火灾自动报警与PLC自动控制相结合在油库消防系统中的应用

为了加强对油库消防监控,更好地保护油库的消防安全,宁波镇海国家储备油库的消防监控系统尝试了火灾自动报警与PLC自动控制相结合的监控模式,并取得了良好效果,使系统监控的智能化程度大为提高,其报警及灭火控制功能更为先进。文章主要阐述了该系统的特点、结构及功能,并结合实际工程应用介绍了该系统的工作流程,为该技术在其他类似工程的应用提供了有益的借鉴。     

静压下ZnS：Te中Te等电子陷阱的发光

研究了4块ZnS：Te薄膜样品(Te组分从0．5％到3．1％)的光致发光谱在常压下的温度特性．对于Te组分较小的2块样品观察到2个发光峰，分别来自Te1和Te2等电子陷阱；而对Te组分较大的2块样品则只观察到1个来自Te2等电子陷阱的发光．我们还研究了这些发光峰在低温1．5K下的流体静压压力行为．观察到与Te1有关的发光峰压力系数比ZnS带边的要大很多，而与Te2有关的发光峰压力系数则比带边小．根据Koster-Slater模型，价带态密度半宽随压力的增加是Te1中心有较大压力系数的主要原因，而Te1和Te2中心的不同压力行为则是由于压力对两者缺陷势增强的不同效果引起的．     

A compact LTCC branch-line coupler UsingModified-T equivalent-circuit modelfor transmission line

In this letter, a compact branch-line coupler is proposed by making good use of the three-dimensional layout capability of the low-temperature co-fired ceramic (LTCC) substrate. This branch-line coupler is accomplished by using lumped-inductors and lumped-capacitors to realize the modified-T equivalent-circuit model for the transmission line so that the circuit size may drastically be reduced. Specifically, a very compact LTCC branch-line coupler with a size of 0.079/spl lambda//spl times/0.0717/spl lambda/ is implemented and carefully examined, where /spl lambda/ is the wavelength of the multilayer structure at the operating frequency f/sub 0/.     

Robust Space Time Receiver for CDMA-based Antenna Arrays

In this paper, we propose a new robust code division multiple access (CDMA) receiver of which weight vector is obtained by projecting the effective spatio-temporal signature waveform onto the signal subspace of the data covariance matrix. We verified our proposed algorithm by the field measured data obtained with a custom-built wideband CDMA test-bed. It will be shown that the proposed algorithm is robust to the signal mismatch.     

降低精炼钢中氢氧含量的探索

主要介绍通过优化炼钢生产工艺,使产品满足新的技术要求:S≤0.010％,P≤0.015％.[H]≤0.0002％,[O]≤0.0045％,[N]≤0.0055％。     

ARTIFICIAL INTELLIGENCE CONTROL OF FOOD FREEZER USING ROTATING DISK AIR DISTRIBUTOR FOR UNIFORM FREEZING

A rotating disk air distribution (RDAD) system consisting of a rotating disk with an air supply hole was fabricated to solve the nonuniform freezing problem of a freezer that supplies air through a duct at a fixed location. The RDAD system was installed in a freezer to supply freezing air in various directions by controlling the position of the air supply hole. An equation estimating air velocity in the freezer was developed based on heat balance between a brass block thermocouple (BBT) probe and ambient air stream. The equation was applied to the analysis of airflow patterns developed through the RDAD and the fixed duct system. For control of the RDAD system, a fuzzy matrix was constructed with the measured nodal temperature at 3D locations in the freezer and used to search for the optimum direction of air supply. Uniform cooling was accomplished with the RDAD system using fuzzy and expert algorithms leading to temperature deviation σ=0.666, compared with 0.289 of the fixed air supply system. Cooling rate of model food (BBT) was 1.75 times faster than that of the fixed system.     

Synthesis and characterization of poly(siloxane-urethane)s

A series of polyurethane block copolymers based on hydroxy-terminated polydimethylsiloxane and poly(propylene glycol) soft segments of molecular weights 1818 and 2000, respectively, were synthesized. The hard segments consisted of 4,4′-diphenylnethane diisocyanate and 1,4-butanediol as the chain extender. Samples with different molar ratios were prepared. We tried to synthesize polydimethylsiloxane-based polyurethanes (PDMS-PU) containing a hard block as major fraction and a soft block as minor fraction for preparing toughened rigid systems. After a study of the pure polydimethylsiloxane-based polyurethane and poly(propylene glycol)-based polyurethane (PPG-PU), (mixed polyol)-based block copolymers and blends of PDMS-PU and PPG-PU were synthesized, and characterized by means of differential scanning calorimetry, tensile testing and scanning electron microscopy. In (mixed polyol)-based copolymers and lower hard-segment content blends, macro-phase separation occurred, but blends with higher hard-segment contents showed significant reduction in amounts of phase separation.     

Platinum concentrations in urban road dust and soil, and in blood and urine in the United Kingdom

Increasing Pt concentrations from vehicle catalysts have been reported from a number of countries. Analysis of Pt and Pd in soils and road dusts taken from areas of high and low traffic flows in SE England show concentrations of Pt in the range < 0.30-40.1 ng g-1 and Pd in the range < 2.1-57.9 ng g-1. Higher concentrations of Pt are associated with high traffic densities. Samples taken from streets of lower traffic flows were found to contain the lower concentrations of the ranges. Pilot studies of Pt concentrations in blood and urine using ICP-MS have been carried out. Platinum concentrations in whole blood were: precious metal workers, 780-2170, mean 1263 pmol l-1 (0.152-0.423, mean 0.246 microgram l-1); motorway maintenance workers, 645-810, mean 744 pmol l-1 (0.126-0.158, mean 0.145 microgram l-1); Imperial College staff, 590-713, mean 660 pmol l-1 (0.115-0.139, mean 0.129 microgram l-1). Platinum concentrations in urine in pmol Pt per mmol creatinine were: precious metal workers, 122-682, mean 273 [0.21-1.18, mean 0.47 microgram Pt (g creatinine)-1]; motorway maintenance workers, 13-78, mean 33.7 [0.022-0.135, mean 0.058 microgram Pt (g creatinine)-1]; Imperial College staff, 28-130, mean 65.6 [0.048-0.224, mean 0.113 microgram Pt (g creatinine)-1]. Detection limits were 0.03 microgram l-1 for both blood and urine. The possible health effects of increasing Pt in the environment are discussed. Platinum provides an excellent example of the significance of speciation in metal toxicity. Platinum allergy is confined to a small group of charged compounds that contain reactive ligand systems, the most effective of which are chloride ligand systems. Metallic Pt is considered to be biologically inert and non allergenic and since the emitted Pt is probably in the metallic or oxide form, the sensitising potential is probably very low. Platinum from road dusts, however, can be solubilised, and enter waters, sediments, soils and the food chain. There is at present no evidence for any adverse health effects from Pt in the general environment, particularly allergic reactions.     

“镍”催化酰氯和有机锡试剂交叉偶联反应的研究

镍络合物催化酰氯与有机锡试剂交叉偶联合成有机酮的反应,其反应选择性强,反应彻底,转化率高,工艺简单。在有机锡过量的情况下,对不同催化剂的催化活性和包括投料比,反应温度,反应时间,反应溶剂等反应条件进行了考察。