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111.
112.
Jia‐Wei Li Yu‐Jing Chiu Chia‐Jui Chang Hung‐Chieh He Yi‐Hsuan Tu Kuan‐Ting Lin Yu‐Liang Lin Tzu‐Hsun Kao Hsun‐Hao Hsu Hsiao‐Fan Tseng Tien‐Chang Lu Jiun‐Tai Chen 《大分子材料与工程》2020,305(1)
Polyimides (PIs) possess excellent mechanical properties, thermal stability, and chemical resistance and can be converted to carbon materials by thermal carbonization. The preparation of carbon nanomaterials by carbonizing PI‐based nanomaterials, however, has been less studied. In this work, the fabrication of PI nanofibers is investigated using electrospinning and their transformation to carbon nanofibers. Poly(amic acid) carboxylate salts (PAASs) solutions are first electrospun to form PAAS nanofibers. After the imidization and carbonization processes, PI and carbon nanofibers can then be obtained, respectively. The Raman spectra reveal that the carbon nanofibers are partially graphitized by the carbonization process. The diameters of the PI nanofibers are observed to be smaller than those of the PAAS nanofibers because of the formation of the more densely packed structures after the imidization processes; the diameters of the carbon nanofibers remain similar to those of the PI nanofibers after the carbonization process. The thermal dissipation behaviors of the PI and carbon nanofibers are also examined. The infrared images indicate that the transfer rates of thermal energy for the carbon nanofibers are higher than those for the PI nanofibers, due to the better thermal conductivity of carbon caused by the covalent sp2 bonding between carbon atoms. 相似文献
113.
Wind energy is currently one of the types of renewable energy with a large generation capacity. However, since the operation of wind power generation is challenging due to its intermittent characteristics, forecasting wind power generation efficiently is essential for economic operation. This paper proposes a new method of wind power and speed forecasting using a multi-layer feed-forward neural network (MFNN) to develop forecasting in time-scales that can vary from a few minutes to an hour. Inputs for the MFNN are modeled by fuzzy numbers because the measurement facilities provide maximum, average and minimum values. Then simultaneous perturbation stochastic approximation (SPSA) algorithm is employed to train the MFNN. Real wind power generation and wind speed data measured at a wind farm are used for simulation. Comparative studies between the proposed method and traditional methods are shown. 相似文献
114.
Blends of poly(ethylene terephthalate) (PET) and polypropylene (PP) at composition 80/20 with and without a compatibilizing
agent were studied. Both materials are widely used in the soft drink bottle industry. The compatibilizing agent was a maleic
anhydride grafted polyethylene-octene elastomer (POE-g-MA). The olefinic segment of POE is compatible with PP, whereas the maleic anhydride is affined with PET carbonyl groups.
The effectiveness of the compatibilizing agent was evaluated using different techniques, such as Fourier transform IR spectroscopy,
mechanical analysis, scanning electron microscopy, dynamic mechanical analysis, and rheological analysis. The results show
that the addition of POE-g-MA promotes a fine dispersed-phase morphology, and improves process ability and toughness of these blends. Shifts in the
glass-transition temperature of the PET phase and the increase in the melt viscosity of the compatibilized blends indicated
enhanced interactions between the discrete PET and PP phases induced by the functional compatibilizer. 相似文献
115.
Feng-Yi Chou Chao-Ming Shih Meng-Chao Tsai Wen-Yen Chiu Shingjiang Jessie Lue 《Polymer》2012,53(14):2839-2846
This paper reports a novel method to synthesize magnetic, stimuli-sensitive latex nanoparticles made with magnetite/poly(N-isopropylacrylamide-co-acrylic acid) (Fe3O4/P(NIPAAm-co-AAc)). To form a stabilized suspended core, iron oxide (Fe3O4) was functionalized with AAc such that further polymerization with NIPAAm and AAc monomers could occur. The P(NIPAAm-co-AAc) shell layer exhibited thermosensitive properties. The inclusion of Fe3O4 into the latex nanoparticles was confirmed using transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction spectroscopy, thermogravimetric analyzer (TGA), and superconducting quantum interference device magnetometer. The NIP–(AAc2.6–Fe) latex nanoparticles contained 2.25% Fe3O4 (by weight), as determined by TGA analysis. The particle diameters measured approximately 160–240 nm with a lower critical solution temperature of 35 °C. These novel magnetic stimuli-responsive latex nanoparticles have potential applications in numerous fields, such as catalyst supports, protein immobilization, cancer therapy, target drug delivery systems, and other biomedical applications. 相似文献
116.
In many hospitals, isolation rooms are used to contain patients who are highly infectious, and the spread of air and bacteria within the isolation room is closely relates to room air distribution. This article uses the computational fluid dynamics (CFD) method to investigate the effects of a moving person and the opening and closing of a sliding door on room air distribution, including velocity, pressure and contaminant fields. Dynamic meshes are employed to simulate the movement of the walking person and sliding door. According to numerical results, the impact of those moving objects on room air distribution is addressed in this study. 相似文献
117.
Chen T.-M. Chiu Y.-M. Wang C.-C. Chan K.-U. Lin Y.-H. Huang M.-C. Lu C.-H. Wang W.-S. Hu C.-S. Lee C.-C. Huang J.-Z. Chang B.-I. Yen S.-C. Lin Y.-Y. 《Solid-State Circuits, IEEE Journal of》2007,42(5):983-991
A low-power fullband 802.11a/b/g WLAN transceiver in 0.15-mum CMOS technology is described. The zero-IF transceiver achieves a receiver noise figure of 4.4/4 dB for the 2.4-GHz/5-GHz bands, respectively. The corresponding sensitivity at 54-Mb/s operation is -72 dBm for 802.11g and -74 dBm for 802.11a using actual PER measurement. An on-chip PA delivers 20 dBm output P1-dB. A new I/Q compensation scheme is implemented in local oscillator (LO) and an image rejection of better than 52 dB is observed. The transmitter delivers 10/1.5 dBm (2.4-/5-GHz) EVM-compliant output power for a 64-QAM OFDM signal at 54-Mb/s. The power consumption is 117/135 mW (1.8-V) in the receive mode and 570/233.1 mW in the transmit mode for 2.4/5 GHz, respectively. The low power consumption, high integration and robustness (-40 to 140degC) make this transceiver suitable for portable applications 相似文献
118.
Chen H. R. Hsu M. K. Chiu S. Y. Chen W. T. Chen G. H. Chang Y. C. Lour W. S. 《Electron Device Letters, IEEE》2006,27(12):948-950
Depositing gate metal across a step undercut between the Schottky barrier layer and the insulator-like layer is employed to obtain a reduced gate length of 0.4 mum with an additional 0.6-mum field plate from a 1-mum gate window. Most dc and ac characteristics including current density (IDSS=451mA/mm), transconductance (gm,max=225mS/mm), breakdown voltages (VBD(DS)/V BD(GD)=22/-25.5V), gate-voltage swing (GVS=2.24V), cutoff, and maximum oscillation frequencies (ft/fmax=17.2/32GHz) are improved as compared to those of a 1-mum gate device without field plate. At a VDS of 4.0 V, a maximum power added efficiency of 36% with an output power of 13.9 dBm and a power gain of 8.7 dB are obtained at a frequency of 1.8 GHz. The saturated output power and the linear power gain are 316 mW/mm and 13 dB, respectively 相似文献
119.
A polymer-organic host-guest emitter (POHGE) system for obtaining polymer light-emitting diodes (PLEDs) with pure red emission and high luminance is proposed. The POHGE system was prepared by the fluorescent dye 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetra-methyljulolidy-9-enyl)-4H-pyran (DCJTB) doped in green-emitting polymer poly (9,9-dioctylfluorene-alt-benzothiadiazole) (BTF8). A photoluminescence (PL) quenching phenomenon was observed owing to the higher doping amount of DCJTB dopant. In this study, the red DCJTB dopant emits with high luminance and without concentration quenching when the host BTF8 emitting layer is doped with a small amount of the red guest DCJTB dopant. An optimal amount of DCCJTB dopant was obtained at 2 mg. Devices with a configuration of indium tin oxide (ITO)/poly (ethylenedioxythiophene) doped with poly (styrenesulfonate) (PEDOT:PSS)/BTF8:DCJTB/Ca/Al were fabricated. This device achieved an electroluminescence (EL) efficiency of 1.33 cd/A at 6 V. The emission area is 1.5 × 0.5 cm2. The devices show the red light emission with a peak at about 630 nm. The color coordinate in Commission Internationale d’Eclairage (CIE) chromaticity is at x = 0.64 and y = 0.36. 相似文献
120.