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991.
Gabriele Giancane Andrés Ruland Vito Sgobba Daniela Manno Antonio Serra Gianluca M. Farinola Omar Hassan Omar Dirk M. Guldi Ludovico Valli 《Advanced functional materials》2010,20(15):2481-2488
An alkoxy‐substituted poly(phenylene thiophene) is used in order to suspend single‐walled carbon nanotubes in an organic solvent. The suspension is spread on the air–water interface of a Langmuir trough and the floating film is characterized by means of Brewster angle microscopy and UV‐visible reflection spectroscopy and the compression isotherm is recorded. The polymer/carbon‐nanotube blend is transferred onto different substrates using the Langmuir–Blodgett technique. AFM measurements indicate the formation of globular structures for the samples transferred at low surface‐pressure values and a tubular morphology for high‐pressure‐deposited samples. AFM analysis is repeated on a sample exposed to soft X‐rays for about 5 h and a highly organized structure of bundles of carbon nanotubes rises up. Samples with different numbers of layers are transferred onto ITO substrates by means of the Langmuir–Blodgett method and are tested as photocathodes in a photo‐electrochemical cell. A Voc of 0.18 V, an Isc of 85.8 mA, FF of 40.0%, and η of (6.23 × 10?3)% are obtained. 相似文献
992.
From initial conceptualization through to market adoption, the introduction of new technology into a commercial market is often fraught with challenges. In the field of biomaterials these challenges manifest themselves at every step of the commercialization process. As the understanding of the mechanobiologic relationship in tissue engineering has progressed, there is greater emphasis being placed on the engineering of specific properties into new biomaterials. During this early development, intellectual property is a critical factor in determining commercial feasibility as patent protection establishes the property lines around the technology and helps define future market segments. Once developed, a new biomaterial then enters the next series of challenges including commercial‐scale manufacturing and addressing regulatory concerns. Synthesis of the biomaterial must be economically and technically scalable to meet market demands and the new biomaterial must be designed to stand up to regulatory scrutiny with regards to safety and efficacy. However daunting, a robust understanding of the design elements and the commercial requirements will aid the researcher in overcoming the challenges of bringing a new biomaterial to the market. © 2018 Society of Chemical Industry 相似文献
993.
Cynthia Barnhart Christopher A. Hane Ellis L. Johnson Gabriele Sigismondi 《Telecommunication Systems》1994,3(3):239-258
Multi-commodity network flow problems, prevalent in transportation, production and communication systems, can be characterized by a set of commodities and an underlying network. The objective is to flow the commodities through the network at minimum cost without exceeding arc capacities. In this paper, we present a partitioning solution procedure for large-scale multi-commodity flow problems with many commodities, such as those encountered in the telecommunications industry. Using a cycle-based multi-commodity formulation and column generation techniques, we solve a series of reduced-size linear programs in which a large number of constraints are relaxed. Each solution to a reduced-size problem is an improved basic dual feasible solution to the original problem and, after a finite number of steps, an optimal multi-commodity flow solution is determined. Computational experience is gained in solving randomly generated test problems and message routing problems in the communications industry. The tests show that the procedure solves large-scale multi-commodity flow problems significantly faster than existing linear programming or column generation solution procedures. 相似文献
994.
995.
Theo Fett Gabriele Rizzi Hans-Achim Bahr Ute Bahr Van-Bac Pham Herbert Balke 《International Journal of Fracture》2007,146(3):189-195
An analytical solution for the linear-elastic problem of an edge-cracked semi-infinite body was given already in 1957. For
the numerical evaluation of this solution an iteration procedure had to be applied. This might be the reason why the related
analysis was not commonly used. By means of powerful mathematical tools developed in the last years it is now possible to
evaluate highly-precise stress intensity factors, T-stress terms, weight functions etc. This will be shown in this paper in
detail. 相似文献
996.
Voltammetry was used to monitor in rats changes in medial prefrontal cortex (PFC) dopamine (DA) levels associated with response-contingent presentation of a condensed milk reward. During two initial training sessions, minor DA signal fluctuations were seen when animals consumed a standard 30 sec (0.2 ml) meal earned on a continuous reinforcement schedule. There was no evidence of experience-dependent changes in these fluctuations. Under delayed reinforcement conditions, lever-presses were followed by DA signal increases that were time-locked to the delay duration, and these were followed by signal decreases when animals eventually received the reward. Such decreases became more pronounced when the standard rate of milk delivery was tripled, but were attenuated when milk delivery was reduced to half the usual rate. Withholding earned milk resulted in signal increases. In contrast, DA signal increases were observed during milk consumption when the standard meal duration was unexpectedly shortened to 15 sec or lengthened to 60 or 90 sec. Orderly changes in DA signal were also observed under partial reinforcement conditions. Unreinforced responses were associated with DA signal decreases, whereas transient increases were seen during the 30 sec meal that followed reinforced responses. These findings indicate that response-contingent reward presentation elicits synchronous changes in PFC DA transmission. They also suggest that the DA input to PFC is activated when rewards are presented under conditions that deviate from those that the animals had come to expect, particularly so when the temporal structure of learned associations is altered. 相似文献
997.
998.
Viet Dung Le Michel Gratton Michaël Caliez Arnaud Frachon Didier Picart 《Journal of Materials Science》2010,45(21):5802-5813
This article deals with the characterization of the static mechanical behavior of an energetic material. Due to its constituents (crystals and a polymeric binder), the behavior is complicated to model. A specific experimental protocol has been proposed in this article. It involves uniaxial tensile and compressive tests, compression under confinement and dynamic mechanical analysis. A constitutive law has been developed. The behavior is described using a Maxwell’s model, in which all the components are influenced by an isotropic damage. The first component takes into account an elasto-plastic behavior. The yield stress evolution is described using a parabolic criterion and an isotropic hardening law. The plastic flow rule is non-associated. A linear visco-elastic behavior is used for the other components. Numerical simulations show that experimental data are quite well reproduced. The last part of the article is devoted to a discussion highlighting the future improvements. 相似文献
999.
Masonry curved structures, as for instance arches, domes and vaults, are very diffused in historical and existing structures and usually require seismic upgrading and/or rehabilitation. 相似文献
1000.
Max Lemberg Gabriele Sadowski Martin Gerlach Emilija Kohls Matthias Stein Christof Hamel Andreas Seidel‐Morgenstern 《American Institute of Chemical Engineers》2017,63(10):4576-4585
Solvent effects on the reaction equilibrium of the 1‐dodecene hydroformylation in a decane/N,N‐dimethylformamide solvent system is investigated. The reaction was performed at different decane/N,N‐dimethylformamide ratios and at temperatures between 368 K and 388 K. The equilibrium concentrations of all reactants and products were determined experimentally. The enthalpy and Gibbs energy of this reaction at the ideal‐gas standard state were determined by quantum‐chemical calculations in good agreement with literature data. Moreover, quantum‐chemically calculated standard Gibbs energies of reaction at infinite dilution in liquid decane/DMF‐solvent mixtures allowed a qualitative prediction of the solvent effect on the equilibrium concentrations. Based on the standard Gibbs energy of reaction at the ideal‐gas standard state and on fugacity coefficients calculated using the Perturbed‐Chain Statistical Associating Fluid Theory, the equilibrium concentrations of reactants and products for the 1‐dodecene hydroformylation performed in decane/N,N‐dimethylformamide mixtures of different compositions could be predicted in very good agreement with experimental data. © 2017 American Institute of Chemical Engineers AIChE J, 63: 4576–4585, 2017 相似文献