of up to about 20 years, depending on the severity of pressure fluctuation. Microcracks had initiated on the polished surface of the X-65 pipeline steel after long-time exposure at open-circuit potential (OCP) in a near-neutral-pH synthetic soil solution. These microcracks were mostly initiated from pits at metallurgical discontinuities such as grain boundaries, pearlitic colonies, and banded phases in the steel. Strong preferential dissolution was observed along planes of the banded structures in the steel. The selective corrosion attack at these metallurgical discontinuities is attributed to the galvanic nature of those areas to their neighbors. Cyclic loading prior to corrosion exposure had significant effects on microcrack initiation and propagation during subsequent corrosion exposure. Cyclic loading prior to corrosion exposure either reduced or increased the probability of crack initiation and the rate of crack propagation, depending upon the magnitude of the stress cycles. The largest reduction was seen at a peak cyclic stress of about 0.8 of the yield strength. This cyclic-loading-dependent cracking behavior might be related to the alteration of the substructures and the residual stress in the steel as a result of precyclic loading.     

磁场对水的表面张力影响的实验研究

水经磁场处理后,某些物理化学性质会发生变化。由于水对环境条件的影响极为敏感,准确地实验测定这些变化碰到了不少难以克服的困难。因此,文献上所报道的数据一致性较差。本工作采用比较法,对二次蒸馏水经过不同磁场强度处理后,其表面张力的变化进行了初步的实验研究和讨论。     

松辽南部早白垩世断陷期沉积相与成岩相

松辽南部早白垩世断陷期地层地震相分析显示,该时期冲积扇、三角洲、水下扇及扇三角洲沉积体系十分发育,是深部油(气)聚集的有利场所。登娄库组可分出:浅埋弱压实成岩相、晚表生溶蚀成岩相、深埋溶蚀成岩相、深埋压溶成岩相,以前二者为油气聚集的有利成岩相。     

用程序升温脱附研究Nd_（1－x）Sr_xMnO_3体系氧的吸附、脱附特性

用氧的程序升温脱附（ＴＰＤ）技术测试了钙钛矿型复合氧化物Ｎｄ（１－ｘ）ＳｒｘＭｎＯ３（ｘ＝０．０，０．２，０．４，０．６，０．８，１．０）系列试样体相内的缺陷结构．发现随着Ｘ的变化，脱附氧量呈现出不同的变化规律。对此，用晶体化学和固体化学的基本理论进行了解释。     

某地下室深井渗漏的治理

分析了上海兰心影剧院地下室深井修建后出现渗漏的原因，介绍了堵漏工程采用的防水材料和施工方法。     

Effects of the organometallic coupling agents on adhesion of the carbon fiber–BMI composites

In order to increase the chemical bonding force between fiber and resin, several kinds of organometallic coupling agent (such as titanate, zirconate, and zircoaluminate) were chosen and added in the BMI resin formulation, which possess the same solvent system with those coupling agents. The DSC analysis technique was used to find the best curing condition, and TGA was used to investigate the thermal stability property of the best curing condition. For the purpose of analyzing the bonding structure, ESCA surface element analysis techniques was applied in this study. Beside that, the mechanical properties of tensile, flexural, and short-beam shear strengths were measured for the effect of adding coupling agents, and the SEM of fracture surfaces were taken to study the fractural analysis. The results showed that composites with the application of organometallic coupling agents of [RO–Ti(OX–R′NH₂)₃] structure in the treatment of BMI resin were highly thermal stable. Also, it was shown that the mechanical strengths of composites fabricated by pretreatment of the carbon fibers with coupling agents were higher than those fabricated by adding coupling agents in resins, but there was no obvious improvement of mechanical properties with higher concentration of coupling agents. However, the SEM showed that the adhesion between fiber and resin can actually be improved by adding proper amount of coupling agents in the BMI resin formulation.     

降低精炼钢中氢氧含量的探索

主要介绍通过优化炼钢生产工艺,使产品满足新的技术要求:S≤0.010％,P≤0.015％.[H]≤0.0002％,[O]≤0.0045％,[N]≤0.0055％。     

Effective improvement of high-k Hf-silicate/silicon interface with thermal nitridation

The electrical properties of polysilicon gate MOS capacitors with hafnium silicate (HfSiO) dielectric, with and without NH/sub 3/ nitridation, were investigated. The results show that with NH/sub 3/ nitridation prior to deposition of HfSiO can effectively tune the flatband voltage close to that of conventional oxide and significantly improve the leakage properties over SiO/sub 2/ (three orders reduction). Furthermore, the excellent interface quality has been evidenced by the result of immunity against soft breakdown with NH/sub 3/ nitridation.