Studies on curing urethane prepolymers with aniline–formaldehyde resins

Commercial aniline–cresol–formaldehyde resin, two model aniline–formaldehyde and aniline–cresol–formaldehyde resins, and methylenedianiline have been used as curatives for NCO-terminated urethane prepolymer prepared from polyoxypropylenediol and toluene-diisocyanate. Based on viscoelastic behavior of the investigated systems and changes in their IR spectra, it has been concluded that phenolic OH groups present in aniline–cresol–formaldehyde resin do not play an important role in the curing process carried out at RT despite earlier suggestions to the contrary. The explanation for specific behavior of systems where urethane prepolymers have been cured with commercial aniline–cresol–formaldehyde resin is presumably the presence of small amount of solvent (benzyl alcohol) in that resin, which may influence the reaction kinetics.     

Adhesives from polyepichlorohydrin elastomers. I. Studies on the properties of adhesive solutions of polyepichlorohydrin

The dependence of the specific viscosity of polyepichlorohydrin solutions in various solvents on the concentration of solutions was investigated. It was shown that there is only a little difference between specific viscosity measured in various solvents at the same concentration. Solubility diagrams for polyepichlorohydrin were made using both Hansen and Lieberman method and some properties (specific viscosity, evaporation rate and solvent retention in adhesive films) of solutions were plotted against the composition of solvent mixtures. A definite dependence of the specific viscosity on the position of solvent mixture in solubility diagrams was found. This behaviour is discussed in terms of intermolecular attractions.     

Packet dispatching using module matching in the modified MSM Clos-network switch

A modified memory-space-memory (MSM) Clos-network switch, called MCNS, with a module-level matching packet dispatching scheme, is presented in the paper. The MCNS is a modification of the MSM Clos-network switch proposed to simplify the packet dispatching scheme. In this paper, we evaluate the combinatorial properties of the MCNS, as well as a new module-level matching packet dispatching algorithm. We also show how this algorithm can be implemented in an field-programmable gate array chip. Selected simulation results obtained for the MCNS are compared with the results obtained for the MSM Clos-network switch using other module-level matching algorithms.     

A comparative study on selective properties of Kraft lignin–natural rubber composites containing different plasticizers

Effect of plasticizer type on the kraft lignin–natural rubber composite microstructure and selected properties was determined. The composites were prepared with addition of a commonly used naphthenic oil plasticizer to study the decomposition product of polyurethane (glycerolysate) and its characteristics. Kraft lignin powder was incorporated into the natural rubber matrix in amounts of 10 and 40 parts per 100 parts of natural rubber (phr). The reference samples were prepared without any lignin present. The chemical interaction between the filler particles and natural rubber macromolecules was analyzed by Fourier transform infrared spectroscopy (FTIR) and the adhesion was characterized by scanning electron microscopy (SEM). The results of the adhesion measurements confirmed poor distribution of lignin particles into the natural rubber matrix with increasing filler content. Optimal lignin content in the composites was 10 phr in the case of both plasticizers. Moreover, the results of FTIR verified the formation of non-covalent bonds and the need for modification of the filler to enhance the reinforcing effect in the natural rubber matrix. Dynamic mechanical analysis (DMA) and mechanical measurements proved that the specimen containing 10 phr of lignin with the use of glycerolysate as plasticizer displayed the highest mechanical performance. It was demonstrated that glycerolysate and naphthenic oil as plasticizing agents showed similar effect on the thermal properties of the prepared composites. Also, the measured mechanical properties, such as tensile strength, hardness, resilience, and abrasiveness confirmed these findings.     

Long-term changes in sewage sludge stored in a reed bed

The problem of the utilization and management of sewage sludge originating from small wastewater treatment plants is still unsolved. A common approach is to store the sludge in plots which in time turn into grassland. This investigation was aimed at evaluating the influence of the storage time in plots on the chemical properties of sewage sludge deposited there. Tests were carried out on samples obtained from discrete layers of stratified sludge that had lain in a hydrophyte facility disused for 7 years after 23 years of continuous sludge discharge. The age of the sludge was established by the lead-210 method. Moisture, organic matter, total nitrogen and total phosphorus contents were measured in samples of dated sewage sludge. The composition of the stored biosolids stabilized with respect to phosphorus, nitrogen and organic matter within 11, 15 and 17 years, respectively.     

Isolation of Failing Scan Cells through Convolutional Test Response Compaction

This paper describes a non-recursive fault diagnosis technique for scan-based designs with convolutional test response compaction. The proposed approach allows a time-efficient and accurate identification of failing scan cells using Gauss–Jordan elimination method.

Inflammation and Oxidative Stress in Diabetic Kidney Disease: The Targets for SGLT2 Inhibitors and GLP-1 Receptor Agonists

The incidence of type 2 diabetes (T2D) has been increasing worldwide, and diabetic kidney disease (DKD) remains one of the leading long-term complications of T2D. Several lines of evidence indicate that glucose-lowering agents prevent the onset and progression of DKD in its early stages but are of limited efficacy in later stages of DKD. However, sodium-glucose cotransporter-2 inhibitors (SGLT2i) and glucagon-like peptide-1 receptor (GLP-1R) agonists were shown to exert nephroprotective effects in patients with established DKD, i.e., those who had a reduced glomerular filtration rate. These effects cannot be solely attributed to the improved metabolic control of diabetes. In our review, we attempted to discuss the interactions of both groups of agents with inflammation and oxidative stress—the key pathways contributing to organ damage in the course of diabetes. SGLT2i and GLP-1R agonists attenuate inflammation and oxidative stress in experimental in vitro and in vivo models of DKD in several ways. In addition, we have described experiments showing the same protective mechanisms as found in DKD in non-diabetic kidney injury models as well as in some tissues and organs other than the kidney. The interaction between both drug groups, inflammation and oxidative stress appears to have a universal mechanism of organ protection in diabetes and other diseases.     

Application of zirconium (IV) acetylacetonate to the copolymerization of glycolide with ɛ-caprolactone and lactide

Summary A study on the copolymerization of glycolide with lactide and glycolide with ɛ-caprolactone was performed in the presence of zirconium (IV) acetylacetonate at moderate temperatures (100° and 150°C). Zirconium acetylacetonate appeared to be an efficient initiator of copolymerization. The obtained polymers were characterized by high molecular weights. Considerable influence of transesterification on the polymer chain microstructure was found. Received: 13 October 1998/Revised version: 4 January 1999/Accepted: 4 January 1999